| Compounds |
| Compound A |
Compound B |
Compound C |
Compound D |
Compound E |
| 1249 [M+Na]+ |
1087 [M+Na]+ |
925 [M+Na]+ |
1231.67 [M+Na]+ |
1069.33 [M+Na]+ |
| Aglycone |
Sugar Moiety |
Aglycone |
Sugar Moiety |
Aglycone |
Sugar Moiety |
Aglycone |
Sugar Moiety |
Aglycone |
Sugar Moiety |
| (ppm) |
(ppm) |
(ppm) |
(ppm) |
(ppm) |
(ppm) |
(ppm) |
(ppm) |
(ppm) |
(ppm) |
| 37.4 (C-1) |
100.9 (Glu'-1) |
37.2 (C-1) |
100.1 (Glu'-1) |
37.8 (C-1) |
102.3 (Glu'-1) |
37.0 (C-1) |
100.3 (Glu'-1) |
37.5 (C-1) |
99.9 (Glu'-1) |
| 30.5 (C-2) |
77.2 (Glu'-2) |
31.5 (C-2) |
77.3 (Glu'-2) |
30.2 (C-2) |
73.1 (Glu'-2) |
31.4 (C-2) |
81.5 (Glu'-2) |
30.1 (C-2) |
77.2 (Glu'-2) |
| 78.6 (C-3) |
77.0 (Glu'-3) |
71.7 (C-3) |
88.7 (Glu'-3) |
78.6 (C-3) |
73.5 (Glu'-3) |
71.6 (C-3) |
76.2 (Glu'-3) |
78.0 (C-3) |
77.7 (Glu'-3) |
| 38.8 (C-4) |
82.1 (Glu'-4) |
42.5 (C-4) |
69.9 (Glu'-4) |
39.9 (C-4) |
72.2 (Glu'-4) |
42.5 (C-4) |
78.6 (Glu'-4) |
38.9 (C-4) |
82.1 (Glu'-4) |
| 141.3 (C-5) |
78.4 (Glu'-5) |
140.2 (C-5) |
78.0 (Glu'-5) |
141.4 (C-5) |
74.6 (Glu'-5) |
140.5 (C-5) |
77.4 (Glu'-5) |
140.7 (C-5) |
76.2 (Glu'-5) |
| 122.5 (C-6) |
62.9 (Glu'-6) |
121.9 (C-6) |
62.1 (Glu'-6) |
121.5 (C-6) |
69.2 (Glu'-6) |
121.0 (C-6) |
61.6 (Glu'-6) |
121.8 (C-6) |
62.5 (Glu'-6) |
| 32.4 (C-7) |
102.0 (Rha'-1) |
32.1 (C-7) |
101.1 (Rha'-1) |
32.4 (C-7) |
105.2 (Glu''-1) |
32.0 (C-7) |
101.7 (Rha'-1) |
32.4 (C-7) |
101.8 (Rha'-1) |
| 30.9 (C-8) |
72.4 (Rha'-2) |
31.7 (C-8) |
72.0 (Rha'-2) |
31.2 (C-8) |
75.7 (Glu''-2) |
31.2 (C-8) |
72.8 (Rha'-2) |
31.4 (C-8) |
72.5 (Rha'-2) |
| 49.9 (C-9) |
72.1 (Rha'-3) |
49.5 (C-9) |
72.2 (Rha'-3) |
50.7 (C-9) |
78.5 (Glu''-3) |
50.3 (C-9) |
72.7 (Rha'-3) |
50.3 (C-9) |
72.7 (Rha'-3) |
| 37.5 (C-10) |
74.2 (Rha'-4) |
36.1 (C-10) |
73.5 (Rha'-4) |
37.2 (C-10) |
71.2 (Glu''-4) |
36.4 (C-10) |
74.1 (Rha'-4) |
37.1 (C-10) |
74.1 (Rha'-4) |
| 21.2 (C-11) |
69.6 (Rha'-5) |
20.5 (C-11) |
69.8 (Rha'-5) |
21.2 (C-11) |
78.3 (Glu''-5) |
20.7 (C-11) |
69.4 (Rha'-5) |
21.2 (C-11) |
69.5 (Rha'-5) |
| 40.8 (C-12) |
18.2 (Rha'-6) |
39.4 (C-12) |
18.8 (Rha'-6) |
40.9 (C-12) |
63.5 (Glu''-6) |
39.7 (C-12) |
18.9 (Rha'-6) |
39.6 (C-12) |
18.7 (Rha'-6) |
| 41.5 (C-13) |
105.7 (Glu''-1) |
41.9 (C-13) |
103.1 (Glu''-1) |
40.5 (C-13) |
100.3 (Rha'-1) |
40.0 (C-13) |
104.3 (Glu''-1) |
43.4 (C-13) |
104.9 (Glu''-1) |
| 56.8 (C-14) |
88.1 (Glu''-2) |
56.1 (C-14) |
74.0 (Glu''-2) |
56.7 (C-14) |
78.7 (Rha'-2) |
56.6 (C-14) |
73.5 (Glu''-2) |
54.9 (C-14) |
78.6 (Glu''-2) |
| 32.1 (C-15) |
74.6 (Glu''-3) |
31.2 (C-15) |
77.5 (Glu''-3) |
32.7 (C-15) |
78.9 (Rha'-3) |
31.6 (C-15) |
88.2 (Glu''-3) |
34.5 (C-15) |
71.7 (Glu''-3) |
| 81.2 (C-16) |
69.2 (Glu''-4) |
81.0 (C-16) |
71.9 (Glu''-4) |
81.4 (C-16) |
62.5 (Rha'-4) |
80.8 (C-16) |
69.7 (Glu''-4) |
84.4 (C-16) |
78.5 (Glu''-4) |
| 63.8 (C-17) |
78.9 (Glu''-5) |
62.5 (C-17) |
78.3 (Glu''-5) |
64.2 (C-17) |
79.1 (Rha'-5) |
62.3 (C-17) |
77.6 (Glu''-5) |
64.5 (C-17) |
62.8 (Glu''-5) |
| 16.7 (C-18) |
61.1 (Glu''-6) |
16.4 (C-18) |
60.3 (Glu''-6) |
16.8 (C-18) |
18.2 (Rha'-6) |
16.5 (C-18) |
61.8 (Glu''-6) |
14.1 (C-18) |
61.8 (Glu''-6) |
| 20.0 (C-19) |
105.2 (Glu'''-1) |
19.1 (C-19) |
100.2 (Glu'''-1) |
19.9 (C-19) |
|
19.7 (C-19) |
105.2 (Glu'''-1) |
19.4 (C-19) |
105.2 (Glu'''-1) |
| 40.9 (C-20) |
75.4 (Glu'''-2) |
41.4 (C-20) |
78.4 (Glu'''-2) |
41.5 (C-20) |
|
41.6 (C-20) |
75.4 (Glu'''-2) |
104.9 (C-20) |
75.0 (Glu'''-2) |
| 16.6 (C-21) |
78.3 (Glu'''-3) |
14.8 (C-21) |
91.3 (Glu'''-3) |
16.2 (C-21) |
|
14.3 (C-21) |
78.3 (Glu'''-3) |
11.8 (C-21) |
78.6 (Glu'''-3) |
| 110.7 (C-22) |
71.1 (Glu'''-4) |
108.9 (C-22) |
69.2 (Glu'''-4) |
110.7 (C-22) |
|
109.3 (C-22) |
71.8 (Glu'''-4) |
152.5 (C-22) |
71.2 (Glu'''-4) |
| 36.8 (C-23) |
62.3 (Glu'''-5) |
31.3 (C-23) |
62.6 (Glu'''-5) |
37.1 (C-23) |
|
31.6 (C-23) |
78.4 (Glu'''-5) |
23.7 (C-23) |
78.5 (Glu'''-5) |
| 28.5 (C-24) |
78.5 (Glu'''-6) |
28.4 (C-24) |
61.7 (Glu'''-6) |
28.4 (C-24) |
|
28.6 (C-24) |
63.3 (Glu'''-6) |
31.4 (C-24) |
61.9 (Glu'''-6) |
| 34.7 (C-25) |
105 (Glu''''-1) |
30.1 (C-25) |
|
34.1 (C-25) |
|
30.1 (C-25) |
106.3 (Glu''''-1) |
33.5 (C-25) |
|
| 75.6 (C-26) |
75.1 (Glu''''-2) |
66.9 (C-26) |
|
75.2 (C-26) |
|
66.8 (C-26) |
75.7 (Glu''''-2) |
74.9 (C-26) |
|
| 17.8 (C-27) |
78.2 (Glu''''-3) |
18.4 (C-27) |
|
17.8 (C-27) |
|
17.2 (C-27) |
78.6 (Glu''''-3) |
17.3 (C-27) |
|
| 71.7 (Glu''''-4) |
71.9 (Glu''''-4) |
| 78.4 (Glu''''-5) |
78.7 (Glu''''-5) |
| 62.4 (Glu''''-6) |
62.6 (Glu''''-6) |
|
