| Technique |
Analytes |
Matrix(% Recovery) |
System |
Eluent |
PF |
Detection limit (μg L−1) |
R.S.D (%) |
Optimum operating condition |
Reference |
| FAAS |
Cu, Fe, Pb, Mn, Zn,Cd, Ni, Bi, Cr |
|
Co-DEDTC |
1.0 mL conc. HNO3 |
225 |
4–64 |
<7 |
pH: |
[32] |
| Amount of carrier element (mg): |
| Amount of chelating agent(mg): |
| Sample volume (mL): |
| FAAS |
Pb, Cd, Cr, Ni, Mn |
Water(96 – 98) |
Cu- DBDTC |
0.5 mL conc. HNO3 |
50 |
0.34–0.87 |
<10 |
pH: 9 |
[33] |
| Amount of carrier element (mg): 1 |
| Amount of chelating agent(mg): 10 |
| Sample volume (mL): 25 |
| FAAS |
Cd, Cu, Pb |
Water( 88.6 -103.5) |
Bi(III)4-MPDTC |
1 mL conc. HNO3 |
200 |
0.18-0.50 |
<10 |
pH: 5 |
[26] |
| Amount of carrier element (mg): 4 |
| Amount of chelating agent(mg): 400 |
| Sample volume (mL): 250 |
| FAAS |
Ni, Cr, Mn, Pb, Zn |
Water (96.8-100) Sediment (97.3-99.2) |
Cu-cHMDTC |
0.5 mL conc. HNO3 |
10 |
0.003-0.10 |
<17 |
pH: 9 |
[28] |
| Amount of carrier element (mg): 1 |
| Amount of chelating agent(mg): 10 |
| Sample volume (mL): 25 |
| FAAS |
Ni |
Water (89.5 ± 1.3)
Sediment (90.2 ± 0.3) |
Cu-MBDTC |
1.0 mL conc. HNO3 |
10 |
0.003-0.006 |
< 5 |
pH: 9 |
This study |
| Cr |
Water (93.2 ± 2.1)
Sediment (87.2 ± 1.1) |
Amount of carrier element (mg): 1 |
| Co |
Water (92.1 ± 2.4)
Sediment (89.0 ± 0.5) |
Amount of chelating agent(mg): 10 |
| Mn |
Water (89.7 ± 0.5)
Sediment (92.7 ± 0.4) |
Sample volume (mL): 10 |
