Organic Chemistry: Current Research
Open Access
ISSN: 2161-0401
ISSN: 2161-0401
Kai Wu, Mei Pan and Cheng-Yong Su
Sun Yat-sen University, China
Posters & Accepted Abstracts: Organic Chem Curr Res
In supramolecular coordination chemistry field, coordination driven assembly of Metal-Organic Cages (MOCs) with welldefined shapes and unique cavities has drawn great attention in the past decades. A wide variety of applications, such as altering chemical reactivity, intriguing host-guest properties and potentials in chiral recognition, catalysis, as well as drug delivery and release have been thoroughly explored. In the present study, we have reported the host-guest and photochemistry study of ferrocene derivative guests, employing our MOC-16 as a host. The host-guest interaction of three ferrocene (Fc) derivative guests with MOC-16 host were thoroughly studied by NMR spectra, their optical property by UV-vis, FL spectra and their electrochemical behavior by CV was also studied. Surprisingly, the fluorescence of MOC-16 quenched rapidly when the ferrocene derivative guests were encapsulated by MOC-16 in water. Hence, it was observed that the fluorescence can be recovered simply by extracting guests from the cage cavity with organic solvent.
Kai Wu has received his BS in Chemistry from Lanzhou University, China in the year 2013. Currently, he is pursuing his PhD degree from Sun Yat-Sen University. His current research interests are centered on supramolecular coordination assembly and its application.
Email: wukai513@126.com