104  [Ce(IV)], mol dm-3 102 [Lys-OH], mol dm-3 104 (k’), sec-1 105 (k), dm3 mol-1 s-1
4.3 1.0 3.85 1.62
5.7 1.0 2.90 1.61
8.5 1.0 1.96 1.61
14.2 1.0 1.15 1.62
17.5 1.0 0.92 1.61
20.0 1.0 0.81 1.62
24.0 1.0 0.68 1.61
4.3 2.0 7.60 1.60
5.7 2.0 5.60 1.56
8.5 2.0 3.80 1.56
14.2 2.0 2.30 1.62
17.5 2.0 1.85 1.61
20.0 2.0 1.62 1.60
24.0 2.0 1.35 1.60
4.3 3.0 11.5 1.61
5.7 3.0 8.40 1.56
8.5 3.0 5.70 1.56
14.2 3.0 3.45 1.62
17.5 3.0 2.80 1.61
20.0 3.0 2.40 1.58
24.0 3.0 2.00 1.58
5.7 0.50 1.40 1.56
5.7 0.75 2.20 1.63
5.7 1.0 2.90 1.61
5.7 1.5 4.20 1.56
5.7 2.0 5.60 1.56
5.7 3.0 8.40 1.56
5.7 4.0 11.2 1.56
5.7 5.0 14.0 1.56
14.2 0.50 0.58 1.63
14.2 0.75 0.86 1.61
14.2 1.0 1.15 1.62
14.2 1.5 1.73 1.62
14.2 2.0 2.30 1.62
14.2 3.0 3.45 1.62
14.2 4.0 4.60 1.62
14.2 5.0 5.75 1.62
20.0 0.50 0.40 1.60
20.0 0.75 0.61 1.61
20.0 1.0 0.81 1.60
20.0 1.5 1.20 1.58
20.0 2.0 1.62 1.60
20.0 3.0 2.40 1.58
20.0 4.0 3.25 1.60
20.0 5.0 4.00 1.58
Table 1: Pseudo-first order and second order rate constant for the reaction of [Lys-OH] and [Ce(IV)] in HClO4 medium.
[Ag(I)]=5×10-4 mol dm-3, [H+]=1.0 mol dm-3, Temp.=45°C.