Reaction ΔH, kJ/mol E, kJ/mol k(310 K), s−1 % C8aOO• → C12• 19.9 44.6 1.71×105 62.6 C8aOO• → C8(O) + HO• -110.5 42.7 6.78 × 104 25.0 C8aOO• → C5a• 31.7 50.3 1.81 × 104 6.4 C8aOO• → C10• 34.4 51.7 1.07 × 104 4.0 C8aOO• → C6• 38.2 53.6 5.12 × 103 1.8 C8aOO•+LSH→C12OOH +LS• 1.6 32.4 6.93 × 101 0.03

Table 1: Kinetic parameters of parallel reactions of C8a peroxyl radical of 1.