k1                               k2        Temp (oC)      t1/2 (min)     Ea (kJ/mol)  ΔG (kJ/mol) ΔH (KJ/mol) ΔS (KJ/mol)    D     t1/2(min)   Ea(kJ/mol)       ΔG(kJ/mol)      ΔH(KJ/mol)    ΔS(KJ/mol)    D      50                 3.79             2510                45.82           -175.422        -221.24       51.2       4.14            2200               -296.98         -485.42            -188.44       72.0       60                3.40              2510               -37.29          -258.562         -221.27       34.4       3.89            2200               -380.09         -568.56            -188.47       56.2      70                 2.86              2510              -120.37         -341.702         -221.30       20.2       3.18            2200               -463.2           -651.70             -188.50      27.8      80                 2.05              2510               -203.51       -424.842          -221.33       8.9        2.67           2200               -546.31         -734.84              -188.53     16.6                               z-value  = 14.11                                                                            z-value = 19.46

Table 1: Half-life and activation parameters for the first and second phase (k1 & k2) respectively in the thermal inactivation of peroxidase.