alexa A luminescent microporous metal-organic framework for the fast and reversible detection of high explosives.


Chemical Sciences Journal

Author(s): Lan A, Li K, Wu H, Olson DH, Emge TJ,

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Abstract Sensors and sensitivity: A highly luminescent microporous metal-organic framework, [Zn(2)(bpdc)(2)(bpee)] (bpdc = 4,4'-biphenyldicarboxylate; bpee = 1,2-bipyridylethene), is capable of very fast and reversible detection of the vapors of the nitroaromatic explosive 2,4-dinitrotoluene and the plastic explosive taggant 2,3-dimethyl-2,3-dinitrobutane, through redox fluorescence quenching with unprecedented sensitivity (see spectra). This article was published in Angew Chem Int Ed Engl and referenced in Chemical Sciences Journal

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