alexa Synthesis and Structure of Homoleptic Iron Complex Bear
ISSN: 2161-0401

Organic Chemistry: Current Research
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Research Article

Synthesis and Structure of Homoleptic Iron Complex Bearing Pincer-Type 1,2,3-Triazol-5-ylidene

Haruka Iwasaki, Yuji Koga and Kouki Matsubara*
Department of Chemistry, Fukuoka University, Fukuoka, Japan
*Corresponding Author : Kouki Matsubara
Professor, Fukuoka University Chemistry
8-19-1, Nanakuma Fukuoka, 814-0180, Japan
Tel: +81928716631
E-mail: [email protected]
Received: January 07, 2016; Accepted: January 08, 2016; Published: January 16, 2016
Citation: Iwasaki H, Koga Y, Matsubara K (2016) Synthesis and Structure of Homoleptic Iron Complex Bearing Pincer-Type 1,2,3-Triazol-5-ylidene. Organic Chem Current Res 5:161. doi:10.4172/2161-0401.1000161
Copyright: © 2016 Iwasaki H, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.
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Abstract

Novel iron(II) complex bearing pyridine-bridged bis(1,2,3-triazol-5-ylidene) ligand was synthesized. During many attempts to obtain the compounds, we found generation of dicationic homoleptic iron(II) complex with two tridentate ligands. Analogous monocationic complex with only one tridentate ligand, which is an unstable intermediary complex during formation of the dicationic complex was detected. Structural identification of the homoleptic dicationic product revealed that octahedral geometry stabilized the iron complex and also π-stacking interaction exists between these two tridentate ligands.

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