Validation Mixture No. |
% Recovery |
PLS |
CRACLS |
Aceclofenac |
Diclofenac |
Aceclofenac |
Diclofenac |
1 |
96.81 |
116.70 |
101.46 |
102.26 |
2 |
96.68 |
124.19 |
102.47 |
92.87 |
3 |
91.29 |
130.94 |
98.14 |
126.59 |
4 |
99.88 |
93.91 |
97.76 |
114.30 |
5 |
99.41 |
86.80 |
101.76 |
97.89 |
6 |
98.76 |
104.75 |
101.85 |
92.19 |
7 |
101.35 |
93.72 |
99.36 |
117.98 |
8 |
97.84 |
93.57 |
101.45 |
104.98 |
9 |
98.28 |
107.17 |
100.51 |
109.85 |
10 |
95.99 |
108.66 |
97.25 |
119.52 |
|
97.63 |
106.04 |
100.20 |
107.84 |
± S.D. |
2.75 |
14.52 |
1.92 |
11.76 |
R.S.D. |
2.82 |
13.69 |
1.92 |
10.90 |
RMSEPa |
0.367 |
0.184 |
0.126 |
0.142 |
|
aRMSEP is the root mean standard error of prediction |
Table 2: Assay results of aceclofenac and diclofenac in validation mixtures by the
proposed multivariate methods. |