Mass Loss Regime 1
Mass Loss Regime 2
Eqn. No.
Onset Temp 1
Endset Temp 1
E
a
A
R
2
Fraction Sample Mass Loss
Onset Temp 2
Endset Temp 2
E
a
A
R
2
Fraction Sample Mass Loss
Total Mass Fraction in E Calc
(K)
(K)
(kJ/mol)
(s
-1
)
(K)
(K)
(kJ/mol)
(s
-1
)
Feed Corn
D1
403
500
85.0
±
0.6
7.40E+00
0.9983
0.036
703
838
9.1
±
0.1
4.41E-06
0.9952
0.27
0.31
D2
403
500
85.8
±
0.6
4.51E+00
0.9981
0.036
703
838
16.7
±
0.04
9.14E+04
0.9998
0.27
0.31
D3
403
500
86.5
±
0.6
1.22E+00
0.9978
0.036
703
838
28.7
±
0.2
2.62E-05
0.9979
0.27
0.31
D4
403
500
86.0
±
0.6
1.07E+00
0.9980
0.036
703
838
20.6
±
0.1
5.25E-06
0.9996
0.27
0.31
D5
403
500
86.5
±
0.6
1.22E+00
0.9978
0.036
703
838
28.7
±
0.2
2.62E-05
0.9979
0.27
0.31
P1
423
553
40.0
±
0.3
1.50E-03
0.9984
0.16
709
835
4.9
±
0.0
2.01E-06
0.9983
0.26
0.42
P2
423
553
40.2
±
0.3
1.05E-03
0.9983
0.16
709
835
7.8
±
0.1
2.37E-06
0.9965
0.26
0.42
N1
418
553
61.7
±
0.4
1.21E-01
0.9987
0.16
709
790
4.4
±
0.1
2.39E-06
0.9903
0.16
0.32
N2
425
546
15.2
±
0.1
3.38E-05
0.9991
0.12
632
899
-7.5
±
0.05
4.62E-07
0.9967
0.42
0.54
N3
425
546
7.5
±
0.04
8.74E-06
0.9988
0.12
632
899
-9.2
±
0.05
3.68E-07
0.9980
0.42
0.54
N4
425
546
3.6
±
0.03
4.44E-06
0.9982
0.12
632
899
-10.0
±
0.05
3.28E-07
0.9983
0.42
0.54
N5
393
542
19.2
±
0.3
1.17E-07
0.9812
0.12
632
866
45.3
±
0.8
3.06E-10
0.9683
0.38
0.50
N6
393
542
14.1
±
0.2
2.60E-05
0.9884
0.12
632
866
-0.1
±
0.2
2.17E-06
0.0010
0.38
0.50
N7
393
542
6.8
±
0.1
7.51E-06
0.9824
0.12
632
866
-4.1
±
0.1
1.05E-06
0.9419
0.38
0.50
N8
393
542
34.0
±
0.9
4.40E-04
0.8546
0.12
632
866
30.5
±
0.1
2.74E-04
0.9970
0.38
0.50
50:50 Blend
D1
430
579
83.6
±
0.4
2.49E+00
0.9978
0.17
629
1019
15.5
±
0.1
4.96E-06
0.9941
0.56
0.73
D2
430
579
84.3
±
0.5
1.49E+00
0.9976
0.17
629
1019
20.5
±
0.1
6.89E-06
0.9954
0.56
0.73
D3
430
579
85.0
±
0.5
3.99E-01
0.9973
0.17
629
1019
27.1
±
0.2
5.58E-06
0.9878
0.56
0.73
D4
430
579
84.5
±
0.5
3.53E-01
0.9975
0.17
629
1019
22.7
±
0.1
2.34E-06
0.9936
0.56
0.73
D5
430
579
85.0
±
0.5
3.99E-01
0.9973
0.17
629
1019
27.1
±
0.2
5.58E-06
0.9878
0.56
0.73
P1
439
611
39.5
±
0.2
9.37E-04
0.9965
0.27
690
1021
5.9
±
0.03
1.28E-06
0.9960
0.49
0.76
P2
439
611
39.8
±
0.2
6.74E-04
0.9962
0.27
690
1021
7.9
±
0.04
1.23E-06
0.9943
0.49
0.76
N1
414
596
62.4
±
0.3
8.19E-02
0.9969
0.23
621
1055
8.0
±
0.1
2.13E-06
0.9780
0.62
0.85
N2
414
596
15.3
±
0.1
2.89E-05
0.9946
0.23
621
1055
-6.3
±
0.1
4.43E-07
0.9781
0.62
0.85
N3
414
596
7.4
±
0.1
7.68E-06
0.9896
0.23
621
1055
-8.7
±
0.1
3.41E-07
0.9887
0.62
0.85
N4
414
596
3.5
±
0.1
3.96E-06
0.9718
0.23
621
1055
-9.9
±
0.1
2.99E-07
0.9913
0.62
0.85
N5
414
596
22.8
±
0.3
5.12E-08
0.9781
0.23
621
1055
44.6
±
0.7
8.82E-10
0.9460
0.62
0.85
N6
414
596
15.9
±
0.1
3.38E-05
0.9938
0.23
621
1055
-1.2
±
0.1
1.20E-06
0.6907
0.62
0.85
N7
414
596
7.8
±
0.1
8.52E-06
0.9894
0.23
621
1055
-5.3
±
0.02
6.61E-07
0.9976
0.62
0.85
N8
414
596
100.1
±
3.3
4.36E-11
0.6532
0.23
621
1055
53.8
±
1.5
1.29E-03
0.8786
0.62
0.85
80:20 Blend
D1
439
558
80.5
±
0.5
1.19E+00
0.9969
0.10
562
976
31.1
±
0.2
4.13E-05
0.9918
0.72
0.83
D2
439
558
81.0
±
0.6
6.92E-01
0.9968
0.10
562
976
35.6
±
0.1
5.15E-05
0.9964
0.72
0.83
D3
439
558
81.6
±
0.6
1.78E-01
0.9966
0.10
562
976
40.9
±
0.2
3.40E-05
0.9967
0.72
0.83
D4
439
558
81.2
±
0.6
1.61E-01
0.9967
0.10
562
976
37.3
±
0.1
1.64E-05
0.9971
0.72
0.83
D5
439
558
81.6
±
0.6
1.78E-01
0.9966
0.10
562
976
40.9
±
0.2
3.40E-05
0.9967
0.72
0.83
P1
439
571
36.8
±
0.2
4.86E-04
0.9968
0.13
591
990
12.9
±
0.1
3.20E-06
0.9919
0.70
0.82
P2
439
571
36.9
±
0.3
3.30E-04
0.9961
0.13
591
990
14.4
±
0.1
2.89E-06
0.9946
0.70
0.82
N1
435
547
57.4
±
0.4
2.49E-02
0.9967
0.084
600
997
19.2
±
0.2
9.68E-06
0.9782
0.70
0.78
N2
435
547
13.7
±
0.1
1.99E-05
0.9942
0.084
600
997
-2.2
±
0.1
7.80E-07
0.6890
0.70
0.78
N3
435
547
6.4
±
0.1
6.07E-06
0.9889
0.084
600
997
-5.7
±
0.1
5.12E-07
0.9556
0.70
0.78
N4
435
547
2.8
±
0.1
3.35E-06
0.9670
0.084
600
997
-7.5
±
0.1
4.15E-07
0.9779
0.70
0.78
N5
435
547
20.5
±
0.2
9.66E-08
0.9924
0.084
600
997
44.4
±
0.6
1.05E-09
0.9629
0.70
0.78
N6
435
547
14.1
±
0.1
2.19E-05
0.9938
0.084
600
997
2.6
±
0.03
1.96E-06
0.9667
0.70
0.78
N7
435
547
6.7
±
0.1
6.47E-06
0.9884
0.084
600
997
2.6
±
0.02
9.47E-07
0.9806
0.70
0.78
N8
435
547
75.3
±
3.3
2.17E-02
0.7904
0.084
600
997
69.4
±
2.4
1.06E-02
0.8792
0.70
0.78
Ill. No. 6 Coal
D1
453
565
49.5
±
0.5
1.27E-04
0.9972
0.026
568
867
64.1
±
0.2
2.85E-03
0.9993
0.47
0.49
D2
453
565
49.6
±
0.5
6.62E-05
0.9972
0.026
568
867
66.8
±
0.2
2.41E-03
0.9996
0.47
0.49
D3
453
565
49.8
±
0.5
1.54E-05
0.9973
0.026
568
867
69.6
±
0.1
9.43E-04
0.9996
0.47
0.49
D4
453
565
49.7
±
0.5
1.49E-05
0.9972
0.026
568
867
67.7
±
0.1
6.47E-04
0.9996
0.47
0.49
D5
453
565
49.8
±
0.5
1.54E-05
0.9973
0.026
568
867
69.6
±
0.1
9.43E-04
0.9996
0.47
0.49
P1
432
509
27.2
±
0.4
2.15E-05
0.9958
0.013
585
867
28.3
±
0.1
2.09E-05
0.9992
0.46
0.47
P2
432
509
27.2
±
0.4
1.44E-05
0.9958
0.013
585
867
29.0
±
0.1
1.61E-05
0.9994
0.46
0.47
N1
429
581
38.3
±
0.4
6.84E-05
0.9942
0.037
583
808
±
0.0000
0.04
N2
429
581
7.2
±
0.2
2.71E-06
0.9771
0.037
583
808
46.5
±
0.1
3.60E-04
0.9998
0.33
0.37
N3
429
581
2.1
±
0.1
1.58E-06
0.8733
0.037
583
808
7.9
±
0.0
3.08E-06
0.9992
0.33
0.37
N4
429
581
-0.5
±
0.1
1.21E-06
0.4891
0.037
583
808
-1.8
±
0.0
9.36E-07
0.9801
0.33
0.37
N5
406
681
17.7
±
0.1
2.27E-07
0.9899
0.12
683
1052
50.5
±
0.4
7.70E-10
0.9892
0.68
0.80
N6
429
581
7.4
±
0.2
2.80E-06
0.9784
0.037
583
808
9.6
±
0.0
4.34E-06
0.9989
0.33
0.37
N7
429
581
2.1
±
0.1
1.62E-06
0.8834
0.037
583
808
2.6
±
0.0
1.75E-06
0.9975
0.33
0.37
N8
406
681
56.7
±
1.1
8.30E-04
0.9529
0.12
683
1052
71.0
±
1.8
4.96E-03
0.9391
0.68
0.80
Table 4:
Solid State Reaction methods applied to pure fuels and blends at 100K/min, Ea presented with 95% confidence interval