Characterisation of Eluvial Corundum (Ruby) from Kermunda, Kalahandi District, Odisha, India

In India, Odisha state is famous for occurrences of varieties of gem stones and among them ruby and sapphire are conspicuous. The entire resource of ruby (5348 tonnes) is located in the state of Odisha, mainly in Kalahandi and Nuapara districts [1]. The important localities of corundum and ruby bearing zones are Jhillngdhar, Hinjlibahal, Banjipadar and Kermunda in Kalahandi district and Sinapalli and Sardapur in Nuapara district. At Jhillingdara, Mishra and Mohanty [2] reported occurrences of ruby and corundum mineralization at the contact between metapyroxenite and granite gneiss and also eluvial placer ruby in the surrounding soil horizons. Mazumder and Mathiew [3] reported corundum (ruby) crystallization in the brecciated pegmatite at contact zones of granite gneiss of Bastar craton near Sardapur area.


Introduction
Gemstones, especially the quality gemstones are most sought after minerals throughout ages due to their astrological and ornamental importance. The quality of gemstones is determined by its natural origin, beauty, durability, uniqueness, rarity, hardness, colour, size, structural defects and chemical resistance.
In India, Odisha state is famous for occurrences of varieties of gem stones and among them ruby and sapphire are conspicuous. The entire resource of ruby (5348 tonnes) is located in the state of Odisha, mainly in Kalahandi and Nuapara districts [1]. The important localities of corundum and ruby bearing zones are Jhillngdhar, Hinjlibahal, Banjipadar and Kermunda in Kalahandi district and Sinapalli and Sardapur in Nuapara district. At Jhillingdara, Mishra and Mohanty [2] reported occurrences of ruby and corundum mineralization at the contact between metapyroxenite and granite gneiss and also eluvial placer ruby in the surrounding soil horizons. Mazumder and Mathiew [3] reported corundum (ruby) crystallization in the brecciated pegmatite at contact zones of granite gneiss of Bastar craton near Sardapur area.
The NW margin of Odisha represents a cratonic mobile belt contact where high grade granulite facies rocks of Eastern Ghats Mobile belt are juxtaposed upon the low grade greenstone supracrustal rocks of Bastar craton. Several authors have studied the geology of Eastern Ghats mobile belt of India [4], and references therein]. Corundumspinel-sapphirine bearing Mg-Al rich granulites occur sporadically at different localities in the high grade metamorphic rocks of Eastern Ghats belt of Odisha [5]. The mineral assemblages in the Mg-Al rich rich rocks include: cordierite, phlogopite, orthopyroxene, corundum, spinel, sapphirine, kyanite, cummingtonite, gedrite, paragsite, garnet, sillimanite, rutile and quartz. Figure 1 is the geological map around Kermunda and the rock types-granite gneiss, mafic granulites and vein quartz-belong to Eastern Ghats belt [6]. Kermunda area is rugged and is extensively covered by soil and alluvium. At a number of localities small to large pits and trenches were dug illegally to pick out the corundum / ruby and garnet varieties form the soil zones. In this paper, we report macroscopic and microscopic textures and mineral chemistry of eluvial corundum/ruby grains from Kermunda area.

Materials and Methods
Corundum and ruby samples were collected by hand picking from different pits and trenches dug within alluvium zone. The size of the samples ranges between 20 to 3 mm. In the laboratory the samples were washed with dil. HCl to remove the ferruginous clay coatings followed by cleaning with water in ultrasonic bath. Thin sections of the grain mounts were prepared. Polished sections were made for study under ore microscope and Scanning Electron Microscope (SEM). Semi-quantitative analysis of the mineral phases was done by Energy Dispersive Spectrometer (EDS) attached to SEM.

Abstract
Corundum and ruby occur sporadically in the soil horizons around Kermunda area, which is situated in Kalahandi district of Odisha. The area is constitutes a part of the Precambrian khondalite-charnockite-granite gneiss terrane of Eastern Ghats. Corundum is light pink while ruby is rose red, carmine or purple red in colour. The corundum and ruby grains contain inclusions of rutile and zircon and are often surrounded by dark coloured spinel exhibiting corona texture. Sapphirine occurs as rim around spinel as well as corundum. Veinlets of hematite and diaspore traverse spinel and sapphirine aggregates. SEM-EDS analysis indicated that (i) corundum and ruby grains contains trace amounts of Fe and Cr, (ii) spinel is pleonaste and chromium pleonaste types and (iii) sapphirine is silica-poor and magnesian rich. The corundum-spinel intergrowth showing corona texture suggests that under high P-T gradient in granulite facies metamorphism, corundum reacted with either phlogopite or garnet to form spinel by the reactions: (i) Corundum + Phlogopite= Spinel + K-feldspar + Water or (ii) Corundum+Garnet = Spinel. Sapphirine is possibly a reaction product of (i) Corundum+Spinel+Garnet= Sapphirine or (ii) Spinel+Silica= Sapphirine.

Microscopic study
Under transmitted light microscope, the colour of the corundum grains is faint pinkish while the ruby grains are crimson red. Fractures are prominent in both corundum and ruby grains (Figures 7 and 8).

Macroscopic study
The colour of the corundum grains is light pinkish and the grains are barrel, hexagonal, rhombohedral and irregular shaped (Figures 2  and 3). Basal parting is prominent in the hexagonal and barrel shaped grains. Small dark colour mineral (rutile) is noted in corundum. The colour of the ruby grains is red to crimson red. The grains are mostly subrounded, elliptical and angular in nature ( Figure 4). Occasionally, dark green spinel partially covers the ruby surface ( Figure 5). Some ruby grains show distinct corona texture due to presence of spinel rim ( Figure 6).        (Figure 9). Rutile and zircon are major mineral inclusions within corundum ( Figure  10). Corona texture is well documented in which spinel partially to completely mantle the host corundum and ruby grains ( Figure 11). Spinel is green to deep green in colour and occurs as coarse xenoblastic crystals ( Figure 12). In some samples, sapphirine grains are noted which exhibits distinct pleochroism from blue, pale yellow to sapphire blue. It occurs as reaction rim around both spinel and corundum with characteristics of tabular, radiating sheaths to granular aggregates (Figures 12 and 13).

SEM study
The SEM micrographs (BSE images) of corundum and ruby grains are shown in Figures 14-22. BSE images have the advantage of distinguishing the mineral phases which show minor differences in the brightness and contrast values. Moreover, EDS analysis of coarse to very fine grains helps in identification of mineral phases. Successive rims of spinel and sapphirine around ruby grains are shown in Figure  14. The contact between the different mineral phases is irregular and sharp. Partial rim of sapphirine around corundum grain is shown in Figure 15. Sapphirine also grows within corundum as Y-shaped grains. This corundum grain contains inclusions of minute phlogopite       laths and subrounded rutile grains. Grain boundary contact between corundum-spinel, spinel-sapphirine and corundum-sapphirine is depicted in Figures 16-19. Fractures are common in both corundum and sapphirine. Spinel grains frequently exhibit corroded patterns which are possibly due to brecciation and chemical weathering. Fine veinlets and irregular masses of hematite are common within spinel grains (Figures 18,19). The patchy and inter-fingering intergrowth of spinel-corundum-sapphirine and spinel-sapphirine are shown in Figures 20 and 21 respectively. Rutile grains occur as inclusion within the corundum, spinel and less commonly within sapphirine grains.
Coarse rutile grains are also noted along the grain boundaries of polygonal spinel grains (Figure 22). Besides rutile, the other minerals noted as inclusions in corundum, spinel and sapphirine are: zircon, monazite, ilmenite and Y-W oxide. Diaspore veinlets and masses are observed mostly in association with spinel and sapphirine (Figure 23). Diaspore is a hydration product of corundum and spinel and formed during chemical weathering.

EDS analsyis of the minerals
The range and average chemical composition of corundum, spinel, sapphirine, phlogopite and rutile are given in Table 1

Discussion
Corundum mineral is encountered in wide variety of rock types. It is relatively common in metamorphic rocks and its P-T stability domain is vast. Sapphirine is a metamorphic mineral and occurs in rocks of granulite facies metamorphism of Mg-Al rocks containing cordierite, phlogopite, corundum, garnet, gedrite, cummingtonite, orthopyroxene, spinel and aluminosilicate minerals [7]. On the basis of texture, grain contact and mineral association in the Mg-Al rich rocks several types of metamorphic reactions have been proposed for the formation of these minerals [8][9][10]. From the textural studies of the eluvial corundum and ruby samples of the study area, it is difficult to uniquely deduce reactions / metamorphic conditions leading to the formation of different minerals. In the surrounding soil horizons, besides corundum the other dominant coarse minerals are quartz, garnet and phlogopite with small amounts of goethite, titaniferous magnetite and altered feldspars.
The textural observation in the studied corundum and ruby grains suggests that the spinel is derived from reaction between corundum and other silicate minerals. In one corundum grain phlogopite inclusion is recorded. Spinel grains contain significant amounts of Fe and Mg suggesting that spinel might have been formed by reaction of corundum and Mg-Fe containing silicate mineral, phlogopite or garnet. The following reactions singularly or in combination might have given rise to the observed corundum-spinel textural features. The reactions are: (a) Phlogopite + Corundum = Spinel + K-feldspar +water [7] or (b) Corundum + Garnet = Spinel.
Sapphirine occurs as rims around spinel as well as corundum. It might have been formed by the following reactions: (i) Spinel + Silica = Sapphirine or (ii) Corundum+Spinel+ Garnet= Sapphirine [10]. These reactions are based on the fact that garnet and quartz are abundant in the surrounding soil suggesting possible reaction with spinel to form sapphirine in the host rocks.

Conclusions
(1) The eluvial corundum grains are faint pinkish whereas ruby grains are purple red in colour. They are highly fractured and contain abundant rutile and minor amounts of zircon, monazite, Y-oxide and ilmenite inclusions.
(2) Well developed corundum-spinel corona texture suggests reaction of corundum and biotite or garnet to form spinel during high grade metamorphic condition of the protolith.
(3) The spinel grains belong to pleonaste to chromium pleonaste type as indicated by their composition.
(4) Sapphirine occurs in contact with corundum and also as rim around spinel. Sapphirine is formed by reaction of spinel and quartz or garnet under granulite facies metamorphic conditions.
From the mineralogical and chemical studies, it is concluded that the eluvial ruby grains from Kermunda area are of low quality due to presence of fractures, random mineral inclusions and corona texture.