alexa Alkenyl thiol-derived metal-organic frameworks (MOFs) by means of postsynthetic modification for effective mercury adsorption.


Chemical Sciences Journal

Author(s): Liu T, Che JX, Hu YZ, Dong XW, Liu XY,

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Abstract The synthesis of new functionally diverse alkenyl-derived Cr-MIL-101s (MIL=material of Institute Lavoisier) was realized by a novel and convenient postsynthetic modification (PSM) protocol by means of the carbon-carbon bond-forming Mizoroki-Heck reaction. The new PSM protocol demonstrates a broad scope of substrates with excellent tolerance of functionality under mild reaction conditions. Moreover, a new metal-organic framework (MOF) that bears both alkenyl and thiol side chains prepared by means of the tandem PSM method has shown excellent adsorbent ability in removing mercury ions from water. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. This article was published in Chemistry and referenced in Chemical Sciences Journal

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