| Sorbate |
γ ∞ |
–ΔH∞, kJ/mol |
–ΔS∞, J/(mol·K) |
HE, kJ/mol |
SE, J/(mol·K) |
GE, kJ/mol |
T=401 K |
| 2,6-lutidin |
1.76 |
18.0 |
49.3 |
16.5 |
36.8 |
2.0 |
| 2,5-lutidin |
1.36 |
22.8 |
59.3 |
15.5 |
36.3 |
1.1 |
| 2,4-lutidin |
1.38 |
22.0 |
57.3 |
14.4 |
33.6 |
1.1 |
| 2,3-lutidin |
1.37 |
21.6 |
56.3 |
16.1 |
37.8 |
1.1 |
| 3,5-lutidin |
1.23 |
26.2 |
66.8 |
13.2 |
31.3 |
0.7 |
| 3,4-lutidin |
1.14 |
30.3 |
76.4 |
10.3 |
24.7 |
0.4 |
| 2-пиколин |
1.29 |
21.3 |
55.3 |
12.4 |
29.0 |
0.8 |
| 3-пиколин |
1.15 |
20.0 |
51.0 |
14.5 |
35.0 |
0.5 |
| 4-пиколин |
1.09 |
23.1 |
58.2 |
10.6 |
25.6 |
0.3 |
T=413 K |
| 2,6-lutidin |
1.30 |
30.4 |
75.8 |
3.3 |
5.7 |
0.9 |
| 2,5-lutidin |
1.05 |
34.4 |
83.7 |
2.3 |
5.2 |
0.2 |
| 2,4-lutidin |
1.06 |
35.2 |
85.6 |
2.3 |
5.2 |
0.2 |
| 2,3-lutidin |
1.02 |
34.6 |
84.0 |
2.5 |
5.8 |
0.1 |
| 3,5-lutidin |
0.93 |
36.1 |
86.8 |
2.5 |
6.6 |
-0.2 |
| 3,4-lutidin |
0.88 |
38.9 |
93.0 |
0.3 |
1.9 |
-0.4 |
| 2-пиколин |
0.97 |
29.9 |
72.2 |
1.7 |
4.2 |
-0.1 |
| 3-пиколин |
0.88 |
31.7 |
75.6 |
1.9 |
5.7 |
-0.4 |
| 4-пиколин |
0.84 |
32.5 |
77.3 |
1.2 |
4.4 |
-0.6 |
|
