alexa beta-triketones from myrtaceae: isoleptospermone from leptospermum scoparium and papuanone from corymbia dallachiana
Pharmaceutical Sciences

Pharmaceutical Sciences

Medicinal & Aromatic Plants

Author(s): van Klink JW, Brophy JJ, Perry NB, Weavers RT

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Abstract Naturally occurring beta-triketones, isoleptospermone [3, 5-hydroxy-4-(2-methyl-1-oxopentyl)-2,2,6, 6-tetramethyl-4-cyclohexene-1,3-dione) from Leptospermum scoparium] and papuanone [6, 5-hydroxy-4-(1-oxohexyl)-2,2,6, 6-tetramethyl-4-cyclohexene-1,3-dione from Corymbia dallachiana], have been synthesized. Full spectral data are reported for the first time. The 13C NMR spectra of 3, 6, and the other triketones flavesone (2), leptospermone (4), and grandiflorone (5) found in Myrtaceous plants are fully assigned. This article was published in J Nat Prod and referenced in Medicinal & Aromatic Plants

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