Sorbate |
γ ∞ |
–ΔH∞, kJ/mol |
–ΔS∞, J/(mol·K) |
HE, kJ/mol |
SE, J/(mol·K) |
GE, kJ/mol |
T=408 K |
2,6-lutidin |
2.04 |
23.9 |
64.5 |
10.3 |
19.2 |
2.4 |
2,5-lutidin |
1.52 |
27.4 |
70.5 |
10.0 |
21.0 |
1.4 |
2,4-lutidin |
1.64 |
26.9 |
70.0 |
9.2 |
18.4 |
1.7 |
2,3-lutidin |
1.55 |
27.1 |
70.1 |
10.4 |
21.8 |
1.5 |
3,5-lutidin |
1.43 |
28.5 |
72.6 |
11.3 |
24.8 |
1.2 |
3,4-lutidin |
1.36 |
30.1 |
76.2 |
11.2 |
25.1 |
1.0 |
2-picoline |
1.47 |
23.4 |
60.5 |
8.8 |
18.3 |
1.3 |
3-picoline |
1.33 |
25.2 |
64.2 |
9.0 |
19.5 |
1.0 |
4-picoline |
1.32 |
25.4 |
64.5 |
9.0 |
19.7 |
0.9 |
T=433.2 K |
2,6-lutidin |
1.56 |
31.4 |
77.1 |
1.2 |
-1.7 |
1.6 |
2,5-lutidin |
1.20 |
32.2 |
75.9 |
2.8 |
5.1 |
0.7 |
2,4-lutidin |
1.30 |
32.5 |
76.6 |
2.8 |
5.1 |
0.9 |
2,3-lutidin |
1.20 |
32.0 |
75.5 |
4.0 |
7.7 |
0.6 |
3,5-lutidin |
1.12 |
35.4 |
82.8 |
2.0 |
3.6 |
0.4 |
3,4-lutidin |
1.10 |
34.4 |
80.2 |
-1.2 |
-3.6 |
0.4 |
2-picoline |
1.18 |
31.9 |
75.0 |
-1.4 |
-4.6 |
0.6 |
3-picoline |
1.08 |
33.1 |
77.0 |
-0.6 |
-2.0 |
0.3 |
4-picoline |
1.08 |
32.0 |
74.6 |
0.7 |
0.9 |
0.3 |
|