L |
M |
Dφeq/Va |
log Kex±S |
log Kex2±S |
Foundb |
Calcdc |
Foundd |
Calcde |
18C6 |
Ca |
0.088 |
3.96 |
3.96 |
-0.5 |
-3.46 |
|
Sr |
0.061 |
5.89 |
5.93 |
1.6 |
-0.42 |
|
Ba |
0.044 |
6.61 |
6.89 |
2.4 |
1.21 |
B18C6 |
Ca |
0.12 |
0.75 |
0.78 |
-2.3 |
-6.20 |
|
Sr |
0.082 |
2.95 |
2.99 |
-0.4 |
-3.14 |
|
Ba |
0.072 |
3.79 |
4.07 |
0.6 |
-1.56 |
aEssentially based on Δφ/V versus Ph4As+BPh4
− electrode. bCalculated from the
relation of log Kex± = f(φeq − Δφex±
0′) in Table 1. cCalculated from the relation of
Δφex±
0′ = 2(ΔφM
0′ − ΔφA
0′ + ΔφML,org
0′) + Δφ1,org
0′ + Δφeq in Table 2. dCalculated from the
thermodynamic cycle, log Kex2± = log KD,M
S + 2log KD,Pic
S + log KML,NB. See ref. [8].
eCalculated from the relation of Δφex2±
0′ = ΔφM
0′ − ΔφA
0′ + ΔφML,org
0′ + Δφeq in Table 2 |