| |
|
G1 |
G2 |
SDS
|
| No |
Analytes |
log Powa |
log Pmw |
∆b |
log Pmw |
∆ |
log Pmw |
∆ |
| NHB solutes |
| 1 |
Benzene |
2.13 |
1.91 |
0.22 |
1.91 |
0.22 |
1.59 |
0.54 |
| 2 |
Toluene |
2.69 |
2.32 |
0.37 |
2.32 |
0.37 |
2.03 |
0.66 |
| 3 |
Chlorobenzene |
2.84 |
2.51 |
0.33 |
2.49 |
0.35 |
2.14 |
0.70 |
| 4 |
Bromobenzene |
2.99 |
2.71 |
0.28 |
2.65 |
0.34 |
2.29 |
0.70 |
| 5 |
Ethylbenzene |
3.15 |
2.69 |
0.46 |
2.67 |
0.48 |
2.40 |
0.75 |
| 6 |
p-Xylene |
3.15 |
2.71 |
0.44 |
2.70 |
0.45 |
2.45 |
0.70 |
| 7 |
4-Chlorotoluene |
3.33 |
2.90 |
0.43 |
2.88 |
0.45 |
2.58 |
0.75 |
| 8 |
Iodobenzene |
3.25 |
2.98 |
0.27 |
2.91 |
0.34 |
2.53 |
0.72 |
| 9 |
Propylbenzene |
3.68 |
3.11 |
0.57 |
3.07 |
0.61 |
2.84 |
0.84 |
| 10 |
Naphthalene |
3.35 |
3.24 |
0.11 |
3.17 |
0.18 |
2.71 |
0.64 |
| Absolute mean ∆c |
|
|
0.35 |
|
0.38 |
|
0.70 |
| HBA solutes |
| 11 |
Benzonitrile |
1.56 |
1.71 |
-0.15 |
1.81 |
-0.25 |
1.65 |
-0.09 |
| 12 |
Acetophenone |
1.58 |
1.76 |
-0.18 |
1.86 |
-0.28 |
1.83 |
-0.25 |
| 13 |
Nitrobenzene |
1.85 |
1.98 |
-0.13 |
2.04 |
-0.19 |
1.72 |
0.13 |
| 14 |
Methyl benzoate |
2.16 |
2.10 |
0.06 |
2.19 |
-0.03 |
2.12 |
0.04 |
| 15 |
Propiophenone |
2.20 |
2.12 |
0.08 |
2.19 |
0.01 |
2.14 |
0.06 |
| 16 |
4-Chloroacetophenone |
2.35 |
2.35 |
0.00 |
2.41 |
-0.06 |
2.35 |
0.00 |
| 17 |
4-Nitrotoluene |
2.45 |
2.38 |
0.07 |
2.45 |
0.00 |
2.17 |
0.28 |
| 18 |
Ethyl benzoate |
2.64 |
2.46 |
0.18 |
2.54 |
0.10 |
2.48 |
0.16 |
| 19 |
4-Chloroanisole |
2.82 |
2.73 |
0.09 |
2.71 |
0.11 |
2.40 |
0.42 |
| Absolute mean ∆c |
|
|
0.10 |
|
0.10 |
|
0.17 |
| HBD solutes |
| 20 |
Benzyl alcohol |
1.08 |
1.56 |
-0.48 |
1.66 |
-0.58 |
1.36 |
-0.28 |
| 21 |
Phenol |
1.49 |
2.24 |
-0.75 |
2.32 |
-0.83 |
1.32 |
-0.17 |
| 22 |
3-Methylphenol |
1.96 |
2.42 |
-0.46 |
2.49 |
-0.53 |
1.48 |
-0.48 |
| 23 |
4-Chloroaniline |
1.83 |
2.60 |
-0.77 |
2.53 |
-0.70 |
1.94 |
-0.11 |
| 24 |
4-Flourophenol |
1.77 |
2.61 |
-0.84 |
2.69 |
-0.92 |
1.73 |
0.04 |
| 25 |
4-Ethylphenol |
2.58 |
2.98 |
-0.40 |
3.05 |
-0.47 |
2.15 |
0.43 |
| 26 |
4-Chlorophenol |
2.35 |
3.08 |
-0.73 |
3.13 |
-0.78 |
2.00 |
0.35 |
| 27 |
3-Chlorophenol |
2.49 |
3.16 |
-0.67 |
3.21 |
-0.72 |
1.98 |
0.51 |
| 28 |
4-Bromophenol |
2.59 |
3.29 |
-0.70 |
3.31 |
-0.72 |
2.16 |
0.43 |
| 29 |
3-Bromophenol |
2.63 |
3.37 |
-0.74 |
3.40 |
-0.77 |
2.14 |
0.49 |
| Absolute mean ∆c |
|
|
0.65 |
|
0.70 |
|
0.33 |
| Alkyl phenyl ketones |
| 30 |
Butyrophenone |
2.73 |
2.49 |
-0.24 |
2.56 |
-0.17 |
2.54 |
-0.19 |
| 31 |
Valerophenone |
3.26 |
2.89 |
-0.37 |
2.94 |
-0.32 |
2.94 |
-0.32 |
| 32 |
Hexanophenone |
3.79 |
3.34 |
-0.45 |
3.36 |
-0.43 |
3.37 |
-0.42 |
| 33 |
Heptanophenone |
4.32 |
3.83 |
-0.49 |
3.78 |
-0.54 |
3.85 |
-0.47 |
| Absolute mean ∆c |
|
|
0.30 |
|
0.30 |
|
0.28 |
| Overall absolute mean ∆d |
|
|
0.35 |
|
0.37 |
|
0.37 |
aLiterature values. From reference [16].
bΔ=log Pow(Lit)- log Pmw(MEKC)
cAbsolute mean of differences for each subset solutes.
dAbsolute mean of differences for all solutes.
|
