Sorbent Desorption
technique
Compounds
sampled
Starting
at bpb
[°C]
Main Advantages and
Disadvantages
Tenax TA thermal -most non polar VOCs
-slightly polar VOCs
-aldehydes>C5
-(acids>C3)a
> 60 -low background
-well investigated
-some decomposition products
(benzaldehyde,
acetophenone)
Carbotrap thermal -most non polar
VOCs
-slightly polar VOCs
> 60 -low background
-reactions of some
compounds
(i.e. aldehydes,
terpenes)
Activated carbon solvent/
thermal
-most non polar
VOCs
-slightly polar VOCs
> 50 -high capacity
-reactions of some
compounds
Porapak Q thermal -most non polar
VOCs
-slightly polar VOCs
> 60 -high background
-low thermal stability
Porapak S or R,N thermal -VOCs incl.
moderately polar
terpenes
> 40 -high background
-low thermal stability
Organic molecular sieves
(e.g., Carboxen 563,564,Carbosieve-S-III)
thermal -polar and non polar VOCs > −80 -water absorption
a. Can be used
b. Boiling point (mainly low recoveries)
Table 3: Solid sorbents used to collect VOCs (adopted and modified from ECA report no 14, 1995 [23]).