alexa Synthesis and Characterization of a New Cadmium Framework Based on 2,5-Dimethyl-1,3,4-Thiodiazole and Dicyanamide Anion
e-ISSN: 2319-9849

Research & Reviews: Journal of Chemistry
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Research Article

Synthesis and Characterization of a New Cadmium Framework Based on 2,5-Dimethyl-1,3,4-Thiodiazole and Dicyanamide Anion

Wang Y*, Zhou B, Li M, Lin P and Zhao X

Tianjin Key Laboratory of Structure and Performance for Functional Molecules, Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry, Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin, China

*Corresponding Author:
Wang Y
Tianjin Key Laboratory of Structure and Performance for Functional Molecules
Key Laboratory of Inorganic-Organic Hybrid Functional Material Chemistry
Ministry of Education, College of Chemistry, Tianjin Normal University, Tianjin, China
Tel: +86-22-23766336
E-mail:
[email protected]

Received date: 12/08/2015; Accepted date: 28/09/2015; Published date: 30/09/2015

 

Abstract

Using the 2,5-dimethyl-1,3,4-thiodiazole (L) ligand and bridging dicyanamide anion, a new CdII complex [Cd0.5(L)(H2O)(cyanourea)] [Cd(N(CN)2(H2O)]n (1) has been synthesized and characterized by X-ray single crystal diffraction. The fundamental structural unit of the title complex contains two CdII centers, two neutral free L ligands, two bridging dca anions, one bridging cyanourea ligand and three terminal coordinated aqua molecules. It is noted that the cyanourea ligands are not used as the starting materials and formed from dicyanamide simply by hydrolysis. To the best of our knowledge, cyanourea represents the first example to participate in the coordination of metal ions in coordination chemistry up to now.

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