El-s |
T |
P |
VL |
ΔV |
σ |
rm |
Vm |
VLf |
λex |
λT |
δ |
Li |
1600 |
0,91 |
1,73 |
13058 |
273 |
1,57 |
0,97 |
0,75 |
134720 |
151512 |
-12,5 |
Na |
1150 |
0,96 |
3,09 |
8760 |
120 |
1,89 |
1,70 |
1,39 |
89590 |
98320 |
-9,7 |
K |
1000 |
0,73 |
5,82 |
10516 |
65 |
2,36 |
3,31 |
2,51 |
75994 |
82311 |
-8,3 |
Rb |
950 |
0,92 |
7,25 |
7893 |
50,7 |
2,53 |
4,08 |
3,17 |
69742 |
73767 |
-5,8 |
Cs |
800 |
0,20 |
8,56 |
31264 |
47,5 |
2,74 |
5,18 |
3,37 |
65126 |
72209 |
-10,9 |
Hg |
613 |
0,75 |
1,57 |
6820 |
384 |
1,60 |
1,03 |
0,54 |
59275 |
67675 |
-14,2 |
|
T[K] is the evaporation temperature, P*10-5 [Pa] is the pressure, VL*105 [m3/mole] is the molar volume of liquid, ΔV *105 [m3/mole] is the volume jump in evaporation, σ*103
[J/m2] is the surface tension coefficient, rm*1010 [m] is the ion radius in Table 2 and the metal radius in Table 3, Vm*105 [m3/mole] is the volume occupied by ions, VLf*105[m3/
mole] is the "free volume" of liquid, λex[J/mole] is experimental evaporation heat, λT[J/mole] is calculated value of evaporation heat, and % is the calculation error λT. |