| |
Composition % w/w |
|
|
| Ion-e×changer |
Graphite |
2-NPPE |
Slope(mV/decade) |
Linear range (M) |
| CLO4ST |
|
|
|
|
| 1.0 × 10-5-5.0× 10-3 |
55.5 ± 0.5 |
45.0 |
54.0 |
1.0 |
| 5.0 × 10-6-1.0× 10-2 |
58.9 ± 1.0 |
43.0 |
54.0 |
3.0 |
| 1.0 × 10-7-1.0 ×10-2 |
60.0 ± 0.5* |
41.0 |
54.0 |
5.0 |
| |
|
|
|
CLO4SM |
| 5.0 × 10-5-5.0× 10-3 |
48.7 ± 1.5 |
45.0 |
54.0 |
1.0 |
| 5.0 ×10-5-5.0× 10-3 |
57.9 ± 0.5 |
43.0 |
54.0 |
3.0 |
| 8.0 ×10-5- 5.0× 10-3 |
56.3 ± 1.5 |
41.0 |
54.0 |
5.0 |
| |
|
|
|
CLO3PT |
| 5.0 × 10-5-1.0× 10-3 |
56.7 ± 1.0 |
45.0 |
54.0 |
1.0 |
| 5.0 × 10-6-5.0× 10-3 |
51.5 ± 1.0 |
43.0 |
54.0 |
3.0 |
| 1.0 ×1 0-6-1.0× 10-2 |
58.5 ± 0.5 |
41.0 |
54.0 |
5.0 |
| |
|
|
|
CLO3PM |
| 5.0 × 10-5-1.0× 10-2 |
53.2 ± 1.1 |
45.0 |
54.0 |
1.0 |
| 5.0 × 10-5-1.0× 10-2 |
56.1 ± 1.2 |
43.0 |
54.0 |
3.0 |
| 5.0 × 10-5-1.0× 10-2 |
56.0 ± 0.8 |
41.0 |
54.0 |
5.0 |
| |
|
|
|
CLOTPB |
| 1.0 ×10-5-1.0×10-2 |
56.0 ± 1.7 |
45.0 |
54.0 |
1.0 |
| 3.0 ×10-5-8.0× 10-3 |
53.3 ± 1.1 |
43.0 |
54.0 |
3.0 |
| 5.0 ×10-6-1.0× 10-2 |
57.6 ± 1.5 |
41.0 |
54.0 |
5.0 |
| |
|
|
|
CLORein |
| 5.0 ×10-5-1.0×10-2 |
55.0 ± 1.7 |
45.0 |
54.0 |
1.0 |
| 5.0 ×10-5-8.0× 10-3 |
52.3 ± 1.1 |
43.0 |
54.0 |
3.0 |
| 7.0 ×10-6-1.0× 10-2 |
57.5 ± 1.5 |
41.0 |
54.0 |
5.0 |
|
| * Selected composition: 5 %CLO-ST with different plasticizers |
| Plasticizers |
| 2-NPPE* |
54.0 |
41.0 |
60.0 ± 0.5 |
1.0 × 10-7-1.0 ×10-2 |
| TCP |
54.0 |
41.0 |
58.5 ± 0.5 |
5.0 × 10-7-1.0 ×10-2 |
| DOP |
54.0 |
41.0 |
56.8 ± 0.5 |
1.0 × 10-6-5.0 ×10-3 |
| DBP |
54.0 |
41.0 |
53.2 ± 0.5 |
5.0 × 10-6-5.0 ×10-3 |
| TBP |
54.0 |
41.0 |
52.0 ± 0.5 |
1.0 × 10-7-5.0 ×10-3 |
| Corn Oil (Afia) |
54.0 |
41.0 |
57.0 ± 0.5 |
5.0 × 10-8-1.0 ×10-4 |
|
| * Selected Plasticizer |
| Table 2: Composition and slope of calibration curves for different clopidogrel carbon paste electrodes at 25.0 ± 0.1°C. |