alexa Preparation and Properties of Luminescent Lanthanide Based Graphene Oxide | OMICS International| Abstract

ISSN: 2161-0398

Journal of Physical Chemistry & Biophysics

  • Research Article   
  • J Phys Chem Biophys 2013, Vol 3(3): 120
  • DOI: 10.4172/2161-0398.1000120

Preparation and Properties of Luminescent Lanthanide Based Graphene Oxide

Amanda L Jenkins1*, David P Ziegler2, Erik Emmons3 and Christopher J Karwacki4
1ASK Incorporated, 7447 Rockawalkin Road, Hebron, Maryland, 21830, USA
2US Army Natick RDE Center, Natick, Massachusetts, 01760, USA
3Science Applications International Corportation, 3465 Box Hill Corporate Center Drive, Abingdon, Maryland, 21009, USA
4Edgewood Chemical Biological Center, 5183 Blackhawk Road, Gunpowder, Maryland, 21010, USA
*Corresponding Author : Amanda L Jenkins, ASK Incorporated, 7447 Rockawalkin Road Hebron, Maryland, 21830, USA, Tel: 410-436-8660, Email: [email protected]

Received Date: Jun 24, 2013 / Accepted Date: Jul 18, 2013 / Published Date: Jul 25, 2013

Abstract

Novel photoluminescent materials were prepared from the reaction of graphene oxide and luminescent lanthanides (europium, terbium, gadolinium, samarium, and dysprosium) in methanol at high pH. The binding of the lanthanides to graphene oxide through the oxygen functionality was evidenced by the sharp enhancement of laser induced luminescence and the appearance of peaks in specific regions of the spectra of the lanthanides. Raman spectroscopy indicated that the graphene oxide maintained its structure within the material and verified the complexation with the lanthanide. Surface morphology studies using SEM and TEM demonstrated the coverage of the graphene oxide surface by the lanthanide. Although some limited work has been published on europium and graphene oxide, this is the first study encompassing the majority of the luminescent lanthanides, taking full advantage of their capabilities including advanced electronic structure, raman and visible luminescence in a variety of colors.

Keywords: Lanthanides; Graphene; Luminescence; Raman; Europium; Terbium; Samarium; Gadolinium; Dysprosium

Citation: Jenkins AL, Ziegler DP, Emmons E, Karwacki CJ (2013) Preparation and Properties of Luminescent Lanthanide Based Graphene Oxide. J Phys Chem Biophys 3: 120. Doi: 10.4172/2161-0398.1000120

Copyright: © 2013 Jenkins AL, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

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