A Preliminary Estimate of the Reserve of the Marble Deposit in Itobe Area, Central Nigeria

Marble, a major raw material for industries, is a crystalline, non-foliated metamorphic rock formed from the metamorphism of limestone (a carbonate sedimentary rock formed at the bottom of lakes and seas). The Itobe marble deposit is located about 1 km from Itobe town along the Ajaokuta-Anyigba road, Kogi State, central Nigeria. The study area lies between longitudes 6°40’ E and 6°48’E and latitudes 7°22’N and 7°30’ N (Figure 1).


Introduction
Marble, a major raw material for industries, is a crystalline, non-foliated metamorphic rock formed from the metamorphism of limestone (a carbonate sedimentary rock formed at the bottom of lakes and seas). The Itobe marble deposit is located about 1 km from Itobe town along the Ajaokuta-Anyigba road, Kogi State, central Nigeria. The study area lies between longitudes 6°40' E and 6°48'E and latitudes 7°22'N and 7°30' N ( Figure 1).
The industrial uses of a marble deposit are determined largely by its chemical composition and the reserve of the deposit. Geological and geophysical investigation methods have been employed in the exploration of marble deposits. The electrical resistivity method of geophysical prospecting in particular has been employed to delineate the areal extent and thickness of marble deposits. The choice of the resistivity method was informed by the local resistivity contrast characteristics of marble deposits (10 2 -2.5 × 10 8 Ωm) compared to the immediate host rocks of schists (20-10 4 Ωm) and quartzites (10-2× 10 8 Ωm) [1][2][3][4]. This study aims at estimating the reserve of the marble deposit in Itobe from both outcrop geological studies and geophysical resistivity investigations.

Field Geologic Occurrence
The marble deposit in Itobe is associated with crystalline rocks of the Precambrian Basement Complex. The marble deposit occurs within a host rock of quartz-mica schist and feldspathic quartzite. Two outcrops (designated as mass I and mass II) of the marble deposit have been identified in the study area ( Figure 2). Mass I with a surface area of 0.84 m 2 , trends NE-SW with a strike azimuth of 033°. It is poorly exposed near Alo village, along the Anyigba-Itobe road. It is light grey in color and fine grained in texture. Mass II, which is about 800 meters from mass I on a NE-SW axis, is a much larger deposit, and outcrops on the Ayanka hill as massive boulders. It is medium grained in texture, dark grey in color and has an elevation of 132 m at the bottom and 138 m at the top. It has a sharp contact with the quartz mica schist to the east and the Feld spathic quartzite to the west.

Method of Study
The lateral extent and thickness of the marble deposit was obtained both from outcrop geological and geophysical resistivity surveys. The Etrex Global Positioning System was used to measure the elevations at the bottom and top of the outcropping marble. The Vertical Electrical Sounding (VES) method using the Schlumberger configuration was employed to determine the thickness of the marble deposit. The horizontal profiling method using the Wenner configuration was employed to determine the lateral extent of the marble deposit ( Figures  3 and 4).
The density of the marble was determined by weighing a fresh and clean sample of the marble rock using a Top Weighing Balance, and the mass was noted. A well calibrated beaker was filled with water to a certain mark and the mark noted. The marble sample was lowered into the beaker containing water using a thin thread. The change in the volume of the water in the beaker, which is equal to the volume of the marble sample, was noted. The density of the marble sample was obtained by dividing the mass of the marble sample by the change in the volume of the water on immersion of the marble sample.
The estimated total reserve of the marble deposit was determined by adding the reserves of the individual masses (masses I and II). The reserve of each mass of the marble deposit has been computed using the block method [5]. The surface extent of mass I and mass II (Figures 5 and 6) were subdivided into blocks of regular geometries (rectangular block of 0.072 cm × 0.096 cm) and then summing up the area of the entire blocks. The reserve of each mass of the marble deposit is obtained as follows:   Table  1 below. The interpretation of the resistivity profiles is qualitative, and it involves identifying signatures characteristic of the marble. Figure 7 shows a correlation of the resistivity profiles along the seven traverses. The outcropping marble along traverses 5 and 6 is characterized by a relatively high resistivity (500-600 Ωm) in a background of low resistivity     Lines correlating resistivity of marbles across pro les (6-250 Ωm) characteristic of the host rocks (mica schist and quartz mica schist). Similar geophysical patterns were observed over marble deposits in Igarra area of southwestern Nigeria [2,3]. The interpretation of the resistivity profiles across the marble deposit in Itobe using the above characteristic shows that there is no continuity between masses I and II of the marble deposit. The marble deposit in Itobe shows a NE-SW trend.
The resistivity sounding data obtained for eight vertical electrical sounding surveys carried out along the trend of the marble deposit are presented in Table 2, and the corresponding resistivity sounding curves are shown in Figures 8 -15. The interpretation of the VES data involves the determination of the geoelectric layer parameters (resistivity and thickness) of the marble and the surrounding rocks (Table 3).      The resistivity value for marble in the study area (obtained from the outcropping marble at VES 2 location), varies from 520 to 555 Ωm, depending on water content and porosity.

Layer Thickness (m)
Depth to layer (m)   of the VES sounding locations. The geoelectric parameters of the resistivity sounding survey (Table 3) shows a thickness of 0.6 m for the outcropping marble (mass I) at VES 2 location. This marble unit is suspected to extend to VES 3 as shown by the resistivity values of the first geoelectric layer (552-523 Ωm) between VES 2 and VES 3 locations. This marble unit is underlain by a second geoelectric layer interpreted as mica schist with a resistivity ranging from 70 50 Ωm, and a thickness ranging from 9.2-9.6 m. The third geoelectric layert, with a resistivity value ranging from 381-261 Ωm, is a highly weathered Basement rock. VES locations 5 and 6, in close contact with the outcropping marble in mass II is a lateritic layer with a resistivity of 1003 1967 Ωm and a thickness ranging from 1.0-1.8 m. It is underlain by a quartz-mica schist layer with resistivity values in the range (249-134 Ωm) and a thickness ranging from 10.6 17.2 m. Underlying the quartz-mica schist is the weathered Basement rock with a layer resistivity ranging from 539-630 Ωm. This is a more competent layer than that below mass I.
The average density value for the two marble outcrops in the study area is presented in Table 4.

Conclusion
Field geological and geophysical investigations of the marble deposit in Itobe area, Kogi State, central Nigeria reveals the occurrence of two separate marble outcrops ( mass I and mass II) occurring 800 m apart along a NE-SW trend. The estimated reserve of the marble in mass I is 1418.4 tons and the estimated reserve of marble in mass II is 142643.2 tons. The total reserve of the marble deposit in Itobe is 144061.6 tons.