alexa Theoretical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures of Anisic Aldehyde with some Esters at Different Temperatures Using Different Theories and Models| Abstract

ISSN: 2157-7544

Journal of Thermodynamics & Catalysis

  • Research Article   
  • J Thermodynam Cat 2012 4: 120,
  • DOI: 10.4172/2157-7544.1000120

Theoretical Evaluation of Ultrasonic Velocities in Binary Liquid Mixtures of Anisic Aldehyde with some Esters at Different Temperatures Using Different Theories and Models

Sandhya Sri PB, Zareena Begum and Rambabu C*
Department of Chemistry, Acharya Nagarjuna University, Guntur, Andhra Pradesh, India
*Corresponding Author : Rambabu C, Department of Chemistry, Acharya Nagarjuna University, Guntur, Andhra Pradesh, India, Email: [email protected]

Received Date: Mar 15, 2013 / Accepted Date: Apr 13, 2013 / Published Date: Apr 26, 2013

Abstract

Densities and Ultrasonic velocities of the binary liquid mixtures of Anisicaldehyde with Methyl Acetate (MA) Ethyl Acetate (EA) and Butyl Acetate (BA) have been measured at a temperature range from 303.15 to 318.15 K with an interval of 5 K, over the entire composition of mole fractions. The theoretical values of ultrasonic velocity were evaluated using the Nomoto’s relation (UNR), Impedance relation (UIR), Ideal mixing relation (UIMR), Rao’s specific velocity relation (UR) Junjie’s relation (UJR) and Danusso model (UD). The molecular interaction parameter (χ), Chi-square value, average percentage error (APE) have been evaluated to find the best applicable theory. The variation of this interaction parameter with the mole fraction of common compound has been discussed in terms of molecular interactions.

Keywords: Ultrasonic velocity; Anisic aldehyde; Acetates; Chisquare test; Molecular interaction parameter

Citation: Sandhya Sri PB, Zareena Begum, Rambabu C (2013) Mixtures of Anisic Aldehyde with some Esters at Different Temperatures Using Different Theories and Models. J Thermodyn Catal 4: 120. Doi: 10.4172/2157-7544.1000120

Copyright: © 2013 Sandhya Sri PB, et al. This is an open-access article distributed under the terms of the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction in any medium, provided the original author and source are credited.

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