Congener

Retention Time (min)

% Match Factor (simple)

SIM ion
(m/z)

Congener

Retention Time (min)

SIM ion
(m/z)

% Match Factor (simple)

2-Chlorobiphenyl

10.30

97

188

2,2',3,3',4-Pentachlorobiphenyl

18.18

326

98

3-Chlorobiphenyl

11.45

98

188

2,2',3,4,5'-Pentachlorobiphenyl

18.64

326

97

4-Chlorobiphenyl

11.57

96

188

2,2',4,4',5-Pentachlorobiphenyl

18.83

326

97

2,2'-Dichlorobiphenyl

12.07

99

222

2,3,3',4',6-Pentachlorobiphenyl

19.06

326

98

2,3'-Dichlorobiphenyl

12.79

100

222

2,2',3,4,4',5'-Hexachlorobiphenyl

19.20

360

96

2,4'-Dichorobiphenyl

13.06

100

222

2,2',3,4',5,5'-Hexachlorobiphenyl

19.68

360

96

2,5 -Dichlorobiphenyl

13.23

100

222

2,2',3,4',5,6-Hexachlorobiphenyl

19.82

360

87

2,2',3-Trichlorobiphenyl

13.69

99

256

2,2',3,3',4,5,6-Heptachlorobiphenyl

20.06

394

96

2,2',5-Trichlorobiphenyl

14.27

100

256

2,2',4,4',5,5'-Hexachlorobiphenyl

20.36

360

96

2,2',6-Trichlorobiphenyl

14.72

99

256

2,2',3,3',4,5,6'-Heptachlorobiphenyl

20.67

394

94

2,3,4'- Trichlorobiphenyl

15.26

99

256

2,2',3,3'4',5,6-Heptachlorobiphenyl

21.22

394

94

2,3',4-Trichlorobiphenyl

15.44

99

256

2,2',3,3',5,6,6'-Heptachlorobiphenyl

21.34

394

94

2,4,4'-Trichlorobiphenyl

15.82

99

256

2,2',3,4,4',5,5'-Heptachlorobiphenyl

21.60

394

94

2,2',3,5'-Tetrachlorobiphenyl

16.20

98

292

2,2',3,4',5,5',6-Heptachlorobiphenyl

21.93

394

97

2,2',5,5'-Tetrachlorobiphenyl

16.63

98

292

2,2',3,3',4,4'5,5'-Octachlorobiphenyl

22.89

430

94

2,3,3',4'-Tetrachlorobiphenyl

16.86

98

292

2,2',3,3',4,4'5,6-Octachlorobiphenyl

23.08

430

96

2,3',4,4'-Tetrachlorobiphenyl

17.23

98

292

2,2',3,3',4,5,5',6'-Octachlorobiphenyl

24.05

430

94

2,3',4,5-Tetrachlorobiphenyl

17.46

98

292

2,2',3,4,4',5,5',6-Octachlorobiphenyl

24.80

430

92

2,3',4',6-Tetrachlorobiphenyl

17.60

98

292

2,2',3,3'4,4',5,5'6-Nonachlorobiphenyl

26.25

464

89

2,4,4',5-Tetrachlorobiphenyl

17.94

97

 

 

 

 

 

Table 2: Retention times, AMDIS match factors and SIM ions