alexa Catalytic Infrared Drying Effect on Tomato Slices Properties | Open Access Journals
ISSN: 2157-7110
Journal of Food Processing & Technology
Like us on:
Make the best use of Scientific Research and information from our 700+ peer reviewed, Open Access Journals that operates with the help of 50,000+ Editorial Board Members and esteemed reviewers and 1000+ Scientific associations in Medical, Clinical, Pharmaceutical, Engineering, Technology and Management Fields.
Meet Inspiring Speakers and Experts at our 3000+ Global Conferenceseries Events with over 600+ Conferences, 1200+ Symposiums and 1200+ Workshops on
Medical, Pharma, Engineering, Science, Technology and Business

Catalytic Infrared Drying Effect on Tomato Slices Properties

Abano EE1*, Ma HL2,3, Qu WJ2,3, Wang PL2, Wu BG2 and Pan ZL2

1 Department of Agricultural Engineering, School of Agriculture, University of Cape Coast, PMB, Cape Coast, Ghana

2 Department of Food Science and Engineering, School of Food and Biological Engineering, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China

3 Jiangsu Provincial Key Laboratory for Physical Processing Of Agricultural Products, Jiangsu University, 301 Xuefu Road, Zhenjiang 212013, China

*Corresponding Author:
Ernest Ekow Abano
Department of Agricultural Engineering
School of Agriculture, University of Cape Coast
PMB, Cape Coast, Ghana
Tel: +233542404334
Fax: +233332132709
E-mail: [email protected]

Received Date: February 17, 2014; Accepted Date: March 24, 2014; Published Date: April 03, 2014

Citation: Abano EE, Ma HL, Qu WJ, Wang PL, Wu BG, et al. (2014) Catalytic Infrared Drying Effect on Tomato Slices Properties. J Food Process Technol 5:312. doi:10.4172/2157-7110.1000312

Copyright: © 2014 Abano EE, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

Visit for more related articles at Journal of Food Processing & Technology

Abstract

In this study, the effect of distance between Far-Infrared Radiation (FIR) emitter and the surface of tomato slices and sample thickness on drying time, non-enzymatic browning, brightness, the ratio of redness to yellowness, ascorbic acid content, and lycopene content of the dried tomato slices was investigated. Three levels of distance (38 to 50 cm), sample thickness (7 to 11 mm) were used for the experiment. The desirability index technique was used to determine the ideal drying conditions that yield minimum drying time and non-enzymatic browning and maximum brightness color, redness to yellowness ratio, lycopene content, and ascorbic acid of drying of tomato slices. At the best conditions of 40.29 cm distance and 9.04 mm sample thickness, the drying time was 108 ± 4 minutes; the non-enzymatic browning index was 0.338 ± 0.12 Abs unit; the brightness was 40.43 ± 2.29; the ratio of redness to yellowness was 0.92 ± 0.13; the ascorbic acid content was 3.76 ± 0.27 mg/g dry matter; and the lycopene content was 72.34 ± 19.87 mg/100 g dry matter. These results demonstrate that FIR should be considered as an efficient drying method for tomato with respect to colour and ascorbic acid preservation, minimization of brown pigment formation and increment in lycopene content.

Keywords

Tomato slices; Drying; Lycopene; Ascorbic acid; Nonenzymatic browning; Colour; Response surface methodology

Introduction

Tomato (Lycopersicon esculentum) plays an important role in the diet of mankind. It provides diet with color, flavor, vitamin, and lycopene. The average tomato composition is: water (94 g/100 g), carbohydrate (3.9 g/100 g), sugar (2.6 g/100 g), dietary fiber (1.2 g/100 g), fat (0.2 g/100 g), protein (0.9 g/100 g), vitamins (mainly vitamin C: 0.014 g/100 g) [1]. Fresh tomatoes contain 94 g/100 g water within a slightly soft cell wall structure, which is responsible for the fast deterioration at post-harvest. Therefore, appropriate processing method is required to prolong the shelf-life of tomatoes. Drying is among the methods for the purpose to make a high-quality product, which can be consumed directly or used as the ingredient for preparation of stews, soups, sauces, pizzas, etc. Among the various drying methods, the most common is the convectional air drying. However, this approach is usually long, energy intensive, and cause many undesirable changes to the dried product. One of the ways to shorten the drying time and to make high-quality product is to use far-infrared radiation (FIR) heating. This method is suitable for thinlayer drying of materials with large surface of exposure to radiation [2]. The FIR impinges on the material to be dried, penetrates it, and converts the IR energy into heat [3]. This causes the material to be heated intensely, and as a result, reduces the temperature gradient inside the material within a short time. The FIR energy is transferred from the heater to the product surface without heating the surrounding air [4]. Therefore, there is lesser energy consumption in FIR drying process. Previous studies have reported several advantages of FIR drying over the conventional hot air: high-heat transfer coefficient, high-energy efficiency, lesser air flows through the food material, short processing time, and low cost of energy requirement [2,5-7]. Applied occasional FIR heating and concluded that the color degradation was offset by a significant reduction in drying time. Shorter drying time with improved product quality was reported by other researchers [8,9], when periodic FIR heating was applied. The FIR process can be done at the ambient temperatures because air is transparent. Many authors have investigated the FIR drying of onion slices [2], apple slices [6,10], wet olive husk [11], barley [12], potato [13], cashew kernel [14], and tomato residue [15]. Little information is available on FIR catalytic drying of tomato slices.

Therefore, in this study, the influence of distance from the FIR catalytic emitter and the surface of the tomato slices, and the thickness of the sample, on drying time (DT), non-enzymatic browning index (BI), color brightness (L*), the ratio of redness to yellowness (a*/b*), ascorbic acid content (AA), and lycopene content (LC) of the dried tomatoes. Optimization of the FIR drying conditions was performed using the desirability index technique to establish the best condition for minimum DT and BI, and maximum values of LC, AA, L*, and a*/b* for FIR drying of tomatoes.

Materials and Methods

Sample preparation

The fresh tomatoes used in this study were tomatoes from the Hong Xiu hybrid No. one variety procured from Zhenjiang local market, China. Selection was based on visual assessment of uniform color and geometry. The tomato samples were washed under running tap water and stored in a refrigerator at a temperature of 4°C to slow down the physiological and chemical changes [16,17]. Prior to drying, the individual tomatoes were cut into slices with a machine (SS-250, SEP Machinery Company Ltd, Guangzhou, China) with an accuracy of 0.05 mm. Uniform slices of diameters (6.32 ± 0.16 cm) were subjected to dry without removing the epidermis and the seeds. The initial mean moisture content of 19.49 ± 0.17 kg water/ dry weight (95.12 ± 0.04% w.b) of the tomatoes was determined gravimetrically at 150°C for 24 h. The initial average LC (11.84 ± 1.3 mg/ g dry weight), AA (4.09 ± 0.36 mg/g dry weight), color (L*: 39.49 ± 0.2, a*: 31.08 ± 0.12, b*: 29.84 ± 0.3, a*/b*: 1.04 ± 0.01), and BI (0.052 ± 0.002 Abs units) were determined according to the method described below for each determination.

Drying equipment and procedure

The tomato slices were dried in a laboratory-type flameless gas FIR catalytic dryer developed for the present study. The device comprises of a 60 by 30 cm rectangular heater (The Bruest, S1224, Kansas, USA), distance adjustable screws, drying chamber, pressure gauge, and online electronic balance (Sartorius 2200S, Germany). The dryer uses propane gas as the energy source after electrical heating for 5-15 minutes. Preliminary experiments conducted with this device revealed that variation of gas pressure has no effect on the temperature of the heater. In this dryer, the pressure and distance were controlled by regulating the pressure gauge and adjustable distance screws. Temperature of the heat source was measured with an infrared thermometer (-50 to +480°C) with an accuracy of 0.1°C. A schematic view of the FIR catalytic dryer is shown in Figure 1.

food-processing-technology-laboratory

Figure 1: Schematic diagram of the laboratory FIR catalytic dryer.

The drying chamber of 600×300×600 mm was made from a stainless steel sheet of thickness 0.4 mm. The outer sides of the chamber were covered with plywood sheet of 8 mm thickness having a single opening at the front. The specifications of the FIR device is as follows: 240 voltage infrared heater, 63 WC orifices, 2.08 amps AC-DC, and 12,000 [email protected] FT.ALT input energy. A stainless steel meshed sample tray was placed on a two-rail platform below the FIR heater. The temperature of the FIR heater was measured with a hand-held infrared thermometer throughout the experiment, and was recorded to be 384.9 ± 12.8°C.

Experimental procedure

The device was run idle for 0.25 h to achieve a steady-state condition prior to each run. About 100 g of the tomato slices was put in thin layer on the sample tray with one slice not touching the other and placed in the drying chamber. Preliminary experiments placed at 20 and 29 cm from the heat source at 2.0 kPa gas pressure darkened the product. Therefore, the drying experiments were carried out at distance of 38, 44, 50 cm and sample thickness of 7, 9, 11 mm at gas pressure of 2.0 kPa. During drying the mass of the samples were monitored online at an interval of 10 minutes. In this dryer, burning spots on the sample surfaces could easily be seen before all the moisture could be removed. Hence, the drying time was defined as the time required reducing the moisture content of the tomato from 19.49 to 0.7 kg water per kg dry weight. On completion of drying, the samples were cooled for 30 minutes in desiccators, wrapped with aluminum foil and stored in a freezer at -18°C for further analysis.

Experimental design

The 3-level factorial Response Surface Method (RSM) was used to design the drying experiments. Three levels of two independent variables; X1 (distance from the infrared heat source, cm), and X2 (sample thickness, mm) was generated for six response variables. The full model used to describe the response variable (Yr) involves the principal, interaction, and curvature effect as shown in Equation (1).

equation(1)

Where β0, β1, β2, β3, β4, β5, are the regression coefficients, X1, X2, are the coded values of the independent variables, and Yr represents the response variables DT, LC, AA, BI, L*, and a*/b* of the dried product.

Determination of ascorbic acid content

The ascorbic acid of the fresh and the dried samples were determined volumetrically with 4% oxalic acid, using 2,6-dichlorophenolindophenol as described in Official Method of Analysis [18].

Determination of lycopene content

The lycopene content of the fresh and dehydrated samples was measured spectrophotometrically following the protocol of [19]. The pigment was repeatedly extracted with mortar and pestle from about 4 g of raw and 0.10 g of dried samples with acetone assisted with ultrasound until the residue was colorless. The acetone extract was transferred into a separating funnel containing 20 ml petroleum ether and mixed gently. Then 20 ml of 5% sodium sulphate solution was added, and the separating funnel shaken slowly. Another 20 ml of petroleum ether was added to make up for any evaporated petroleum ether. The colored pigment noticed in the upper petroleum ether phase was separated and the lower phase re-extracted with more petroleum ether until colorless. The petroleum ether was washed with a little distilled water and poured into a brown bottle containing 10 g of anhydrous sodium sulphate and kept for at least 30 minutes. The petroleum ether was decanted into a 100 ml volumetric flask through a cotton wool in a funnel. The sodium sulphate slurry was washed with petroleum ether until it was colorless and transferred into the volumetric flask. It was topped up to the mark with petroleum ether, and the absorbance measured in a spectrophotometer (UNICO 7200, Shanghai, China) with an accuracy of 0.0001 Abs units at 503 nm with petroleum ether as the blank. The lycopene content (mg/100 g sample) was calculated using [Equation 2]

equation(2)

Where Lc is the lycopene content (mg/100g), Abs is the absorbance, and wt is the weight of the sample (g)

Color measurement

The color of the fresh and the dried product was measured in Hunter parameters with a colorimeter (DC-P3, Beijing, China). The raw tomatoes were milled for 2 minutes with kitchen type blender and passed through the 70 μm sieve and poured into the cuvette holder. The colors of the dried samples were measured directly by focusing the light flux on the samples and covered with black cloth. The colorimeter was calibrated by placing the tip of the measuring light flux against the surface of the white and black calibration plates.

After calibration, three readings were recorded for the dried samples with the fresh tomato as the standard. The coordinate, L*, measures the brightness value, which ranges between black (0) and white (100). The chromaticity coordinate, a*, measures red when positive and green when negative, while the chromaticity coordinate, b*, measures yellow when positive and blue when negative. Values of a* and b* range between -60 and +60.

Non-enzymatic browning determination

A modified method of [20] was used to determine the nonenzymatic browning index (BI) of the dried tomatoes. To 50 mL of 60% ethanol (v/v), 2 g of the powdered tomato sample was added and stirred. The mixture was allowed to stand for 12 h, agitated, and then filtered through 0.45 μm nylon filter membrane. The filtrate was topped up to the 50 mL mark, and the absorbance was measured at 440 nm with a spectrophotometer (UNICO 7200, Shanghai, China) against 60% ethanol as blank. The absorbance value obtained was used to indicate the extent of browning. All samples were extracted in duplicate.

Optimization of the drying process

The optimization of the drying process was performed using a multivariate response method called overall desirability index, DI [21] using Equation 3. The di represents the desirability index for each response variable (Yi), and it is a multi-criteria optimization approach used to show how worthwhile the various responses are.

equation (3)

The DI ranges between 0 and 1 with 0 being the least suitable whiles 1 is the most desirable. Maximization of DI value is the goal in optimization studies. The optimization process incorporates goals and priorities for the independent and response variables. For this study, the goal for the independent variables was at any level within the range of the design values. However, in the case of the response variables, the goal was minimum values of DT and BI, and maximum values of LC, AA content, L*, and a*/b*.

Statistical analysis

A second-order polynomial model was fitted to the mean values of the experimental results to get the regression equations with Design Expert 8.0.7.1 [22]. The statistical significance of the model terms was checked out at a probability of 0.05. The accuracy of the model to describe the response variables was diagnosed against the normal probability plots of the residuals, the predicted versus actual plots, and the coefficients of determination (R2) values. The 3-D surface plots for the factors were generated for the various responses.

Result and Discussion

Effect of fir drying on drying time

The results of the thirteen experiments performed according to the three-level factorial RSM are shown in Table 1. Kinetics of drying time of tomato slices with FIR energy was dependent on both the distance between the heat source and the surface of tomato slices as well as the thickness of the samples. The effect sample thickness and distance between the FIR energy emitter and the surface of tomato slices is evident (Figure 2). As expected, the principal effect of increasing the distance between the FIR emitter and the surface of tomato slices resulted in a significant increase in the DT of the tomato slices (Table 2 and Figure 2). Similarly, the principal and quadratic effect of an increase in sample thickness so increased DT significantly. Depending on the drying condition, the time required reducing moisture content of tomatoes from 19.49 to 0.7 kg water / kg dry matter was between 100 and 150 minutes. This means that there were significant savings in time as distance between the FIR emitter and surface of the tomato slices and sample thickness was decreased. Variations in the estimated coefficients show that there were different relative effects of the independent variables. The effect of sample thickness was more pronounced on DT than the effect of the distance from the FIR heater [Equation 4]. The lowest sample thickness and distance between the infrared energy emitter and the surface of tomato slices gave the least DT. The interaction effect of distance and sample thickness was an unimportant model term on the DT. The quadratic effect of the sample thickness was, however, significant. The result depicted that as distance increases, the temperature of the sample decreases, and as a result decreases the removal of moisture from the surface, which, consequently prolongs the processing time. Similarly, with the increase in the sample thickness, the distance for moisture transport from the centre to the surface of the slices is widened, thereby resulting in an extension in DT.

food-processing-technology-catalytic-infrared

Figure 2: Effect of catalytic infrared intensity and sample thickness on response surface plot of drying time.

Distance Thickness DT (min) L* a*/b* BI (Absunit) AA (mg/g d.m) LC (mg/ 100g d.m)
44 7 100 41.39 0.83 0.520 1.72 52.58
44 9 110 42.58 0.78 0.279 3.58 73.02
44 9 110 43.8 0.72 0.281 3.64 76.30
38 11 130 45.04 0.66 0.410 2.43 74.48
50 7 110 43.16 0.76 0.732 1.91 24.95
44 9 110 41.44 0.87 0.278 3.58 76.30
44 9 110 39.37 0.98 0.279 3.76 75.21
44 9 110 38.97 1.00 0.281 3.64 73.02
38 7 100 38.34 1.03 0.781 2.58 68.86
38 9 110 38.06 1.06 0.413 3.54 40.02
44 11 150 38.38 1.02 0.636 1.51 24.29
50 9 120 38.72 0.97 0.472 3.15 60.48
50 11 150 39.08 0.93 0.339 1.62 48.28

Table 1: Three-Level Factorial Design For Two Factors And Results Of Dt, L* , A*/B*, Bi, Aa And Lc.

Source Coefficient Estimate Sum of squares Df F-value P-value Prob>F
Intercept(β0) 111.03        
Model   3154.80 5 36.17 <0.0001*
X11) 6.67 266.67 1 15.28 <0.0058*
X22) 20.00 2400.00 1 137.56 <0.0001*
X1 X23) 2.50 25.00 1 1.43 0.2702**
X124) 1.38 5.25 1 0.30 0.6002**
X225) 11.38 357.64 1 20.50 0.0027*

Table 2: ANOVA of drying time for infrared dried tomato slices by response surface quadratic model.

equation (R2=0.9627)(4)

A similar effect of distance on the DT for FIR drying of apple slices [6] and onion slices [2] were reported.

The higher value of R2 of 0.9627 depicts that a higher proportion of the experimental variability was explained by the RSM model. The suitability of the model was further verified with the normal probability plot of the DT residuals (Figure 3a) and the predicted versus actual DT plot (Figure 3b). The lack of fit test was also not significant, which further validates the model.

food-processing-technology-Normal-probability

Figure 3: (a) Normal probability plot of the drying time residuals; (b) Predicted versus actual drying time

Effect of FIR Drying on Color

Color change is another quality criterion for assessing the quality of dried products. The closer it is to the fresh tomatoes, the better it is preferred by consumers. Higher values of L* and a*/b* are desirable in dried products [23]. The effect of the independent variables on L* and a*/b* is shown in Figures 4 and 5.

food-processing-technology-infrared-intensity

Figure 4: Effect of catalytic infrared intensity and sample thickness on response surface plot of brightness color of dried tomatoes.

food-processing-technology-yellowness

Figure 5: Effect of catalytic infrared intensity and sample thickness on on response surface plot ratio of redness to yellowness of dried tomatoes.

Generally, the effect of distance and sample thickness on the L* was not statistically significant within the range of distance and sample thickness studied (Equation 5 and Table 3) even though the luminance improved with increasing these factors (Figure 4).

Source Coefficient Estimate
L*
Sum
of squares L*
Df F-value L* P-value
Prob>F L*
Coefficient Estimate
a*/b*
Sum
of squares a*/b*
F-value a*/b* P-value
Prob>F a*/b*
Intercept(β0) 40.63         0.90      
Model   31.35 5 1.19 0.4016**   0.083 0.93 0.5157**
X11) -0.080 0.0388 1 0.0073 0.9344** -0.015 0.00135 0.075 0.7915**
X22) -0.065 0.025 1 0.0048 0.9466** -0.001667 0.001655 0.00093 0.9765**
X1 X23) -2.69 29.05 1 5.51 0.0512** 0.14 0.073 4.07 0.0833**
X124) -0.74 1.50 1 0.28 0.6105** 0.036 0.003655 0.20 0.6650**
X225) 0.76 1.59 1 0.30 0.5998** -0.054 0.007941 0.44 0.5266**

Table 3: ANOVA of color L* and a*/b* for the infrared dried tomatoes by response surface quadratic model.

Source Coefficient Estimate Sum of squares Df F-value P-value Prob>F
Intercept(β0) 0.30        
Model   0.28 5 3.61 0.0620**
X11) -0.010 0.00062 1 0.04 0.8471**
X22) -0.010 0.23 1 4.53 0.0708**
X1 X23) -0.0055 0.000121 1 0.000823 0.9320**
X124) 0.078 0.017 1 1.08 0.3323**
X225) 0.21 0.13 1 8.17 0.0244*

Table 4: ANOVA of BI for the infrared dried tomato slices by response surface quadratic model.

A similar trend was observed for the a*/b* values (Equation 6 and Table 3). The increase in distance and sample distance decreased the a*/b* values insignificantly. When the color values of dried tomato slices were compared with the fresh (L*: 39.49, a*: 31.08, b*: 29.84, a*/b*: 1.04), there were enhancement in brightness and general reduction in a*/b*. The reduction in a*/b* ratio were smaller (4.9%) compared with hot air dried tomato slices (11.04%) [24]. The decrease of the a*/b* suggests less Maillard reaction. Siriamornpun et al. [25] dried marigold using FIR heating and reported color degradation even though the extent of degradation was less in FIR drying than freeze and hot air drying. The color changes in tomato slices may be caused by the destruction of the pigment present in tomatoes [26]. The color of the final dried tomatoes may be strongly related to the carotenoid lycopene [27]. This is because lycopene, which is carotenoids, gives the red-color of dried tomatoes. Degradation of a*/b* pigment of the dried tomatoes might show decreased bioactivity of the dried products. The color of the FIR dried tomatoes suggests that this method of drying can preserve bioactive compounds and activities than hot air method. The results were consistent with what Al-Muhtaseb et al. [28] reported for drying tomato pomace. The normal probability plots and simulated versus actual L* and a*/b* are displayed in Figure 6.

food-processing-technology-Predicted-versus

Figure 6: a) Normal probability plot of the L*; (b) Predicted versus actual plot of L*.,(c) Normal probability plot of a*/b* residuals; (d) Predicted versus actual plot of the a*/b* residuals.

equation (R2= 0.4595)(5)

equation (R2= 0.4595)(6)

Effect of FIR drying on non-enzymatic browning

Non-enzymatic browning is another quality indicator in drying. Whereas browning is desirable in some processed foods, it is undesirable in dried tomatoes. The extent of browning is mainly attributed to the color changes resulting from Maillard reactions in the tomatoes [29,30]. Expectedly, the combined effect of increases in these conditions decreased the BI values (Figure 7, Equation 7) with the quadratic effect being significant (b). The decreasing trend of BI depicts that the rate of brown pigment formation diminished with increasing the factors and were mainly caused by thermal effect of the drying air. For this present study, the BIs were in the range of 0.279- 0.781. In comparison with the raw tomatoes (BI of 0.052), there was browning in all the dried samples with the majority of the BIs below 0.60 absorbance unit. The browning indexes in the range of 0.585- 0.684 were reported at temperature between 50 and 90°C by [20]. In a visual assessment of dried tomato samples by 11 randomly selected panels, browning absorbance equal to 0.6 was considered critical [20]. Based on the above, without doubt, more than 77% of the samples dried under the experimental conditions studied would be acceptable to consumers. The occurrence of the browning might be attributed to the reactions between nitrogenous constituents and reducing sugars, nitrogen-bearing constituents and organic acids, and sugars and organic acids in the tomatoes [30,31]. The validity of the model is shown in Figures 8a and 8b. The lack of fit test was significant, which indicate that the overall mean of the BI values is a better predictor than the quadratic model.

food-processing-technology-catalytic-distance

Figure 7: Effect of catalytic distance and sample thickness on BI of dried tomatoes.

food-processing-technology-actual-plot

Figure 8: (a) Normal probability plot of the BI; (b) Predicted versus actual plot of BI.

equation (R2=0.7206)(7)

Effect of IR Drying on Ascorbic Acid Content

Principally, the distance of the tomato from the FIR heat source was significant for the ascorbic acid content of the final samples (Table 5). On the contrary, AA was affected insignificantly by its sample thickness. The increase in distance and sample thickness resulted in AA decrease, but the effect of distance was higher than sample thickness (Equation 8). Quadratically, the effect of sample thickness on AA content was very profound and showed statistical significance (Figure 9). The relative percentage degradation after infrared heating was between 8 and 63%. Comparatively, the FIR degradation of AA was higher than what Sokhansanj and Jayas [32] reported for industrial drying of fruits and vegetables (i.e. between10% and 50%).

food-processing-technology-sample-thickness

Figure 9: Effect of catalytic FIR distance and sample thickness on AA content.

Source Coefficient Estimate Sum of squares Df F-value P-value Prob>F
Intercept(β0) 3.53        
Model   8.89 5 23.92 0.0003*
X11) -0.31 0.58 1 7.84 0.0265*
X22) -0.11 0.070 1 0.95 0.3629**
X1 X23) -0.035 0.0049 1 0.066 0.8048**
X124) 0.098 7.35 1 0.36 0.5674**
X225) -1.63 0.52 1 98.87 <0.0001*

Table 5: ANOVA of AA content for FIR dried tomato slices.

There are complexities surrounding AA content degradation in drying of fruits and vegetables [33]. As distance and sample thickness increases, it takes a longer time to dry the sample. There is therefore, a long-time exposure of the samples to air temperature and as a result decreased the AA content. In onion [34], okra [35], and potato [36,37] drying, sample thickness was observed to affect AA retention significantly. Timoumia et al. [38] studied infrared dried Red Chief apple slices at 40-70°C and reported a pseudo-first-order degradation rate for AA content with an increase in temperature. Marfil et al. [39] investigated the ascorbic acid degradation of air dried tomato halves at temperatures of 50, 60, and 70°C at speed of 1.0 m/s and reported that the ascorbic acid in the tomatoes after dehydration reduced from 4.00 ± 0.30 mg/g to 2.19 ± 0.24 mg/g dry matter, representing 35% reduction. In pear drying, Mrad et al. [40] found AA to decrease as air temperature increased in the range of 30-70°C and attributed this to the occurrence of irreversible oxidative reactions during drying. There was a similar degradation in AA content when Erenturk et al. [41] dried rosehip in the temperature range of 50-80°C at constant air velocity and humidity ratio of 1.67 m/s and 0.005 kg moisture/kg dry matter respectively. Compared with the initial AA content of 4.09 ± 0.48 mg/g of the fresh tomatoes used for the study, it can be concluded that the reduction of AA was caused by thermal due to the high temperature used rather than oxidative damage. The normal probability plot of the residuals and the predicted versus experimental AA content used to check the suitability of the model are displayed in Figures 10a and 10b.

food-processing-technology-probability

Figure 10: (a) Normal probability plot of AA content residuals; (b) Predicted versus actual plot of AA content.

equation ( R2=0.9447)(8)

Effect of FIR drying on lycopene content

The distance between the FIR heat source and the surface of the samples was an important parameter for LC (Figure 11, Equation 9, Table 6). The enlargement in sample thickness increased the LC but not significantly. The LC measured in this study was between 24.29 and 76.30 mg/100g dry matter. Compared with the LC of the fresh samples (11.84 mg/100 dry matter) there was significant improvement in the LC after infrared heating. In drying of most vegetables, increases in lycopene content have been reported [42-44]. Lycopene degradation depends on many factors, including processing temperature. The increase in bio-accessible lycopene content is primarily due to the increased release of phytochemicals from the matrix to make it more accessible in the extraction process [43]. Additionally, the increment may be explained by an increased release of lycopene from the cell, skin and insoluble fibre of tomato [45]. Lycopene of the fresh tomato isomerizes from trans-form into the cis-lycopene as a result of thermal treatment or degrades into a colorless form [46]. Common heat treatments of tomato products do not result in a shift in the distribution of cis-lycopene isomers [47]. Thus, the increase in lycopene content reported in this study may be due to actual increase of lycopene due to concentration effect as a result of drying rather than a progressive conversion from its trans form to a less strongly colored, less intensely absorbing cis form. Siriamornpun et al. [25] studied the LC of a marigold flower after Freeze Drying (FD), Hot Air (HA) drying, and combined FIR-HA and reported that the FIR-HA samples had the highest amount of lycopene (58.7 mg/100 d.m), followed by the HA (51.2 mg/ 100g d.m), and then the FD samples (48.7 mg/100 d.m). In comparison with the fresh marigold flowers used by Siriamornpun et al. [25], the lycopene of FIR-HA samples increased by 54%, whereas that of HA and FD samples respectively increased by 34 and 28%. The normal probability plot of the LC residuals (Figure 12a), the predicted versus actual LC plots (Figure 12b), and the lack of fit test further shows that the overall mean of the LC is a better predictor.

food-processing-technology-catalytic

Figure 11: Effect of catalytic FIR distance and sample thickness on the LC of dried tomatoes.

food-processing-technology-lycopene

Figure 12: (a) Normal probability plot of the lycopene content residuals; (b) Predicted versus actual of the lycopene content.

Source Coefficient Estimate Sum of squares Df F-value P-value Prob>F
Intercept(β0) 69.22        
Model   1710.06 5 36.17 0.5473**
X11) -8.28 410.85 1 15.28 0.03417*
X22) 0.11 0.073 1 137.56 0.9896**
X1 X23) 4.43 78.41 1 1.43 0.6693**
X124) -5.10 71.83 1 0.30 0.6825**
X225) -16.91 790.21 1 20.50 0.2001**

Table 6: ANOVA of LC for FIR drying of tomato slices by response surface quadratic model.

equation (R2=0.8822)(9)

Optimization of the drying parameters

The affirmation of the location of the optimal FIR drying conditions was done using the concept of overall desirability index in Equation 3. The maximum predicted DT, BI, L*, a*/b*, AA and LC, and AA, were 118.63 min, 0.662 Abs unit, 46.40, 4.46 mg/g d.m, and 124.02 mg/100 g d.m respectively. These simulated values are closer to their corresponding experimental values of 150 min DT, 0.781 BI, 45.04 L* , 1.03 a*/b*, 3.64 mg/ g dry matter AA content, and 76.3 mg/ 100 dry matter LC.

The desirability of the responses gave an overall desirability of 0.731 (Figure 13). The results predicted with 95% confidence in the range of the independent variables gave optimal distance between the infrared radiation emitter and surface of the sample as 40.29 cm, and sample thickness as 9.04 mm. At this optimum condition, the DT, BI, L, a*/b*, AA and LC were found to be 107.8 min, 0.338 Abs unit, 40.43, 0.92, 3.76 mg/g dry matter and 72.34 mg/100 g dry matter respectively.

food-processing-technology-desirability

Figure 13: Effect of catalytic FIR and sample thickness on response surface plot of the desirability index for the optimal drying condition.

Conclusion

The study demonstrated that catalytic infrared drying conditions affect specific quality properties of tomatoes. The distance between the infrared radiation emitter source and the surface of tomato slices and the thickness of tomato slices affected the drying time, non-enzymatic browning index, and brightness, ratio of redness to yellowness, ascorbic acid content, and lycopene content of dried tomatoes. Within the range of distances investigated, the increase in distance significantly decreased the drying time, ascorbic acid content, but insignificantly increased the lycopene content and the ratio of redness to yellowness. The combined effect of increasing the independent variables decreased the non-enzymatic browning indexes. With increase in thickness of the samples, the drying time increased significantly, the lycopene increased insignificantly, but decreased the non-enzymatic browning index, redness to yellowness ratio, ascorbic acid content, and color brightness values insignificantly. The prediction of the desirability model based on 95% confidence in the range of the independent variables gave the optimal drying conditions as 40.29 cm distance, and 9.04 mm sample thickness. The present study has provided useful information for industrial drying of tomatoes and for tomato powder for food preparation and pharmaceutical formulations. The results offer optimized drying conditions for the food industry to improve on quality of dried product.

Acknowledgements

The authors wish to extend their appreciation to the Open Fund of Jiangsu Provincial Key Laboratory for Physical Processing of Agricultural Products (JAPP2010-6), the Jiangsu Province Science and Technology Support Project (BE2011382), the Jiangsu University Graduate Research Innovation Program (CXZZ12_0700), the Jiangsu University Student Scientific Research Project (11A346), the Jiangsu University Student Practice Innovation Training Program, and the Priority Academic Program Development (PAPD) of Jiangsu Higher Education Institutions for their financial support toward the study.

References

Select your language of interest to view the total content in your interested language
Post your comment

Share This Article

Relevant Topics

Recommended Conferences

Article Usage

  • Total views: 11690
  • [From(publication date):
    March-2014 - Oct 20, 2017]
  • Breakdown by view type
  • HTML page views : 7903
  • PDF downloads :3787
 

Post your comment

captcha   Reload  Can't read the image? click here to refresh

Peer Reviewed Journals
 
Make the best use of Scientific Research and information from our 700 + peer reviewed, Open Access Journals
International Conferences 2017-18
 
Meet Inspiring Speakers and Experts at our 3000+ Global Annual Meetings

Contact Us

Agri, Food, Aqua and Veterinary Science Journals

Dr. Krish

[email protected]

1-702-714-7001 Extn: 9040

Clinical and Biochemistry Journals

Datta A

[email protected]

1-702-714-7001Extn: 9037

Business & Management Journals

Ronald

[email protected]

1-702-714-7001Extn: 9042

Chemical Engineering and Chemistry Journals

Gabriel Shaw

[email protected]

1-702-714-7001 Extn: 9040

Earth & Environmental Sciences

Katie Wilson

[email protected]

1-702-714-7001Extn: 9042

Engineering Journals

James Franklin

[email protected]

1-702-714-7001Extn: 9042

General Science and Health care Journals

Andrea Jason

[email protected]

1-702-714-7001Extn: 9043

Genetics and Molecular Biology Journals

Anna Melissa

[email protected]

1-702-714-7001 Extn: 9006

Immunology & Microbiology Journals

David Gorantl

[email protected]

1-702-714-7001Extn: 9014

Informatics Journals

Stephanie Skinner

[email protected]

1-702-714-7001Extn: 9039

Material Sciences Journals

Rachle Green

[email protected]

1-702-714-7001Extn: 9039

Mathematics and Physics Journals

Jim Willison

[email protected]

1-702-714-7001 Extn: 9042

Medical Journals

Nimmi Anna

[email protected]

1-702-714-7001 Extn: 9038

Neuroscience & Psychology Journals

Nathan T

[email protected]

1-702-714-7001Extn: 9041

Pharmaceutical Sciences Journals

John Behannon

[email protected]

1-702-714-7001Extn: 9007

Social & Political Science Journals

Steve Harry

[email protected]

1-702-714-7001 Extn: 9042

 
© 2008-2017 OMICS International - Open Access Publisher. Best viewed in Mozilla Firefox | Google Chrome | Above IE 7.0 version
adwords