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Electrical Transport Properties and Gamma-Ray Attenuation Coefficient of Some Phosphate Glasses Containing By-Pass Cement Dust

Salem SM, Mostafa AG, Ahmed MA, Yassin OM and Abu Gasser RA*

Department of Physics, Faculty of Science, Al-Azhar University, Nasr City, Cairo, Egypt

*Corresponding Author:
Gasser R
Department of Physics, Faculty of Science
Al-Azhar University, Nasr City, Cairo, Egypt
Tel: +20 102 722 7142
[email protected]

Received date: March 20, 2017; Accepted date: April 20, 2017; Published date: April 25, 2017

Citation: Salem SM, Mostafa AG, Ahmed MA, Yassin OM, Abu Gasser RA (2017) Electrical Transport Properties and Gamma-Ray Attenuation Coefficient of Some Phosphate Glasses Containing By-Pass Cement Dust. Bioceram Dev Appl 7:100. doi:10.4172/2090-5025.1000100

Copyright: © 2017 Salem SM, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

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Some phosphate glasses containing different amounts of by-pass cement dust (BCD) were prepared by the melt quenching method. The selected molecular composition was [(100-x)% - P2O5 (x)% BCD (where 30≤ x≥60)]. The obtained experimental density and molar volume values were inspected and were then compared with those obtained empirically for the close packed structure of the corresponding compounds. The comparison between experimental and emperical values evidenced the short range order of the studied samples. The electric and dielectric properties were thoroughly investigated. The appearance of maxima and minima in the total conductivity BCD concentration dependence can be attributed to the mixed alkali – alkaline earth effect (MAAE) and to the presence of considerable amount of CaO. The suitability of such glasses to act as gamma-ray shielding materials was thoroughly investigated, and correlation between the chemical composition (the BCD concentration) and gamma-ray attenuation behavior was established.


By-pass cement dust; Phosphate glasses; Electrical transport properties; Gamma – ray attenuation


Amorphous materials and glasses appear now of interest due to their important functional applications in both science and technology [1]. Therefore, much efforts have been devoted to study either high purity glasses samples used for scientific purposes, or others doped with a controlled amount of impurities used for commercial application [2,3]. Among all scientific applications, electrical transport properties are of interest, where some glasses can be used as electrically insulators while some others can be used as conductors depending mainly on their compositions. It is known also that the amount and type of the introduced alkali oxide into a glass network affect directly relation with several properties of such glass [4-6]. Therefore, the understanding of the electrical conductivity of glasses is very important. Although a great deal of work has been done to determine the electrical conductivity in such like glasses, more work is still needed to clarify the true mechanism of conduction [5-7].

From another point of view the use of different radioactive isotopes now in industry, medicine, agriculture etc, make it necessary to study various materials that possess shielding character. For different nuclear radiation, special shielding materials are required [8-10].

From another point of view, by-bass cement dust (BCD) represents a dangerous by-product of cement industry and it accumulated in huge amounts in Egypt. It causes various diseases, especially those related to human respiratory system [11]. According to the chemical analysis, such waste consists of various oxides (mainly, CaO, SiO2, Na2O, K2O and Fe2O3) [12,13], where all these oxides can be used for manufacturing different types of oxide glass [13].

However, in this article, it will be tried to prepare some phosphate glasses with different additives of BCD, as high as possible, aiming to consume the waste accumulation as well as to obtain low coast glasses that can be used for different industrial and scientific application. Also, the prepared glasses will be thoroughly investigated from the electrical properties point of view as well as their gamma-ray shielding properties, in order to obtain some shielding transparent glasses as well as, they can act to capsulate the radio-active wastes before interment underground.

Experimental Procedure

BCD was supplied by Tora Cement Co., Helwan, Cairo, Egypt, and it was chemically analyzed using X-ray fluorescence technique (model, Panalytical Axios advanced, The Netherlands). The obtained chemical analysis is exhibited in Table 1.

Constituents Cement dust
SiO2 6.96
Al2O3 2.36
Fe2O3 3.60
CaO 60.36
MgO 1.54
Na2O 0.03
K2O 10.74
L.O.I. 16.59
Total 100

Table 1: The chemical composition of the used BCD.

The selected glass batches were weighted from ammonium dihydrogen ortho-phosphate and the supplied BCD, so that when melted, they give glasses having the following percentage molecular composition [(70-x) P2O5 - x BCD, where 30 ≤ X≥ 60 in steps of five]. The weighted batches were ground and mixed well in an agate mortar and they were then melted in porcelain crucibles in an electric muffle furnace for 2 hrs at 110°C. Melts were stirred several times during melting, and were then poured between two copper plates in the environmental air. The obtained glass samples, just after solidifying, were transferred to the annealing furnace at 450°C for 2 hrs and the furnace was then turned off and left to cool to RT with a cooling rate of 0.42 K/min.

The XRD spectra of the prepared samples were obtained using (Rigaku RINT2100) outfitted with (Cukα radiation of λ= 0.1541 nm) and the maximum current and voltage were 300 mA and 50 KV respectively.

The experimental density was measured applying Archimedes technique, using carbon tetra-chloride (CCl4) as an immersion liquid, using equation (1),

equation (1)

where ρexp and Ρl are the experimental density of a sample as well as the density of the iquid respectively, Ma and Ml are the masses of the sample in air and in liquid respectively.

The experimental molar volume values (Vm) were then calculated using equations (2) [14].

equation (2)

where (Mm) is the main molecular weight in (g/mol) of a sample and ρexp is the experimental density value of such sample..

The empirical density values were also calculated using the following equation:

equation (3)

where ρi are the densities of the oxides forming the glass and Xi is the mole fraction of each oxide.

The empirical molar volume values were then calculated using equation (3) but with replacing ρexp by ρemp [14].

For the electrical measurements, the obtained glasses were polished from both sides in order to obtain optically flat disk shape samples of 8 mm diameter and 2 mm thickness. Then the disks were coated from both sides with an air drying silver paste to achieve good electrical contact. The measurements were carried out using a computerized Stanford LCR bridge model SR 720 at four fixed frequencies [0.12 kHz, 1 kHz, 10 kHz and 100 kHz], and all measurements were performed in the temperature range from 300 K to 525K.

Results and Discussion

The amorphous nature of the prepared samples was examined visually where they all appeared transparent, homogenous and having no crakes or air bubbles.

For more conformation, X-Ray Diffraction (XRD) technique was applied to confirm the amorphous nature of the prepared samples. Therefore, Figures 1a and 1b shows the XRD patterns of the glasses containing 30 and 60 mol% BCD as representative patterns, and all other patterns show similar spectra.


Figure 1: (a and b) (XRD) of the samples containing 30 and mol% BCD.

These patterns show no any discreet lines or sharp peaks, but only a hump appeared at 2Ɵ between 20o and 30o degree indicating that the prepared samples are all of amorphous nature and short range order character.

The density values of the studied glasses were experimentally measured applying the liquid displacement technique. The empirical values were also calculated applying equation (3) and the obtained values were compared with those obtained theoretically for the close packed structure of the corresponding compounds.

Both the experimental and empirical density values are exhibited in Figure 2 as a function of BCD content, for comparison. It is seen that both density values (empirical and experimental) increased gradually and linearly with the gradual increase of BCD, and the empirical density is usually higher than the corresponding experimental density values.


Figure 2: The variation of both density values (experimental and empirical) versus BCD content.

Since the molar volume is directly related to the internal spatial structure of materials, it is suitable to exhibit also the change of the molar volume of the studied glasses [14]. Figure 3 exhibits the variation of the calculated molar volume values (both empirical and experimental) as the BCD was gradually increased, where it show a linear gradual decrease. It is observed also that the empirical values are usually lower than those obtained experimentally.


Figure 3: The variation of both the molar volume values (experimental and empirical) versus BCD content.

Also, the rate of the decrement of the experimental molar volume values appeared to be higher than that of the corresponding empirical rate of change. The observed variations of both the empirical and the experimental density and molar volume values may be due to the introduced BCD which contains various positive cations, where these cations fill mostly the network vacancies, and in turn decreases the internal free volume. Accordingly the density is logically increased, while the molar volume is gradually decreased, as BCD was gradually increased.

It is worth to state that, the higher empirical density as well as the lower empirical molar volume in comparison to the corresponding experimental values can be taken also as evidences for the amorphous nature and the short range order character of the studied samples. It can be stated also that, it is possible to obtain pure glasses with higher amounts of BCD up to 60 mol%.

The frequency dependence total conductivity (σ(ω,T)) for all samples follows the exponent law of the following equation (no. 4),

equation (4)

where σdc is the frequency independent conductivity, A is a weakly temperature dependent factor, s is the exponent factor (usually less than unity) and ω is the angular frequency [15-17]. The obtained experimental conductivity data (σ(T)) for sample no. (4) (as a representative figure), are exhibited in Figure 4 as a function of 1000/T.


Figure 4: Total conductivity temperature dependent for sample no. (4) as representative figure.

It is appeared that at low temperatures the conductivity shows weak temperature dependence and strong frequency dispersion, while at high temperatures, it shows strong temperature dependence and weak frequency dependence. It is worth to state that all sample exhibited similar behavior. It can be stated that, the dc conductivity is dominant at high temperatures while the ac conductivity is dominant at low temperatures. It is concluded also from the conductivity values that all samples behave like semiconductors [18].

Figure 5 shows the variation of lnσT as a function of BCD, where two maxima and two minima are easily observed. It is easy to observe also that, all lnσT values are fluctuated between 13 s/m and 11 s/m. Since the used BCD consists of about 60.4% CaO and 10.7% of K2O, it is supposed that an electrical resistance appeared due to the interaction between the alkali and the alkaline earth cations at some compositions. Interesting physical effects have been previously observed in studying the behavior of glassy ionic conductors by Mansour [19].


Figure 5: The total conductivity as a function of BCD content.

The understanding of the microscopic transport mechanism for conduction in glass is a longstanding problem in glass science. Many glasses exhibit a roughly linear behavior with changing their chemical composition. But glasses containing two different alkali oxides represent a major exception to this trend due to the mixed alkali effect (MAE) or mixed alkali earth effect (MAEE) phenomenon [20]. For the studied glasses, the deviation from linearity may be so great that two maxima (at 40 mol% and 55 mol%) and minima (at 35 mol% and 45 mol%) occur. Moreover, the MAE was observed as a dramatic nonlinear trend due to the introduction of alkali (K+) and alkaline earth (Ca2+) cations, where the resistance increased with increasing the difference between the radii of both the alkali and alkaline earth cations [20,21]. The concentrations of both CaO and K2O in all samples were calculated and exhibited in Table 2.

Sample no. Mol.% of BCD Mol. % of CaO Mol.% of K2O
1 30 18 3.36
2 35 21 3.85
3 40 24 4.4
4 45 27 4.95
5 50 30 5.5
6 55 33 6.05
7 60 36 6.6

Table 2: The concentrations of CaO and K2O in all the prepared samples.

At a fixed temperature (325 K), the relation between ln(σT) and ln(ω) for sample no. (4), is exhibited in (Figure 2) as a representative figure.

The dotes and solid line represent the experimental data and theoretical fitting respectively (with any equation). It can be seen that, at low frequency the conductivity is approximately stable and independent on frequency, while at high frequency the conductivity increased [22], According to all the obtained data, it can be stated that all samples show similar semiconducting behavior (Figure 6).


Figure 6: ln (σT) versus ln (ω) at a fixed temperate for the sample no. (4) as a representative curve.

The DC conductivity values were then calculated from the fitting of the experimentally obtained σT data with equation no. (4) and the obtained data are then plotted in Figure 7 as a function of BCD content. It is seen that the change of σT is a non-linear behavior and maxima and minima are exhibited at 35 mol% and 55 mol% BCD, corresponding to CaO concentrations of 21 and 33 mol% respectively and the amounts of K2O are also 3.3 and 6.05 mol% respectively. It can be supposed that the observed nonlinear behavior may be due to the mixed Alkali (K+) alkaline earth (Ca2+) effect.


Figure 7: The DC conductivity as a function of BCD content.

The DC activation energy of conduction can be calculated form the slopes of the obtained straight lines of the studied sample according to Arhenius equation (equation number 5) at high temperatures, where the dc conductivity is dominant.

equation (5)

where σ0 is the pre-exponential factor and ΔE is the activation energy. The variation of the activation energy with BCD is exhibited in Figure 8 where this figure shows approximately the reverse behavior of the conductivity [23] and such trend was expected to be logic.


Figure 8: The DC activation energy of conduction as a function of BCD content.

Figure 9 shows the variation of the s-factor as a function of temperature for sample no. (4), as representative figure. The obtained values of the exponent factor (s), for all samples, show approximately linear decrease with the increase of temperature. Because of the agreement between the experimental behavior of the exponent factor (S) and those predicted by the CBH model (equation (6)), proposed by Elliot [19]. It is supposed that such model can be used to describe the conduction mechanism in these glasses, and it is observed that, all samples exhibit the same behavior.


Figure 9: The variation of the S-factor as a function of temperature for sample (1) as representative figure.

equation (6)

where (τ0 = fo-1) is the characteristic relaxation time in between 10-9 and 10-12 sec, k is the Boltzman constant, T is the absolute temperature and Wm is the energy required to remove an electron from its site to infinity.

The dielectric constant (ε') has been also measured, and Figure 10 shows the variation of ε' as a function of temperature for sample no. (4), as representative figure. It is observed that at low temperatures ε' is almost independent of temperature, while at high temperatures it increases gradually as the temperature was increased, but it shows an inverse variation with frequency. The reason for this behavior is that, the electric dipoles move almost parallel to the ac external electric field and create an inverse internal electric field. With the increase of temperature the movement of the electric dipole is easier and the dipoles move parallel to the ac external electric field and then the internal electric field increased and acts to decrease the dielectric constant [19,23]. It is also found that all samples exhibited similar behavior.


Figure 10: The di-electric constant temperature dependence at different frequencies.

On the other hand, Figure 11 shows the variation of the dielectric loss factor (ε″) as a function of temperature for sample no. (4) as a representative figure. It is clear that at low temperatures ε″ exhibit approximately stable value, while at high temperatures it starts to increase as the temperature was increased, and the increment rate is inversely proportional to the frequency. This behavior was explained by Stevels [24,25] who divided the relaxation phenomena into three parts, the conduction loss, the dipole loss and the vibrational loss. Since the conduction loss is proportional to σ(ω), therefore ε″ increases as the conductivity increased, where σ(ω) is temperature dependent quantity.


Figure 11: The variation of the dielectric loss factor (ε″) as a function of temperature.

Until now, the majority of the nuclear radiation shields consists of layers of different concretes with different compositions and densities. But considerable variations in water contents in concretes add high uncertainty factor in calculating the attenuation coefficients and moreover, they are also opaque to visible light [26]. With the development of the X-COM computer program the mass attenuation coefficient for different shielding materials can be calculated [27,28]. Material to be used for shielding should have homogeneous density and composition. Glasses are promising materials in this regard.

The main objective is to correlate between the composition and structure of studied glasses and their attenuation behaviors to examine the suitability for users as radiation-shielding materials.

The mass attenuation coefficient is written as:

equation (7)

Where ρ is the density of material (g/cm3), I0 and I are the incident and transmitted intensities, respectively, and x is the thickness of absorber (cm).

The Theoretical value of the total mass attenuation coefficients of mixture or compound has been calculated by WinXCom, based on the mixture rule [26].

equation (8)

Where (μ/ρ) m is the total mass attenuation coefficient for the individual element in each component and wi is the fractional weight of the element in each component.

This mixture is valid when the effects of molecular binding, chemical and crystalline environment are negligible. Theoretical values for the total mass attenuation coefficient can be found in the tables prepared by Hubbell and Seltzer. Berger and Hubbell developed XCOM program for calculating the total mass absorption coefficients or the photon interaction cross- sections for any element, compounds or mixtures at various photon energies from (1 keV to 100 GeV). Recently, XCOM was transformed to the Windows platform by Gerward et al. [27], where it called WinXCom.

The following mass attenuation coefficient relates half value layer to linear attenuation coefficient (μL):

HVL = 0.693/ μ (9)

where HVL is half value layer and μL is the linear attenuation coefficient (cm)

The obtained gamma-ray attenuation coefficient and the Half Value Layer:

Mass attenuation coefficient

Figure 12 shows the calculated results of the mass attenuation coefficients of the studied glass samples for different energies (low gamma-ray energies) as a function of BCD content; It was found that the mass attenuation coefficients (μm) of all samples show generally an increase only slowly with the increase of the weight fraction of BCD at the expense of P2O5. This may be due to the gradual increase in the density of the investigated glass samples (Figure 13). In addition, the increase in photon interaction probability at these energies leads to the decrease the gamma-rays transmission with the increase in the amount of P2O5, which indicates the better shielding properties.


Figure 12: The mass attenuation coefficient as a function of BCD content at different γ – ray energies.


Figure 13: The mass attenuation coefficient as a function of BCD content at 356 Kev.

The numerical values of the calculated mass attenuation coefficients (μm) at different energies are summarized in Table 3.

Glass No BCD (mol %) Density (gm/cm3) µm   (cm2/gm) × (10-2 )
356   Kev 662    Kev 1173 Kev 1332 Kev
1 30 0.8183 9.851 7.44 5.641 5.289
2 35 0.950 9.858 7.471 5.67 5.317
3 40 1.083 9.864 7.502 5.699 5.344
4 45 1.215 9.871 7.532 5.728 5.371
5 50 1.348 9.877 7.563 5.757 5.398
6 55 1.480 9.884 7.593 5.786 5.425
7 60 1.612 9.89 7.64 5.816 5.445

Table 3: The mass attenuation coefficient as a function of BCD content at relatively low γ – ray energies.

The Half Value Layer (HVL)

HVL is the thickness of a material required to reduce the intensity of the transmitted radiation to its half value. Such value can be used to describe the effectiveness of the studied shields. Definition from the European Nuclear Society]. Figure 14 shows the behavior of the HVL for the studied glasses with different amounts of BCD and various gamma-ray energies. These figures indicate that the half value layer (HVL) decreases with the increase of the weight fractions of BCD. This may be due to the higher values of mass attenuation coefficients and the densities of the studied glass samples. The numerical values of the calculated HVL at different energies are summarized in Table 4.


Figure 14: The half value layer as a function of BCD content at relatively low γ – ray energies.

Glass No BCD (mol %) Density (gm/cm3) HVL
356   Kev 662    Kev 1173 Kev 1332 Kev
1 30 1.92905 9.999 7.665 5.828 5.462
2 35 2.34899 10.01 7.670 5.831 5.465
3 40 2.47639 10.02 7.675 5.835 5.469
4 45 2.62365 10.03 7.681 5.838 5.472
5 50 2.70551 10.04 7.686 5.842 5.475
6 55 2.85243 10.05 7.691 5.845 5.478
7 60 3.15972 10.06 7.696 5.848 5.481

Table 4: The half value layer as a function of BCD content at relatively low gamma-ray ray energies.

Generally, these results indicate that the present glass system is a good attenuator for gamma photons (Figure 15) and promising gammaray shielding material due to their high mass attenuation coefficient and their low half value layer (HVL). Finally, it is worth to mention that the present glass system will open new possibility for a lead-free radiation protecting glass with non-toxicity to our environment.


Figure 15: The half value layer as a function of BCD content at 356 Kev.


It was found that the recycling of BCD in the glass manufacture is a matter of interest due the accumulation of huge amounts as well as its dangerous attack to the human reparatory system. It was concluded also that, phosphate glasses accept up to 60 mol% of BCD to give pure transparent and homogenous glasses, which evidenced by comparing the experimental and empirical density and molar volume values, as well as by XRD results It was found, electric transport properties studies that all glasses behave like semiconductors. The mixed alkali effect and the amount of CaO present act to corrupt the expected linear behavior of the total conductivity dependence BCD concentration.

The present glass system is a good attenuator for γ –photons and promising gamma-ray shielding material due to their high mass attenuation coefficient and their low half value layer (HVL) to certain low gamma-ray energy.


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