Compounda Decomposition temperature (°C) Method Parameter Correlation coefficient (r) Ea (KJ mol−1) A (s−1) ΔS* (J mol−1K−1) ΔH* (KJ mol−1) ΔG* (KJ mol−1) HL1 211-346 CR 45.8 7.58×101 -214 41.2 159 0.99221     HM 53.6 4.18×102 -200 49 159 0.99398   498-624 CR 180 4.43×108 -87.9 174 247 0.99355     HM 193 6.40×109 -65.8 186 241 0.99169 HL3 158-401 CR 46.9 7.11×101 -215 42.3 161 0.99322     HM 48.4 1.17×102 -210 43.8 160 0.99788   502-643 CR 162 2.34×107 -113 155 250 0.98442     HM 173 2.50×108 -92.2 166 245 0.99156 HL5 225-271 CR 329 2.54×1030 333 325 151 0.99453     HM 338 1.70×1032 367 333 142 0.99452   443-630 CR 108 1.51×104 -173 101 242 0.99432     HM 120 2.05×105 -152 113 236 0.9939 (1) 142-240 CR 70.9 5.53×105 -139 67.1 131 0.99122     HM 80.8 1.40×107 -112 76.9 129 0.98595   301-418 CR 102 1.31×106 -134 96.5 181 0.99104     HM 114 2.10×107 -111 108 179 0.99064 (2) 127-372 CR 31.2 3.31×100 -240 26.9 152 0.99523     HM 39.2 3.59×101 -220 34.9 150 0.98744   496-715 CR 108 1.59×104 -173 101 254 0.98712     HM 119 5.78×104 -163 112 255 0.98669 (3) 189-292 CR 106 3.74×108 -85.3 102 146 0.99596     HM 115 7.73×109 -60.0 111 142 0.99460   349-403 CR 235 9.36×1016 73.5 230 182 0.99590     HM 250 2.09×1018 99.3 244 180 0.99435 (4) 142-399 CR 31.8 2.10×100 -244 27.3 160 0.99161     HM 41.0 3.60×101 -220 36.5 156 0.98130   599-715 CR 171 4.27×107 -108 163 264 0.98947     HM 187 2.01×108 -95.4 179 268 0.99112

Table 5:Thermodynamic parameters of the thermal decomposition of HLn and their Cu(II) complexes.