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E-ISSN: 2252-5211
International Journal of Waste Resources
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Use of Sepiolite and Zeolite Mixtures as a Landfill Liner

Ahmet Tuncan*, Mehmet Inanc Onur, Kazım Akpinar and Mustafa Tuncan

Department of Civil Engineering, Anadolu University, Eskisehir, Turkey

*Corresponding Author:
Tuncan A
Department of Civil Engineering
Anadolu University
Eskisehir, Turkey
Tel: + 90.222.321.3550
Fax: + 90222.323950
E-mail: [email protected]

Received date: January 02, 2016; Accepted date: January 19, 2016; Published date: January 26, 2016

Citation: Tuncan A, Onur MI, Akpinar K, Tuncan M (2016) Use of Sepiolite and Zeolite Mixtures as a Landfill Liner. J Waste Resources 6:197. doi: 10.4172/2252-5211.1000197

Copyright: © 2016 Tuncan A, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

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Abstract

This study presents an investigation into the possibility of using sepiolite and zeolite mixtures to design a landfill liner. Leakage from the impervious layer into the environment is the main difficulty of storing hazardous waste. Therefore, determining the impermeable layer and in-situ application procedure is very important and needs laboratory experimentation. For this purpose, a series of experiments have been conducted on a mixture of zeolite+sepiolite. The geotechnical, physico-chemical and micro-structural properties of 30% sepiolite by weight of zeolite have been determined through laboratory testing. At the end of the research, the results show that zeolitesepiolite mixtures can be effectively used in bottom lining systems for hazardous, industrial and municipal waste.

Keywords

Sepiolite; Zeolite; Landfill liner; Geotechnical and chemical properties

Introduction

Waste disposal sites are areas of soil and groundwater contamination in industrialized countries. Leachate generated from water percolating through waste is a principal carrier of soluble and suspended contaminants in an impermeable liner. Proper management of leachate is important to minimize the risk of contamination of soil and groundwater. Properly designed lining and capping systems are essential for the protection of the surrounding environment. The construction of correct lining systems also has importance in reducing the risk to the environment through design procedure.

Güney et al. [1] investigated the feasibility of using kaolinite, sepiolite, zeolite and their mixtures as a bottom liner material. They indicate that sepiolite is the dominant material that affects both geo mechanical and geo environmental properties of these alternative liners. They conclude that an increase in the sepiolite content in sepiolite + zeolite mixtures increases the strength, swelling potential and metal adsorption capacity of the soil mixtures. Sun et al. [2] considered microbial properties, such as microbial community and enzyme activities, chemical properties, such as pH and metal fraction and heavy metal accumulation in spinach to assess stabilization remediation effectiveness using sepiolite. Their results show that soil pH increases with rising sepiolite concentration. An addition of sepiolite converted significant amounts of the exchangeable fraction of Cd and Pb into residual form. Benson et al. [3] investigated the hydraulic conductivity (permeability) of compacted clay liners. Hydraulic conductivity measurements were conducted on a wide variety of soils from 67 landfills in North America. They found that the hydraulic conductivity values were less than 1x10-7 cm/sec.

Simon and Muller [4] refer to standards for alternative cover lining materials and design criteria in Germany. Jain et al. [5] investigated heavy metal concentrations of old and new sanitary landfill liner systems. Tuncan et al. [6] studied using natural zeolite as a landfill liner. Different ratios of bentonite and zeolite mixtures were compacted with an optimum water content. Shear strength parameters, permeability, pH heavy metal content and other properties of compacted mixtures were determined. They conclude that B/Z = 0.10 ratio is the ideal mixture for sanitary land fill liner material. Ozdemir [7] studied using sepiolite as a sanitary liner. He concludes that sepiolite could be used with kaolinite as a landfill material

Typically, hydraulic conductivity must be less than or equal to 1x10-7 cm/sec for soil liners and covers used to contain hazardous waste, industrial waste and municipal waste [8]. One important aspect of hydraulic barriers is the cation exchange capacity (CEC) of the liner material. The most common clay minerals, such as kaolinite, illite and chlorite have CEC values of between 5 and 40 meq/100 g [9], whereas natural zeolites have CEC values of between 200 and 400 [10].

A miniature artificial landfill tank (3 m x 1 m x 0.50 m) was constructed in order to simulate an actual in-situ application 30% sepiolite mixed zeolite was compacted and layered in the tank. The tank was divided into six sections. Each section was 0.50 m x 0.50 m x 0.50 m in dimension. After 28 days curing time, copper and chromium were poured into each pair of parts, separately and distilled water was also poured into two parts for comparison. The tank was observed for sixteen weeks. Nylon covered on the tank to prevent evaporation. Leachate samples were collected from the bottom of the tank to determine physico-chemical properties of the leachate. Changes in geotechnical and physico-chemical properties of the sepiolite mixed zeolite, before and after the experiment, were determined. Scanning electron microscope pictures were also taken to observe the microstructure of both contaminated and uncontaminated samples.

Materials

Sepiolite

In this study, sepiolite was obtained from the city of Eskisehir, Turkey. The chemical composition of sepiolite consists of 55.97%, SiO2, 22.81% MgO, 1.56% Al2O3, 0.12% Na2O, 0.27% K2O, 0.77% Fe2O3, 0.02% MnO, 0.125 TiO2, 0.57% CaO, 17.75% Loss of Ignition [6]. Sepiolite is a magnesium hydro silicate clay mineral. It has a fiber structure form. Certain physico-chemical and geotechnical properties are shown in Table 1.

Properties Zeolite* Sepiolite#
pH 9.50 7.72
Electrical conductivity (mS/cm) 2.69 0.3
Cation exchange capacity (meq/100g) 90 20-30
Specific Gravity 2.60 2.50
Silt (%) 12 31
Clay (%) 88 69
Liquid Limit (%) 447 132
Plastic Limit (%) 60 85
Shrinkage Limit (%) 32 39
* Taken from [6]        # Taken from [7].

Table 1: Physico-chemical and geotechnical properties of sepiolite and zeolite.

Zeolite

In this study, zeolite was obtained from the city of Balikesir, Turkey. X-ray diffraction analyses of zeolite give the following results; 71.39% Si, 13.30% Al, 3.69% K, 2.74% Mg, 0.94% Fe, 0.47% Na, 0.03% P and 0.01% S [6]. Zeolites are a group of basic hydro-alumina-silicate minerals. Certain physico-chemical and geotechnical properties are shown in Table 1.

Contaminants

Waste produces leachate, which contains various heavy metals. A landfill liner can be affected by these substances. In this study, copper (Cu) and chromium (Cr) are chosen contaminants. In this study, 1000 ppm Cu (CuCl2x2H2O) and 1000 ppm Cr (Cr3Clx6H2O) solutions were prepared and used for the leachate experiments.

Testing method

The mixture of sepiolite and zeolite was prepared on the basis of dry weight. The chosen sepiolite/zeolite ratio was 0.3, which was found to be the best ratio by Kabakc [11]. Distilled water was then added to the mixture. A miniature landfill tank was used to obtain the closest results of in-situ applications. The tank was divided into six sections as shown in Figures 1 and 2.

international-journal-waste-resources-Landfill-tank

Figure 1: Landfill tank with a division.

international-journal-waste-resources-soil-tank

Figure 2: Placement of soil into tank.

The first and the second sections consist of a 10 cm thick compacted S/Z = 0.3 mixture with Cr solution over it. The third and fourth sections consist of a 10 cm thick compacted S/Z = 0.3 mixture with Cu solution over it. The fifth and sixth sections consist of a 10 cm thick compacted S/Z = 0.3 mixture with distilled water over it. The procedure is shown in Figures 3 and 4.

international-journal-waste-resources-Compaction-procedure

Figure 3: Compaction procedure.

international-journal-waste-resources-Compaction-procedure

Figure 4: Compaction procedure.

The impermeable layer, the index and physico-chemical properties of which were determined, was placed into the miniature landfill tank and compacted. A standard compaction test was employed to prepare the specimens. The optimum moisture content and maximum dry density of the S/Z = 0.3 mixture were 36.5% and 12.1 kN/m3, respectively. Heavy metals, such as Cu and Cr, were added over the compacted layers at the end of a 28 day curing period (Figure 5).

international-journal-waste-resources-Cr-solutions

Figure 5: Preparation procedure and addition of Cu and Cr solutions into the sections.

Distilled water was also added to the other sections for comparisons. Room temperature was kept at 15-18 °C over the 16 weeks of observations. The miniature landfill was covered in nylon to prevent evaporation from the liquids as shown in Figures 6 and 7.

international-journal-waste-resources-Curing-procedure

Figure 6: Curing procedure.

international-journal-waste-resources-Curing-procedure

Figure 7: Curing procedure.

Leakage samples were collected from the bottom of the tank (Figure 8) and kept in a refrigerator. The liquids in the landfill tank were discharged at the end of the 16 week period. The geotechnical and physico-chemical properties of the impermeable layers in the sections were determined. Scanning electron micrograph pictures were also taken to observe the change in the micro-structural properties of the mixtures.

international-journal-waste-resources-Leakage-collection

Figure 8: Leakage collection procedure.

Results and Discussion

Atterberg consistency limits, unconfined compressive strength and permeability

Atterberg consistency limits, unconfined compressive test (UCS) results, permeability and the coefficient of compression values of the mixtures are given in Table 2. It can be seen that the addition of Cr and Cu decreases plasticity and strength values, but increases the permeability and coefficient of the compression values of the S/Z = 0.3 mixtures after the 16 week curing period. The PI values are less than 50%, so the required value for the samples used as hazardous landfill should be less than 50% [8]. The permeability values are also less than 1x10-7 cm/sec, so the permeability results are within limits.

Materials LL(%) PL(%) PI(%) UCS(kPa) k(cm/sec)x10-8 Cc
S/Z=0.3
(Compacted)
68 45 23 292 1.17 0.240
Cr Solution 73 65 8 55 ---- 0.278
Cu Solution 75 59 16 105 3.50 0.248
Distilled Water 76 63 13 71 ---- ----

Table 2: Test results.

Electrical conductivity, ph and cation exchange capacity

The accumulation and migration of salt were measured using a conductivity meter (Omega CDB-70). Approximately two hundred and fifty grams of air dried (20oC) specimen were sieved through a No. 16 sieve, and homogeneously mixed with distilled water to make a paste. This was then left for 24 hours to determine the electrical conductivity (EC) of the mixtures [12,13]. The electrical conductivity values are less than 4 mS/cm, so this value is within limits. General views of the Cu and Cr contaminated and the distilled water sections of the tank after the test are given in Figures 9-11, respectively.

international-journal-waste-resources-Cu-contaminated-mixture

Figure 9: Cu contaminated mixture.

international-journal-waste-resources-Cr-contaminated-mixture

Figure 10: Cr contaminated mixture.

international-journal-waste-resources-Distilled-water

Figure 11: Distilled water added mixture.

The pH of the specimens was measured using a pH meter (Cole Parmer 39000-50). A twenty gram specimen of air dried (20°C) was sieved through a No. 40 sieve, homogeneously mixed with 50ml of distilled water and left for one hour to determine the pH of the mixtures according to the EPA Method 9045 (1986). The pH values are all between 8,0 and 8,5. The soil pH should be between 6 and 8 to minimize any immobilization of heavy metals. Cation Exchange capacity (CEC) is an important parameter for the attenuation of leachate through a clay landfill liner. If the CEC of a clay liner is high, more contaminants are removed from the leachate. The CEC was determined by the sodium saturation method [14]. The electrical conductivity, pH and cation exchange capacity values of the specimens are given in Table 3. The cation exchange capacity values found in the experiments are enough to hold heavy metals in soil.

Materials pH E.C.(mS/cm) CEC (mg/lt)
Cr Solution 8,40    0,55     58,83
Cu Solution 8,03 0,60 57,74
Distilled Water 8,10           0,40     56,52

Table 3: Results of electrical conductivity (e.c.), ph, cation exchange capacity.

Total heavy metals

The Cu amount of 10 cm thick S/Z = 0,3 specimen is around zero, which means that there is no leaching through the specimen. There is also no leaching through the 10 cm thick specimen with distilled water above it. There is leaching through the 5 cm thick specimen which have Cr and Cu above it. The Cr and Cu amounts in the leachate samples are 0,2 mg/lt and 0,227 mg/lt, respectively. These heavy metals are below limits (Cu = 0,005-9,9 mg/lt and Cr = 0,2-18 mg/lt) [15].

Scanning electron microscopy

Undisturbed specimens were prepared for a scanning electron microscopy (SEM) analysis. The specimens were examined for microstructure (fabric) by SEM and for chemical composition by the energy dispersive x-ray (EDX) technique, using an LEO 440 model scanning electron microscope. The specimens were dried in an oven at 105oC and were held on an aluminum sample holder with adhesive tape. Later, they were coated with gold to minimize any charge build up and were examined under the SEM. The specimens were then scanned for chemical composition using EDX.

The scanning electron microscope is an ideal tool to observe features of the fabric of soil. Soil microstructure is a function of the fabric and the physico-chemistry of the soil waste additive system. Microstructural units are not only composed of single particles, but also compound particles held together by physico-chemical forces. The compound particles are domains, aggregates, agglomerates, flocculates and organic compounds. Physico-chemical forces are responsible for aggregating clay particles and binding them together.

Scanning electron micrographs of the S/Z = 0,3 mixture with distilled water are shown in Figures 12 and 13. It can be seen from the figures that the zeolite particles are of cubic form. The scanning electron micrographs of the S/Z = 0,3 with Cu and Cr solution samples are shown in Figures 14-17, respectively. Flocculated and aglomareted structures can be observed from these figures. When the zeolite is mixed with water, agglomerated structures may form. After adding sepiolite to the zeolite, the agglomerated structures are cemented and bonded. The addition of Cu and Cr breaks the bonds between the particles and the sample therefore becomes less aggregated and flocculated.

international-journal-waste-resources-SEM-micrographs

Figure 12: SEM micrographs of S/Z=0.3 (1000X - 5000X) [15].

international-journal-waste-resources-SEM-micrographs

Figure 13: SEM micrographs of S/Z=0.3 (10000X - 20000X) [15].

international-journal-waste-resources-SEM-micrographs

Figure 14: SEM micrographs of S/Z=0.3 with Cu solution (1000X - 5000X) [15].

international-journal-waste-resources-SEM-micrographs

Figure 15: SEM micrographs of S/Z=0.3 with Cu solution (10000X -20000X) [15].

international-journal-waste-resources-SEM-micrographs

Figure 16: SEM micrographs of S/Z=0.3 with Cr solution (1000X - 5000X) [15].

international-journal-waste-resources-SEM-micrographs

Figure 17: SEM micrographs of S/Z=0.3 with Cr solution (20000X - 25000X) [15].

Conclusion

This study shows that zeolite-sepiolite mixtures can be effectively used in bottom lining systems for hazardous, industrial and municipal waste. The sepiolite-zeolite mixtures proposed in this study, not only exhibit low permeability, but would also act as an efficient chemical filter. The cation exchange capacity of zeolite is measured at very high levels compared to sepiolite. Therefore, heavy metals, such as Cu and Cr, can be held by zeolite [16]. Sepiolite-zeolite mixtures having a ratio of S/Z:0.3 can also be used as a hazardous landfill liner. On the other hand, this study is performed for specific soil properties and heavy metals, so additional research is recommended for other conditions.

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