Proteinoida |
Mw
(Da) b |
Mn
(Da) b |
Mp
(Da)b |
PDIc |
OpticalActivity[a]D25°C (°)d |
Prot1 |
26250 |
11300 |
11320 |
2.32 |
+6.5 |
Prot2 |
181540 |
144940 |
195300 |
1.25 |
-4.4 |
Prot2e |
500240 |
497280 |
503070 |
1.01 |
+8.1 |
Prot3 |
164930 |
138250 |
158740 |
1.19 |
-9.0 |
Prot4 |
87660 |
84410 |
85250 |
1.04 |
-3.3 |
Prot5 |
195080 |
165870 |
191440 |
1.17 |
-7.4 |
Prot6 |
190390 |
163290 |
204050 |
1.16 |
-15.1 |
Prot7 |
72260 |
56880 |
42870 |
1.27 |
+2.8 |
Prot8 |
168300 |
156600 |
136800 |
1.07 |
-4.6 |
Proteinoida |
Mw
(Da) b |
Mn
(Da)b |
Mp
(Da)b |
PDIc |
OpticalActivity[a]D25°C (°)d |
Prot1 |
26250 |
11300 |
11320 |
2.32 |
+6.5 |
Prot2 |
181540 |
144940 |
195300 |
1.25 |
-4.4 |
Prot2e |
500240 |
497280 |
503070 |
1.01 |
+8.1 |
Prot3 |
164930 |
138250 |
158740 |
1.19 |
-9.0 |
Prot4 |
87660 |
84410 |
85250 |
1.04 |
-3.3 |
Prot5 |
195080 |
165870 |
191440 |
1.17 |
-7.4 |
Prot6 |
190390 |
163290 |
204050 |
1.16 |
-15.1 |
Prot7 |
72260 |
56880 |
42870 |
1.27 |
+2.8 |
Prot8 |
168300 |
156600 |
136800 |
1.07 |
-4.6 |
|
aThe proteinoids were prepared at 180°C according to the experimental section; bmolecular masses were measured by GPC, Mp is the molecular mass at the peak; cPDI is the polydispersity index, given by Mw/Mn; dspecific optical rotation (c=1, in H2O, at 25°C); emade by microwave-assisted polymerization. Each experiment was performed
3 times, with an error of 0.5-1.7%. |
Table 2: Mw, Mn, Mp, PDI and optical activity of the various proteinoids. |