S.No |
% solvent |
ΔG° (kJ/mole) values |
Methanol- H2O* |
Ethanol-H2O |
1-propanol-H2O |
2-propanol-H2O |
1 |
0 |
32.471 ± 0.05 |
34.404 ± 0.03 |
34.312 ± 0.04 |
34.335 ± 0.04 |
2 |
1 |
32.450 ± 0.05 |
34.358 ± 0.02 |
34.321 ± 0.04 |
34.757 ± 0.04 |
3 |
2 |
32.492 ± 0.06 |
34.473 ± 0.03 |
34.335 ± 0.04 |
34.815 ± 0.03 |
4 |
3 |
32.475 ± 0.07 |
34.381 ± 0.04 |
34.478 ± 0.04 |
34.844 ± 0.04 |
5 |
4 |
32.643 ± 0.01 |
34.473 ± 0.04 |
34.520 ± 0.03 |
34.952 ± 0.04 |
6 |
5 |
32.819 ± 0.04 |
34.52 ± 0.04 |
34.520 ± 0.04 |
35.076 ± 0.04 |
7 |
6 |
33.067 ± 0.04 |
34.952 ± 0.03 |
34.805 ± 0.05 |
35.616 ± 0.04 |
8 |
10 |
33.229 ± 0.05 |
35.458 ± 0.04 |
35.831 ± 0.05 |
36.136 ± 0.04 |
9 |
15 |
33.371 ± 0.06 |
35.996 ± 0.05 |
37.242 ± 0.06 |
38.678 ± 0.07 |
10 |
20 |
33.861 ± 0.06 |
38.056 ± 0.05 |
38.716 ± 0.07 |
41.475 ± 0.08 |
11 |
25 |
35.173 ± 0.05 |
40.579 ± 0.08 |
42.476 ± 0.11 |
44.021 ± 0.11 |
*328 ± 2K in case of methanol |