| |
1H nmr |
13C nmr |
| Position |
B2
[13] |
3sst002 (acetone
+D2O) |
B5
[13] |
B2
[14] |
B5
[14] |
3sst002
(acetone
+D2O) |
B2
[15] |
B5[15]
|
B2
[16] (CD3OD) |
| 2 |
(U)4.99
(L) 4.92 |
(U)5.111
(L) 4.979 |
(U)4.90
(L) 4.77 |
(U)76.6, (L)79.1 |
(U)76.6, (L)78.9 |
(U)76.2,
(L)78.5 |
(U)76.55,
(L)78.91 |
(U)76.69,
(L)78.98 |
(U)77.9,
(L)80.6 |
| 3 |
(U)3.85
(L)4.29 |
(U)4.010
(L) 4.312 |
(U)3.99
(L)4.13 |
(U)72.8, (L)66.2 |
(U)72.1, (L)66.6 |
(U)72.2,
(L)65.7 |
(U)72.56,
(L)65.99 |
(U)71.73,
(L)66.49 |
(U)74.3,
(L)67.8 |
| 4 |
(U)4.63
(L)2.83,2.69 |
(U)4.741, (L)2.731,2.925 |
(U)4.54
(L)2.585,2.745 |
(U)36.7, (L)29.1 |
(U)37.0, (L)28.9 |
(U)36.2,
(L)28.3 |
(U)36.60,
(L)28.92 |
(U)37.03,
(L)29.04 |
(U)37.7,
(L)30.5 |
| 5,7,8a (U,L) |
|
|
|
|
|
157.6,156.8,155.2 |
155.6,157.3,
157.9 |
154.73,155.50,
157.44 |
158.5,159.1,
157.2 |
| 6 |
5.91, 5.92(U,L) |
6.02 |
6.02 |
(U)96.5,
(L)97.4 |
(U)96.9, (L)108.6 |
(U)96.4,
(L)95.1 |
(U)95.48,
(L)96.03 |
(U)95.49,
(L)96.11 |
(U)97.1,
(L)98.0 |
| 8 |
5.98 |
|
6.06,6.04(U,L) |
(U)96.0
(L)107.7 |
(U)96.0, (L)96.9 |
(U)95.6,
(L)106.3 |
96.81, |
96.32, |
(U)98.1,
(L)108.1 |
| 4a |
|
|
|
|
|
99.8 |
100.22 |
100.18 |
101.0,102.1(U,L) |
| 1′ |
|
|
|
|
|
(U)131.5,
(L)130.98 |
(U)131.41,
(L)131.90 |
(U)131.72,
(L)131.62, |
(U)132.8,
(L)133.4 |
| 2′ |
6.92 |
6.94(U,L) |
6.95,6.99(U,L) |
|
|
(U)114.6,
(L)114.3 |
(U)115.05,
(L)114.77 |
(U)115.01,
(L)115.38 |
(U)116.1,
(L)116.7 |
3′,4′
(U,L) |
|
|
|
|
|
144.8,144.6,144.4 |
144.76,144.95,
145.14 |
145.0,145.12,
145.20 |
146.5,146.4, 155.2, |
| 5′ |
6.68, 6.70(U,L) |
6.72(U,L) |
6.74,6.75(U,L) |
|
|
(U)114.8,
(L)115.0 |
(U)115.35,
(L)115.48 |
(U)115.01,
(L)115.38 |
(U)116.1,
(L)116.7 |
| 6′ |
6.87, 6.58(U,L) |
6.66(U,L) |
6.64,6.78(U,L) |
|
|
(U)118.5,
(L)118.3 |
118.95 |
(U)118.98,
(L)118.90 |
|
|