Reaction ΔH,
kJ/mol
E,
kJ/mol
k(310 K),
s−1
%
C8aOO• → C12 19.9 44.6 1.71×105 62.6
C8aOO• → C8(O) + HO• -110.5 42.7 6.78 × 104 25.0
C8aOO• → C5a• 31.7 50.3 1.81 × 104 6.4
C8aOO• → C10 34.4 51.7 1.07 × 104 4.0
C8aOO• → C6 38.2 53.6 5.12 × 103 1.8
C8aOO•+LSH→C12OOH +LS• 1.6 32.4 6.93 × 101 0.03
Table 1: Kinetic parameters of parallel reactions of C8a peroxyl radical of 1.