| Entry |
Catalyst |
Conditions |
Reference |
104 kobs (s-1)
(rate constant) |
Half life
(t1/2) (h) |
| 1
|
(NaBrO3)-(NaHSO3)
|
(NaBrO3)=1 × 10-3 mol dm-3
(NaHSO3)=2 × 10-3 mol dm-3
Temp=30°C |
(30)
|
1.96
|
0.982
|
| 2
|
DCSB in 1:1 water acid medium |
(HClO4)=0.1 mol dm-3
I=0.3 mol dm-3
(DCSB)=1 × 10-3 mol dm-3
Temp=30°C |
(31) |
1.9 |
1.01 |
| 3
|
Pd(II)
|
(IO4-)=1 × 10-4 mol dm-3 (OH-)=0.5 mol dm-3 Pd(II)=1 × 10-4mol dm-3 Temp=25°C |
(32)
|
3.8 |
0.506
|
| 4 |
SDS (catalyst)+phen (promoter) |
(phen)=0.0125 mol dm-3 (SDS)=0.02 mol dm-3 |
Curent work |
9 |
0.214 |
