Technique Example Instrument/Method Positive Features Negative Features
Analytical (Screening) Methods  
Direct-measuring Organic vapor analyzer - On-site detection and quantification - Capability of catching concentration excursions -  Low sensitivity -  Low specificity
  Photo-ionization detector
Field/Analytical Portable gas chromatograph - On-site detection and quantification - Allows use of simple collection device such as a Tedlar bag - Better detection capability than the direct-measuring techniques -  Usually considered a “screening” method because does not involve identification using a mass spectrometer
   
Collection Methods  
  Evacuated canisters -   Capability of taking multiple aliquots for analysis -  More expensive than adsorbent tube method -  May require special handling to prevent sample deterioration during transport to lab for analysis
  Adsorbent media tubes -   Less expensive than evacuated canister method -  May be subject to “breakthrough” problems -  May require special handling to prevent sample deterioration during transport to lab for analysis
  Passive badge sampler -   Can monitor longer-term period of time -    Relatively inexpensive -  Higher humidity can produce erroneous results -  Possible back- diffusion off sampling medium -  Possible interferences between compounds
Table 8: Summary of some general air monitoring techniques (adopted and modified from MADEP, 2002 [55]).