| Compound |
∆H**, Jmol-1 |
∆S, J mol-1 K-1 |
∆G, KJmol-1 |
R2 |
| Phenol |
76.75
(78.58) |
233.3
(231.3) |
-69.45
(-68.85) |
0.9938
(0.9568) |
| 2-CP |
38.64
(47.8) |
104.51
(120.8) |
-31.11
(-35.95) |
0.9162
(0.9682) |
|
*The values of thermodynamic parameters using plasticized iron(Ш)-immobilized
PUF are given in parentheses.
**The calculated values of ΔH from Vant,hoff equation for phenol and 2-CP retention
onto unplasticized- and plasticized iron (III) immobilized PUF were found 75.55
(78.72) and 38.7 (48.33) Jmol-1, respectively. |
| Table 2: Numerical thermodynamic parameters (ΔH, ΔS and ΔG) for the tested
phenols onto unplasticized and TBP plasticized iron (III)-immobilized PUF*. |
