| Polymer SPE material |
Template |
Functional monomers
(mmol) |
Cross-linking Monomer (mmol) |
ACN
mL |
S
m2 g-1 |
Vp
cm3 g-1 |
dp
(Å) |
| MC-LR (mmol) |
APMSA |
MAA |
IA |
EGDMA |
| MIP-1 |
1 |
- |
10 |
- |
1.5 |
5 |
380±5 |
0.632 |
125 |
| MIP-2 |
1 |
10 |
- |
- |
1.5 |
5 |
393±4 |
0.645 |
118 |
| MIP-3 |
1 |
- |
- |
10 |
1.5 |
5 |
416±3 |
0.653 |
97 |
SPE, Solid Phase Extraction; MIP-1, molecularly imprinted polymer formulated with MAA and EGDMA; MIP-2, molecularly imprinted polymer formulated with APMSA and EGDMA and MIP-3, molecularly imprinted polymer formulated with IA and EGDMA.
MC-LR, microcystin-LR; APMSA, 2-Acrylamido-2-methyl-1-propanesulfonic acid; MAA, methacrylic acid; IA, itaconic acid; EGDMA, ethylene glycol dimethacrylate; ACN, acetinitrile.
S, BET surface area; Vp, specific pore volume; and dp, average pore diameter were calculated from nitrogen absorption measurements. |
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