Parameters |
MET |
GLZ |
PLS-1 |
NAP/CLS |
PLS-1 |
NAP/CLS |
Calibration set results |
No. of factors |
9 |
11 |
6 |
6 |
Press |
0.2066 |
0.3082 |
0.0434 |
0.0190 |
RMSE(µg/ml) |
0.1136 |
0.1388 |
0.0520 |
0.0345 |
REP% |
0.7410 |
0.9051 |
1.6743 |
1.1102 |
Slope |
1.0035 |
0.9996 |
1.0052 |
1.0018 |
R2 |
0.9996 |
0.9993 |
0.9994 |
0.9992 |
Bias |
0.0000 |
0.0000 |
0.000 |
0.0000 |
Validation set results |
Press |
1.6127 |
1.5232 |
0.0723 |
0.0661 |
RMSE(µg/ml) |
0.4489 |
0.4364 |
0.0951 |
0.0909 |
REP% |
3.2070 |
3.1169 |
3.1696 |
3.0292 |
Slope |
1.0686 |
1.0625 |
1.0438 |
1.0382 |
R2 |
0.9912 |
0.9911 |
0.9966 |
0.9976 |
Bias |
-0.0349 |
0.0367 |
0.0225 |
0.0463 |
Figure of merits |
LOD(µg/ml) |
0.0965 |
0.1183 |
0.0441 |
0.0294 |
LOQ(µg/ml) |
0.2923 |
0.3584 |
0.1337 |
0.0890 |
SEM |
0.0293 |
0.035 |
0.0134 |
0.0089 |
|
