Principles of green chemistry* Biological CCU
P Prevent wastes. Recyclable bio-wastes.
R Renewable materials. Light/H2 as energy source and CO2/flue gas as carbon source.
O Omit derivatization steps. CO2 converted via integrated biochemical pathways.
D Degradable chemical products. Biodegradable products.
U Use safe synthetic methods. Use of non-pathogenic organisms.
C Catalytic reagents. Specialised enzymes, micro-compartments or organelles.
T Temperature, pressure ambient. Mild cultivation conditions.
I In-process monitoring. Process control for bioreactors or fermenters is available.
V Very few auxiliary substances. Other non-carbon nutrients derived from biomass.
E E-factor, maximize feed in product. Yield optimization via strain selection, genetic engineering and synthetic biology.
L Low toxicity of chemical products. Biocompatible products.
Y Yes it’s safe. Generally safe. Cautions in large-scale H2/O2/syngas utilization.
* Adapted from [126]
Table 5: Alignment of biological CCU with the principles of green chemistry.