Compounds 
Compound A 
Compound B 
Compound C 
Compound D 
Compound E 
1249 [M+Na]+ 
1087 [M+Na]+ 
925 [M+Na]+ 
1231.67 [M+Na]+ 
1069.33 [M+Na]+ 
Aglycone 
Sugar Moiety 
Aglycone 
Sugar Moiety 
Aglycone 
Sugar Moiety 
Aglycone 
Sugar Moiety 
Aglycone 
Sugar Moiety 
(ppm) 
(ppm) 
(ppm) 
(ppm) 
(ppm) 
(ppm) 
(ppm) 
(ppm) 
(ppm) 
(ppm) 
37.4 (C1) 
100.9 (Glu'1) 
37.2 (C1) 
100.1 (Glu'1) 
37.8 (C1) 
102.3 (Glu'1) 
37.0 (C1) 
100.3 (Glu'1) 
37.5 (C1) 
99.9 (Glu'1) 
30.5 (C2) 
77.2 (Glu'2) 
31.5 (C2) 
77.3 (Glu'2) 
30.2 (C2) 
73.1 (Glu'2) 
31.4 (C2) 
81.5 (Glu'2) 
30.1 (C2) 
77.2 (Glu'2) 
78.6 (C3) 
77.0 (Glu'3) 
71.7 (C3) 
88.7 (Glu'3) 
78.6 (C3) 
73.5 (Glu'3) 
71.6 (C3) 
76.2 (Glu'3) 
78.0 (C3) 
77.7 (Glu'3) 
38.8 (C4) 
82.1 (Glu'4) 
42.5 (C4) 
69.9 (Glu'4) 
39.9 (C4) 
72.2 (Glu'4) 
42.5 (C4) 
78.6 (Glu'4) 
38.9 (C4) 
82.1 (Glu'4) 
141.3 (C5) 
78.4 (Glu'5) 
140.2 (C5) 
78.0 (Glu'5) 
141.4 (C5) 
74.6 (Glu'5) 
140.5 (C5) 
77.4 (Glu'5) 
140.7 (C5) 
76.2 (Glu'5) 
122.5 (C6) 
62.9 (Glu'6) 
121.9 (C6) 
62.1 (Glu'6) 
121.5 (C6) 
69.2 (Glu'6) 
121.0 (C6) 
61.6 (Glu'6) 
121.8 (C6) 
62.5 (Glu'6) 
32.4 (C7) 
102.0 (Rha'1) 
32.1 (C7) 
101.1 (Rha'1) 
32.4 (C7) 
105.2 (Glu''1) 
32.0 (C7) 
101.7 (Rha'1) 
32.4 (C7) 
101.8 (Rha'1) 
30.9 (C8) 
72.4 (Rha'2) 
31.7 (C8) 
72.0 (Rha'2) 
31.2 (C8) 
75.7 (Glu''2) 
31.2 (C8) 
72.8 (Rha'2) 
31.4 (C8) 
72.5 (Rha'2) 
49.9 (C9) 
72.1 (Rha'3) 
49.5 (C9) 
72.2 (Rha'3) 
50.7 (C9) 
78.5 (Glu''3) 
50.3 (C9) 
72.7 (Rha'3) 
50.3 (C9) 
72.7 (Rha'3) 
37.5 (C10) 
74.2 (Rha'4) 
36.1 (C10) 
73.5 (Rha'4) 
37.2 (C10) 
71.2 (Glu''4) 
36.4 (C10) 
74.1 (Rha'4) 
37.1 (C10) 
74.1 (Rha'4) 
21.2 (C11) 
69.6 (Rha'5) 
20.5 (C11) 
69.8 (Rha'5) 
21.2 (C11) 
78.3 (Glu''5) 
20.7 (C11) 
69.4 (Rha'5) 
21.2 (C11) 
69.5 (Rha'5) 
40.8 (C12) 
18.2 (Rha'6) 
39.4 (C12) 
18.8 (Rha'6) 
40.9 (C12) 
63.5 (Glu''6) 
39.7 (C12) 
18.9 (Rha'6) 
39.6 (C12) 
18.7 (Rha'6) 
41.5 (C13) 
105.7 (Glu''1) 
41.9 (C13) 
103.1 (Glu''1) 
40.5 (C13) 
100.3 (Rha'1) 
40.0 (C13) 
104.3 (Glu''1) 
43.4 (C13) 
104.9 (Glu''1) 
56.8 (C14) 
88.1 (Glu''2) 
56.1 (C14) 
74.0 (Glu''2) 
56.7 (C14) 
78.7 (Rha'2) 
56.6 (C14) 
73.5 (Glu''2) 
54.9 (C14) 
78.6 (Glu''2) 
32.1 (C15) 
74.6 (Glu''3) 
31.2 (C15) 
77.5 (Glu''3) 
32.7 (C15) 
78.9 (Rha'3) 
31.6 (C15) 
88.2 (Glu''3) 
34.5 (C15) 
71.7 (Glu''3) 
81.2 (C16) 
69.2 (Glu''4) 
81.0 (C16) 
71.9 (Glu''4) 
81.4 (C16) 
62.5 (Rha'4) 
80.8 (C16) 
69.7 (Glu''4) 
84.4 (C16) 
78.5 (Glu''4) 
63.8 (C17) 
78.9 (Glu''5) 
62.5 (C17) 
78.3 (Glu''5) 
64.2 (C17) 
79.1 (Rha'5) 
62.3 (C17) 
77.6 (Glu''5) 
64.5 (C17) 
62.8 (Glu''5) 
16.7 (C18) 
61.1 (Glu''6) 
16.4 (C18) 
60.3 (Glu''6) 
16.8 (C18) 
18.2 (Rha'6) 
16.5 (C18) 
61.8 (Glu''6) 
14.1 (C18) 
61.8 (Glu''6) 
20.0 (C19) 
105.2 (Glu'''1) 
19.1 (C19) 
100.2 (Glu'''1) 
19.9 (C19) 

19.7 (C19) 
105.2 (Glu'''1) 
19.4 (C19) 
105.2 (Glu'''1) 
40.9 (C20) 
75.4 (Glu'''2) 
41.4 (C20) 
78.4 (Glu'''2) 
41.5 (C20) 

41.6 (C20) 
75.4 (Glu'''2) 
104.9 (C20) 
75.0 (Glu'''2) 
16.6 (C21) 
78.3 (Glu'''3) 
14.8 (C21) 
91.3 (Glu'''3) 
16.2 (C21) 

14.3 (C21) 
78.3 (Glu'''3) 
11.8 (C21) 
78.6 (Glu'''3) 
110.7 (C22) 
71.1 (Glu'''4) 
108.9 (C22) 
69.2 (Glu'''4) 
110.7 (C22) 

109.3 (C22) 
71.8 (Glu'''4) 
152.5 (C22) 
71.2 (Glu'''4) 
36.8 (C23) 
62.3 (Glu'''5) 
31.3 (C23) 
62.6 (Glu'''5) 
37.1 (C23) 

31.6 (C23) 
78.4 (Glu'''5) 
23.7 (C23) 
78.5 (Glu'''5) 
28.5 (C24) 
78.5 (Glu'''6) 
28.4 (C24) 
61.7 (Glu'''6) 
28.4 (C24) 

28.6 (C24) 
63.3 (Glu'''6) 
31.4 (C24) 
61.9 (Glu'''6) 
34.7 (C25) 
105 (Glu''''1) 
30.1 (C25) 

34.1 (C25) 

30.1 (C25) 
106.3 (Glu''''1) 
33.5 (C25) 

75.6 (C26) 
75.1 (Glu''''2) 
66.9 (C26) 

75.2 (C26) 

66.8 (C26) 
75.7 (Glu''''2) 
74.9 (C26) 

17.8 (C27) 
78.2 (Glu''''3) 
18.4 (C27) 

17.8 (C27) 

17.2 (C27) 
78.6 (Glu''''3) 
17.3 (C27) 

71.7 (Glu''''4) 
71.9 (Glu''''4) 
78.4 (Glu''''5) 
78.7 (Glu''''5) 
62.4 (Glu''''6) 
62.6 (Glu''''6) 
