alexa A readily synthesized cyclic pyrrolysine analogue for site-specific protein "click" labeling.
Chemistry

Chemistry

Organic Chemistry: Current Research

Author(s): Hao Z, Song Y, Lin S, Yang M, Liang Y,

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Abstract A concise route was developed for the facile synthesis of a cyclic pyrrolysine analogue bearing an azide handle. Directed evolution enabled the encoding of this non-natural amino acid in both prokaryotic and eukaryotic cells, which offers a highly efficient approach for the site-specific protein labeling using click chemistry. © The Royal Society of Chemistry 2011 This article was published in Chem Commun (Camb) and referenced in Organic Chemistry: Current Research

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