Parameter |
Reagent |
I |
II |
III |
IV |
lmax
|
462 |
478 |
482 |
495 |
Beer’s law, mg mL−1 |
0.05-1.20 |
0.05-1.00 |
0.5-1.10 |
0.05-1.15 |
Ringbom conc, mg mL−1 |
0.15-1.05 |
0.20-0.85 |
0.1-1.0 |
0.15-1.05 |
Molar absorptivity, L mol-1cm−1 |
1.05 x 105 |
1.12 x 105 |
1.57 x 105 |
1.31 x 105 |
Sandell sensitivity ng cm−2 |
1.97 |
1.85 |
1.32 |
1.58 |
Detection limit, ng mL-1 |
15 |
14 |
16 |
17 |
Quantification limit, ng mL-1 |
48 |
45 |
50 |
54 |
Stability up to bray |
7.0 |
7.0 |
9.0 |
10.6 |
Regression equation * |
|
|
|
|
(a) intercept |
- 0.013 |
0.009 |
0.012 |
- 0.008 |
(b) slope |
0.51 |
0.54 |
0.76 |
0.63 |
Correlation coefficient a |
0.9992 |
0.9990 |
0.9996 |
0.9988 |
Standard deviation % |
0.38 |
0.61 |
0.72 |
0.54 |
Relative standard deviation % |
0.87 |
1.13 |
1.27 |
0.96 |
Error % |
± 1.3 |
± 1.6 |
± 1.7 |
± 1.5 |
aA = a +bC where C is the concentration of Pb2+ in ng mL−1 |