|
L |
M |
log KD,A |
log Kex ()a |
log Kex± |
log Kn,NB ()b |
| n = 1 |
2 |
| 18C6 |
Ca |
-1.43 ± 0.03 |
9.82 ± 0.02
(5.3×10-3) |
5.44 ± 0.07
5.43 ± 0.18c |
5.9
[4.7]d |
4.38 ± 0.08
(8.9×10-4) |
| Sr |
-0.98 ± 0.07 |
11.44 ± 0.03
(3.1×10-3) |
6.92 ± 0.12
6.91± 0.13c |
5.3
[4.6]d |
4.52±0.12
(4.8×10-4) |
| Ba |
-0.69 ± 0.04 |
10.75 ± 0.08
(4.5×10-3) |
7.35 ± 0.11
7.44 ± 0.33c |
4.9
[3.4]d |
3.41 ± 0.14
(5.9×10-4) |
| B18C6 |
Ca |
-1.92 ± 0.04 |
7.35 ± 0.08
(3.6×10-3) |
2.71 ± 0.10
2.80 ± 0.29c |
5.0
[5.5]d |
4.64 ± 0.13
(6.9×10-4) |
| Sr |
-1.34 ± 0.04 |
9.41 ± 0.02
(4.0×10-3) |
4.34 ± 0.08
4.33 ± 0.13c |
4.7
[4.6]d |
5.07 ± 0.08
(2.3×10-4) |
| Ba |
-1.17 ± 0.02 |
9.51 ± 0.02
(4.7×10-3) |
5.01 ± 0.11
5.08 ± 0.42c |
4.1
[4.2]d |
4.50 ± 0.11
(2.1×10-4) |
aAverage values of I in the w phase. bAverage values of INB in the NB phase.
cLogarithms of average values calculated from each values of Kex± and their
propagation errors simultaneously-calculated. dNumber, h, of water molecules
coextracted with ML2+ into the NB phase. See ref. [17] |
