(a): Super fine 20 min
Peak R. time Area%  Name of compound
1 6.912 1.51 Cyclooctasiloxane
2 8.86 1.44 Cyclohexasiloxane
3 10.469 0.54 Cyclononasiloxane
4 12.016 4.5 Pentadecanoic acid
5 13.328 0.23 Phenol
6 13.59 1.2 Chlorocyclopentane
7 14.597 13.83 Hexadecanoic acid, Palmitic acid, methyl ester
8 15.893 0.62 Phenol
9 15.988 0.49 Cyclononasiloxane, octadecamethyl, Octadeamethyl-cyclononasiloxane, Octadecamethylcyclon
10 16.225 3.09 Phthalic acid, diethyl ester
11 17.342 1.7 Octadecanoic acid, methyl ester
12 17.501 22.99 9-Octadecenoic acid, Methyl ester, Oleic acid
13 17.912 0.85 Linoleic acid,
14 18.915 1.58 Cyclononasiloxane
15 19.57 0.77 9,12-Octadecadienoic acid (Z,Z)-, methyl ester $$ Linoleic acid, methyl ester
16 20.381 2.09 Tetradecanoic acid $$ Myristic acid,
17 20.772 1.37 Cyclodecasiloxane, eicosamethyl, Icosamethylcyclodecasiloxane
18 23.765 2.1 Cyclooctasiloxane, Hexadecamethyl
19 28.306 37.7 Caffein
20 28.954 1.41 Cyclononasiloxane, octadecamethyl
(b): Superfine 40 min
Peak R. time Area% Name of compound
1 6.877 2.73 Cyclooctasiloxane, Hexadecamethyl-
2 8.843 1.44 Cyclohexasiloxane, dodecamethyl
3 9.746 0.19 Tridecanoic acid, methyl ester
4 10.444 0.72 Icosamethylcyclodecasiloxane
5 12.009 7.92 Methyl tetradecanoate, Myristic acid, methyl ester
6 13.554 1.01 Cyclononasiloxane, Octadecamethyl
7 14.588 23.87 Hexadecanoic acid, Methyl Ester
8 15.953 0.54 1H-Purin-6-amine, [(2-Fluorophenyl)methyl]
9 16.221 3.28 1,2-Benzenedicarboxylic acid, Diethyl ester, Phthalic acid
10 17.332 2.87 Octadecanoic acid; Methyl Ester; Stearic acid Methyl Ester
11 17.493 38.46 9-Octadecenoic acid, Oleic acid, methyl ester
12 18.88 1.52 1H-Purin-6-amine, [(2-Fluorophenyl)methyl]
13 19.569 1.5 Cyclopropanebutanoic acid
14 20.516 1.19 Hexadecanoic acid, (2-Phenyl-1,3-dioxolan-4-yl) methyl palmitate
15 20.723 2.05 1H-Purin-6-amine, [(2-Fluorophenyl)methyl]
16 22.657 1.03 Methyl behenate, n-Docosanoic acid methyl ester
17 23.682 1.98 1H-Purin-6-amine, [(2-Fluorophenyl)methyl]-
18 28.267 5.79 1H-Purine-2,6-dione, 3,7-dihydro-1,3,7-trimethyl-, Cafeina, Caffein, Caffine, Cafipel, Coffeine, Guaranine, Koffein
19 28.815 1.9 1H-Purin-6-amine, [(2-Fluorophenyl)methyl], Octadeamethyl-cyclononasiloxane
(c): Superfine 120 min
Peak R. time Area% Name of compound
1 6.913 1.48 Cyclooctasiloxane, hexadecamethyl-
2 8.881 1.26 Cyclononasiloxane, octadecamethyl-
3 9.758 0.21 Dodecanoic acid, methyl ester
4 10.494 0.57 Icosamethylcyclodecasiloxane
5 12.02 7.25 Tetradecanoic acid, Methyl ester
6 13.331 0.3 Phenol, 2-Methoxy-4-(2-Propenyl)
7 13.611 0.68 Cyclononasiloxane, Octadecamethyl
8 14.606 21.07 Palmitic Acid, Hexadecanoic acid, Methyl ester
9 15.896 0.46 Phenol, 2-methoxy-4-(1-propenyl
10 16.015 0.49 Cyclononasiloxane, Octadecamethyl.
11 16.229 3.63 Phthalic acid, diethyl ester
12 17.351 1.95 Octadecanoic acid, Stearic acid
13 17.508 34.92 Oleic acid, methyl ester, 9-Octadecenoic acid , methyl ester
14 17.918 2.6 Linoleic acid, methyl ester
15 18.939 1.34 Cyclononasiloxane, octadecamethyl-
16 19.582 1.59 9,12-Octadecadienoic acid, methyl ester
17 20.258 2.89 Tetradecanoic acid, Myristic acid
18 20.809 1.58 Cyclodecasiloxane, eicosamethyl-
19 23.813 1.62 Cyclononasiloxane, octadecamethyl-
20 28.282 12.55 Caffein
21 29.018 1.56 Cyclononasiloxane, octadecamethyl
Table 2: (a-c) Showing the identification and relative percentage of volatile compounds in superfine green tea at 90°C in 20, 40 and 120 minutes time of extraction.