Mass Loss Regime 1 Mass Loss Regime 2  
Eqn. No. Onset Temp 1 Endset Temp 1 Ea A R2 Fraction Sample Mass Loss Onset Temp 2 Endset Temp 2 Ea A R2 Fraction Sample Mass Loss Total Mass Fraction in E Calc
  (K) (K) (kJ/mol) (s-1)     (K) (K) (kJ/mol) (s-1)      
Feed Corn                                
D1 403 500 85.0 ± 0.6 7.40E+00 0.9983 0.036 703 838 9.1 ± 0.1 4.41E-06 0.9952 0.27 0.31
D2 403 500 85.8 ± 0.6 4.51E+00 0.9981 0.036 703 838 16.7 ± 0.04 9.14E+04 0.9998 0.27 0.31
D3 403 500 86.5 ± 0.6 1.22E+00 0.9978 0.036 703 838 28.7 ± 0.2 2.62E-05 0.9979 0.27 0.31
D4 403 500 86.0 ± 0.6 1.07E+00 0.9980 0.036 703 838 20.6 ± 0.1 5.25E-06 0.9996 0.27 0.31
D5 403 500 86.5 ± 0.6 1.22E+00 0.9978 0.036 703 838 28.7 ± 0.2 2.62E-05 0.9979 0.27 0.31
P1 423 553 40.0 ± 0.3 1.50E-03 0.9984 0.16 709 835 4.9 ± 0.0 2.01E-06 0.9983 0.26 0.42
P2 423 553 40.2 ± 0.3 1.05E-03 0.9983 0.16 709 835 7.8 ± 0.1 2.37E-06 0.9965 0.26 0.42
N1 418 553 61.7 ± 0.4 1.21E-01 0.9987 0.16 709 790 4.4 ± 0.1 2.39E-06 0.9903 0.16 0.32
N2 425 546 15.2 ± 0.1 3.38E-05 0.9991 0.12 632 899 -7.5 ± 0.05 4.62E-07 0.9967 0.42 0.54
N3 425 546 7.5 ± 0.04 8.74E-06 0.9988 0.12 632 899 -9.2 ± 0.05 3.68E-07 0.9980 0.42 0.54
N4 425 546 3.6 ± 0.03 4.44E-06 0.9982 0.12 632 899 -10.0 ± 0.05 3.28E-07 0.9983 0.42 0.54
N5 393 542 19.2 ± 0.3 1.17E-07 0.9812 0.12 632 866 45.3 ± 0.8 3.06E-10 0.9683 0.38 0.50
N6 393 542 14.1 ± 0.2 2.60E-05 0.9884 0.12 632 866 -0.1 ± 0.2 2.17E-06 0.0010 0.38 0.50
N7 393 542 6.8 ± 0.1 7.51E-06 0.9824 0.12 632 866 -4.1 ± 0.1 1.05E-06 0.9419 0.38 0.50
N8 393 542 34.0 ± 0.9 4.40E-04 0.8546 0.12 632 866 30.5 ± 0.1 2.74E-04 0.9970 0.38 0.50
50:50 Blend                                 
D1 430 579 83.6 ± 0.4 2.49E+00 0.9978 0.17 629 1019 15.5 ± 0.1 4.96E-06 0.9941 0.56 0.73
D2 430 579 84.3 ± 0.5 1.49E+00 0.9976 0.17 629 1019 20.5 ± 0.1 6.89E-06 0.9954 0.56 0.73
D3 430 579 85.0 ± 0.5 3.99E-01 0.9973 0.17 629 1019 27.1 ± 0.2 5.58E-06 0.9878 0.56 0.73
D4 430 579 84.5 ± 0.5 3.53E-01 0.9975 0.17 629 1019 22.7 ± 0.1 2.34E-06 0.9936 0.56 0.73
D5 430 579 85.0 ± 0.5 3.99E-01 0.9973 0.17 629 1019 27.1 ± 0.2 5.58E-06 0.9878 0.56 0.73
P1 439 611 39.5 ± 0.2 9.37E-04 0.9965 0.27 690 1021 5.9 ± 0.03 1.28E-06 0.9960 0.49 0.76
P2 439 611 39.8 ± 0.2 6.74E-04 0.9962 0.27 690 1021 7.9 ± 0.04 1.23E-06 0.9943 0.49 0.76
N1 414 596 62.4 ± 0.3 8.19E-02 0.9969 0.23 621 1055 8.0 ± 0.1 2.13E-06 0.9780 0.62 0.85
N2 414 596 15.3 ± 0.1 2.89E-05 0.9946 0.23 621 1055 -6.3 ± 0.1 4.43E-07 0.9781 0.62 0.85
N3 414 596 7.4 ± 0.1 7.68E-06 0.9896 0.23 621 1055 -8.7 ± 0.1 3.41E-07 0.9887 0.62 0.85
N4 414 596 3.5 ± 0.1 3.96E-06 0.9718 0.23 621 1055 -9.9 ± 0.1 2.99E-07 0.9913 0.62 0.85
N5 414 596 22.8 ± 0.3 5.12E-08 0.9781 0.23 621 1055 44.6 ± 0.7 8.82E-10 0.9460 0.62 0.85
N6 414 596 15.9 ± 0.1 3.38E-05 0.9938 0.23 621 1055 -1.2 ± 0.1 1.20E-06 0.6907 0.62 0.85
N7 414 596 7.8 ± 0.1 8.52E-06 0.9894 0.23 621 1055 -5.3 ± 0.02 6.61E-07 0.9976 0.62 0.85
N8 414 596 100.1 ± 3.3 4.36E-11 0.6532 0.23 621 1055 53.8 ± 1.5 1.29E-03 0.8786 0.62 0.85
80:20 Blend                                
D1 439 558 80.5 ± 0.5 1.19E+00 0.9969 0.10 562 976 31.1 ± 0.2 4.13E-05 0.9918 0.72 0.83
D2 439 558 81.0 ± 0.6 6.92E-01 0.9968 0.10 562 976 35.6 ± 0.1 5.15E-05 0.9964 0.72 0.83
D3 439 558 81.6 ± 0.6 1.78E-01 0.9966 0.10 562 976 40.9 ± 0.2 3.40E-05 0.9967 0.72 0.83
D4 439 558 81.2 ± 0.6 1.61E-01 0.9967 0.10 562 976 37.3 ± 0.1 1.64E-05 0.9971 0.72 0.83
D5 439 558 81.6 ± 0.6 1.78E-01 0.9966 0.10 562 976 40.9 ± 0.2 3.40E-05 0.9967 0.72 0.83
P1 439 571 36.8 ± 0.2 4.86E-04 0.9968 0.13 591 990 12.9 ± 0.1 3.20E-06 0.9919 0.70 0.82
P2 439 571 36.9 ± 0.3 3.30E-04 0.9961 0.13 591 990 14.4 ± 0.1 2.89E-06 0.9946 0.70 0.82
N1 435 547 57.4 ± 0.4 2.49E-02 0.9967 0.084 600 997 19.2 ± 0.2 9.68E-06 0.9782 0.70 0.78
N2 435 547 13.7 ± 0.1 1.99E-05 0.9942 0.084 600 997 -2.2 ± 0.1 7.80E-07 0.6890 0.70 0.78
N3 435 547 6.4 ± 0.1 6.07E-06 0.9889 0.084 600 997 -5.7 ± 0.1 5.12E-07 0.9556 0.70 0.78
N4 435 547 2.8 ± 0.1 3.35E-06 0.9670 0.084 600 997 -7.5 ± 0.1 4.15E-07 0.9779 0.70 0.78
N5 435 547 20.5 ± 0.2 9.66E-08 0.9924 0.084 600 997 44.4 ± 0.6 1.05E-09 0.9629 0.70 0.78
N6 435 547 14.1 ± 0.1 2.19E-05 0.9938 0.084 600 997 2.6 ± 0.03 1.96E-06 0.9667 0.70 0.78
N7 435 547 6.7 ± 0.1 6.47E-06 0.9884 0.084 600 997 2.6 ± 0.02 9.47E-07 0.9806 0.70 0.78
N8 435 547 75.3 ± 3.3 2.17E-02 0.7904 0.084 600 997 69.4 ± 2.4 1.06E-02 0.8792 0.70 0.78
Ill. No. 6 Coal                                
D1 453 565 49.5 ± 0.5 1.27E-04 0.9972 0.026 568 867 64.1 ± 0.2 2.85E-03 0.9993 0.47 0.49
D2 453 565 49.6 ± 0.5 6.62E-05 0.9972 0.026 568 867 66.8 ± 0.2 2.41E-03 0.9996 0.47 0.49
D3 453 565 49.8 ± 0.5 1.54E-05 0.9973 0.026 568 867 69.6 ± 0.1 9.43E-04 0.9996 0.47 0.49
D4 453 565 49.7 ± 0.5 1.49E-05 0.9972 0.026 568 867 67.7 ± 0.1 6.47E-04 0.9996 0.47 0.49
D5 453 565 49.8 ± 0.5 1.54E-05 0.9973 0.026 568 867 69.6 ± 0.1 9.43E-04 0.9996 0.47 0.49
P1 432 509 27.2 ± 0.4 2.15E-05 0.9958 0.013 585 867 28.3 ± 0.1 2.09E-05 0.9992 0.46 0.47
P2 432 509 27.2 ± 0.4 1.44E-05 0.9958 0.013 585 867 29.0 ± 0.1 1.61E-05 0.9994 0.46 0.47
N1 429 581 38.3 ± 0.4 6.84E-05 0.9942 0.037 583 808   ±     0.0000   0.04
N2 429 581 7.2 ± 0.2 2.71E-06 0.9771 0.037 583 808 46.5 ± 0.1 3.60E-04 0.9998 0.33 0.37
N3 429 581 2.1 ± 0.1 1.58E-06 0.8733 0.037 583 808 7.9 ± 0.0 3.08E-06 0.9992 0.33 0.37
N4 429 581 -0.5 ± 0.1 1.21E-06 0.4891 0.037 583 808 -1.8 ± 0.0 9.36E-07 0.9801 0.33 0.37
N5 406 681 17.7 ± 0.1 2.27E-07 0.9899 0.12 683 1052 50.5 ± 0.4 7.70E-10 0.9892 0.68 0.80
N6 429 581 7.4 ± 0.2 2.80E-06 0.9784 0.037 583 808 9.6 ± 0.0 4.34E-06 0.9989 0.33 0.37
N7 429 581 2.1 ± 0.1 1.62E-06 0.8834 0.037 583 808 2.6 ± 0.0 1.75E-06 0.9975 0.33 0.37
N8 406 681 56.7 ± 1.1 8.30E-04 0.9529 0.12 683 1052 71.0 ± 1.8 4.96E-03 0.9391 0.68 0.80
Table 4: Solid State Reaction methods applied to pure fuels and blends at 100K/min, Ea presented with 95% confidence interval