Modified Electrode Linear range Detection Limit (µM) Reference
CPE/GNP/HRP 0.5–50  µM 0.2 [69]
ITO/APTMS /GNP /HRP 20.0 µM–8.0 mM 8.0 [70]
ITO/GNP/HRP 8.0 µM–3.0 mM 2.0 [71]
GDE/SSG/GNP/HRP 1.6 µM–3.2 mM 0.5 [72]
GCE/SF/GNP/HRP 10.0 µM–1.8 mM 5 [73]
GDE/MPA/CBU/GNP/HRP 0.4–0.9  µM 50 nM [74]
GDE/nano-TiO2/AuNWs/HRP 2.3 µM–2.4 mM 0.7 [75]
GDE/ATP/CaCO3–GNPs/HRP 0.5 µM–5.2 mM 0.1 [76]
GCE/MWCNTs/CHIT/HRP 16.7 µM–0.7 mM 10.3 [77]
GDE/MWCNTs/TTF–TCNQ/HRP 5.0 µM–1.1 mM 0.5 [78]
PDDA/MWNTs/HRP Up to 120 nM 1.5 nM [79]
MWNTs/organosilica@chitosan/HRP 0.7 µM–2.8 mM 0.3 [80]
GCE/ACS/MWCNTs/HRP 1.0 µM–0.5 mM 0.6 [81]
GCE/CHIT/GP/HRP 5.0 µM–5.3 mM 1.7 [82]
ITO/CHIT/GP-Fe3O4/HRP 5.0 µM–3.8 mM 0.6 [83]
GP/GNP/CdTe–CdS/GNP/HRP 0.1–12.0 nM 0.03 nM [84]
GCE/QDs/HRP 5.0 µM–0.1 mM 0.3 [85]
GDE/SNP/HRP 3.3 µM–9.4 mM 0.8 [86]
GDE/DNA/SNP/HRP 1.5 µM–2.0 mM 0.5 [87]
GDE/SNW/HRP 4.8 nM–0.31 µM 1.2 nM [88]
GCE/DSSD/HRP 0.7 µM–0.1 mM 50 nM [89]
TPA/SLGnP/HRP 0.6–16.8 µM 0.1 [90]
FTO/PANI/HRP up to 20 mM --- [92]
GCE/PANI/HRP 1.0 µM–2.0 mM 0.6 [93]
PANI/PNP/CHIT/GNP/HRP 7.0 µM–14.0 mM 2.8 [94]
Nano-PANI/GNP-PNP/CHIT/HRP 1.0 µM–2.2 mM 0.5 [95]
PPy/PNP/GNP/HRP 4.9 µM–4.8 mM 1.3 [97]
Pt/PPA/GNP/HRP 0.4 µM–1.5 mM 0.1 [99]
Au/PEDOT-PSS/HRP 0.2 µM–38.0 mM 0.1 [100]
GCE/PNM/HRP 0.2–1.4 µM 47.5 nM [101]
GDE/DNA/ BMITB/HRP 10.0 µM–7.4 mM 3.5 [102]
β-CD//ILs/ BMIMBF4/HRP 4.0–84.0 µM 2.7 [103]
GDE/4-CP/HRP 20.0 µM–20.0 mM 5.0 [105]
SGE/HRP 4.0 µM–0.1 mM 1.6 [108]
GCE/SHAP/HRP 1.0 µM–0.1 mM 0.4 [109]
PSPCE/HRP 5.9–35.4 µM 0.5 [110]
CPE: Carbon Paste Electrode; GNP: Gold Nano Particle; ITO: Indium Tin Oxide; GDE: Gold Electrode; SSG: Silica Sol-gel; SF: Silk Fibroin; MPA: Mercapto Propionic Acid; CBU: Cyclic Bisureas; AuNWs: Gold Nanowires; ATP: 4-aminothiophenol; APTMS, (3-aminopropyl) Trimethoxysilane; MWCNTs: Multi- Walled Carbon Nanotubes; CHIT: Chitosan; TTF–TCNQ: Tetrathiafulvalene– Tetracyanoquinodimethane; PDDA: Poly(dially dimethylammonium); ACS: Alumina-Coated Silica; GP: Graphene; QDs: Quantum Dots; SNP: Silver Nanoparticles; SNW: Silver Nanowire; DSSD: Dendritic Silver/Silicon Dioxide; TPA: Tetrasodium 1,3,6,8-Pyrenetetrasulfonic acid); SLGnP: Single-Layer Graphene Nanoplate; PANI: Polyaniline; FTO: F-doped Tin Oxide; PNP: Pt Nanoparticle; PPy, polypyrrole, Pt: Platinum; PPA: Poly 2,6-Pyridinediamine; PEDOT: Poly(3,4-ethylenedioxythiophene); PSS: Poly(styrene sulfonic acid); PNM: Poly (N-isopropylacyamide-co-3-methacryloxy-propyltrimethoxysilane); BMITB: 1-Butyl-3-Methylimidazolium Tetrafluoroborate; β-CD: β-cyclodextrin; ILs: Ionic Liquids; BMIMBF4: 1-Butyl-3-Methylimidazolium Tetrafluoroborate; 4-CP: 4-carboxyphenyl; SGE: Sonogel–Carbon Electrode; SHAP: Silica–Hydroxyapatite; PSPCE: Porous Screen-Printed Carbon Electrode
Table 2: Characteristics of the mediator-free HRP based H2O2 biosensor.