Overall process & Its cyclea Relationb
M2+ + Lo + 2A- MLA2,o Kex = KD,M(KD,A)2KML,org bip,org Dfex0¢ = DfM0¢ - DfA0¢ + DfML,org0¢ + Dfip,org0¢
M2+ + Lo + 2A- MLA+o + A-o (a) Kex± = KD,M(KD,A)2KML,org K1,org (b) Kex± = KML KD,ML K1,org(KD,A)2/KD,L (a) Dfex±0¢ = 2DfM0¢ - 2DfA0¢ + 2DfML,org0¢ + Df1,org00¢ + Dfeq (b) Dfex±0¢ = 2DfML,w0¢ + 2DfML0¢ + Df1,org00¢ - 2DfA0¢ - DfL0¢ + Dfeq
M2+ + Lo + 2A- ML2+o + 2A-o Kex2± = KD,M(KD,A)2KML,org Dfex2±0¢ = DfM0¢ - DfA0¢ + DfML,org0¢ + Dfeq
aA thermodynamic cycle of an extraction constant expressed by the component equilibrium constants. bΔφip,org 0′ = (Δφ1,org 0′ + Δφ2,org 0′)/2
Table 2: Some examples on relations between the Δφk 0′ values and the potential differences based on component equilibrium constants.