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Nano barium diphenylamine sulfonate association constant, triple ion association constant and thermodynamic parameters
4th International Conference on Nanotek & Expo
December 01-03, 2014 DoubleTree by Hilton Hotel San Francisco Airport, USA
Elsayed T Helmy
Scientific Tracks Abstracts: J Nanomed Nanotechnol
Abstract:
In this paper, the interaction of nano barium diphenylamine sulfonate with methanol and water has been studied by using conductance properties. Limiting molar conductivity (Λo), association constant (KA) ,Walden product (Λo, ηo), fluidity ratio (Rx), Fuoss- Shedlovsky parameters (S, Z and S(z)), activity coefficient (γ? ), association constant (KA), dissociation constant (KD), degree of dissociation (α), triple ion association constant (K3), thermodynamic parameters , activation free energies and its related thermodynamic parameters were calculated from conductance measurements at different temperatures from (293.15 K?308.15 K). The values of (Λo) increases with increasing temperatures, the values of (KA) increase with increasing temperatures. All values are discussed.