S.No |
% of solvent |
ΔH° (kJ/mol.) |
Methanol- H2O* |
Ethanol-H2O |
1-propanol-H2O |
2-propanol-H2O |
1 |
0 |
-2.325 ± 0.16 |
-3.167 ± 0.02 |
-2.574 ± 0.02 |
-2.503 ± 0.06 |
2 |
1 |
-2.061 ± 0.13 |
-3.023 ± 0.06 |
-1.776 ± 0.09 |
-3.824 ± 0.03 |
3 |
2 |
-2.516 ± 0.20 |
-3.449 ± 0.03 |
-2.503 ± 0.03 |
-2.833 ± 0.02 |
4 |
3 |
-2.326 ± 0.16 |
-3.005 ± 0.04 |
-3.527 ± 0.07 |
-2.625 ± 0.04 |
5 |
4 |
-3.048 ± 0.18 |
-1.006 ± 0.01 |
-1.092 ± 0.04 |
-2.822 ± 0.01 |
6 |
5 |
-1.961 ± 0.56 |
-1.092 ± 0.03 |
-0.957 ± 0.07 |
-3.001 ± 0.02 |
7 |
6 |
-3.403 ± 0.01 |
-0.921 ± 0.02 |
-0.850 ± 0.01 |
-0.623 ± 0.05 |
8 |
10 |
-2.869 ± 0.09 |
-0.582 ± 0.04 |
-2.508 ± 0.04 |
2.561 ± 0.03 |
9 |
15 |
-2.385 ± 0.18 |
-0.327 ± 0.01 |
-5.008 ± 0.01 |
0.450 ± 0.07 |
10 |
20 |
-1.861 ± 0.02 |
-1.234 ± 0.01 |
-2.199 ± 0.05 |
-0.616 ± 0.01 |
11 |
25 |
-7.595 ± 0.16 |
-2.716 ± 0.02 |
-2.709 ± 0.06 |
-1.638 ± 0.02 |
*328 ± 1K in case of methanol |