Validation parameters |
PCM |
DOM |
TMD |
Linear range (ηg per band) |
3250-19500 |
100-600 |
375-2250 |
LOD (ηg per band) |
64.30 |
9.95 |
5.51 |
LOQ (ηg per band) |
194.87 |
30.16 |
16.70 |
Accuracy (%) |
99.92 – 100.06 |
99.63 – 100.05 |
100.02 – 100.08 |
Repeatability of measurement of peak area (RSD %,n = 6) |
0.6859 |
0.69 |
0.9229 |
Repeatability of sample application (RSD%, n = 6) |
0.5823 |
0.78 |
0.2957 |
Precision (RSD %) |
Intraday (n = 3) |
0.5296 |
0.57 |
0.3335 |
Interday (n = 3) |
0.4783 |
0.48 |
0.7490 |
b= Limit of quantification
c=Relative standard deviation
n= number of determinations |
