Process |
Symbol |
Relationa |
Overall |
|
|
M2+ + Lo + 2A- MLA2,o |
Kex |
Log Kex = -2fΔfex0¢ |
M2+ + Lo + 2A- MLA+o + A-o |
Kex± |
Log Kex± = f(Δfeq - Δfex±0¢) |
M2+ + Lo + 2A- ML2+o + 2A-o |
Kex2± |
Log Kex2± = 2f(Δfeq - Δfex2±0¢) |
Component |
|
|
M2+ M2+o |
KD,M |
Log KD,M = 2f(Δfeq - ΔfM0¢) |
ML2+ ML2+o |
KD,ML |
Log KD,ML = 2f(Δfeq - ΔfML0¢) |
A- A-o |
KD,A |
Log KD,A = -f(Δfeq - ΔfA0¢) |
M2+o + Lo ML2+o |
KML.org |
Log KML.org = -2fΔfML.org0¢ |
M2+ + LML2+ |
KML |
Log KML = -2fΔfML.w0¢b |
LLo |
KD,L |
Log KD,L= -fΔfL0¢ |
ML2+o + A-o MLA+o |
K1,org |
Log K1,org = -fΔf1,org0¢ |
MLA+o + A-o MLA2,o |
K2,org |
Log K2,org = -fΔf2,org0¢ |
ML2+o + 2A-o MLA2,o |
bip,orgc |
Log bip,org = -2fΔfip,org0¢ |
af = F/2.3RT. Hence, 1/f = 0.05916 V at 298 K. bΔφML.w
0′ shows a standard formal
potential for the ML2+ formation in the w phase. cβip,org = K1,org K2,org. Accordingly,
the relation of 2Δφip,org
0′ = Δφ1,org
0′ + Δφ2,org
0′ holds |