[SO32–], moldm–3       Zero order
First order
Second order
ko x 10-3 R2 k1 x 10-3 R2 k2 x 10-2 R2
0.4
0.6
0.8
1.0
1.2
1.5
1.6
1.8
2.4
2.4
3.0
3.1
0.576 
0.547
0.554
0.422
0.457
0.485
8.0
8.6
11.1
12.8
14.8
15.2
0.960
0.975
0.972
0.968
0.966
0.978
9.8
15.0
16.1
24.6
27.8
28.1
0.506
0.625
0.598
0.704
0.659
0.678
[MB+] mg/L Zero order
First order
Second order
ko x 10-3 R2 k1 x 10-2 R2 k2 x 10-1 R2
20
30
40
50
60
70
3.6
3.6
3.8
4.2
4.5
3.3
0.452
0.634
0.764
0.802
0.832
0.890
1.67
1.48
1.28
1.40
1.38
0.86
0.968
0.972
0.993
0.978
0.972
0.962
2.81
2.78
1.73
1.96
1.89
0.81
0.705
0.629
0.550
0.528
0.533
0.449
Table 1: Kinetics rates of reaction with respect to MB+ and SO32− .