alexa Catalytic allylic oxidation with a recyclable, fluorous seleninic acid.
Diabetes & Endocrinology

Diabetes & Endocrinology

Journal of Steroids & Hormonal Science

Author(s): Crich D, Zou Y

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Abstract In conjunction with iodoxybenzene as reoxidant perfluorooctylseleninic acid catalyzes the allylic oxidation of alkenes to enones in trifluoromethylbenzene at reflux in moderate to good yield. After a reductive workup with sodium metabisulfite, the catalyst is recovered by fluorous extraction in the form of bis(perfluorooctyl) diselenide, which, itself, serves as a convenient catalyst precursor. [reaction: see text] This article was published in Org Lett and referenced in Journal of Steroids & Hormonal Science

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